[2,2'-联吡啶]-4,4'-二磺酸钠盐 | 101028-42-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 中文名称: [2,2'-联吡啶]-4,4'-二磺酸钠盐
• 英文名称: sodium [2,2'-bipyridine]-4,4'-disulfonate
• 英文别名: disodium [2,2'-bipyridine]-4,4'-disulfonate；disodium 2,2'-bipyridine-4,4'-disulphonate
• CAS: 101028-42-6
• 化学式: C₁₀H₆N₂O₆S₂*2Na
• 分子量: 360.279
• InChiKey: ANHQMUWHNIAYPJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.04
• 重原子数：
  21.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  140.18
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 [2,2'-联吡啶]-4,4'-二磺酸钠盐 在 水 作用下， 以 水 为溶剂， 生成 bis(2,2'-bipyridine)(2,2'-bipyridine-4,4'-disulphonato)ruthenium(II) dihydrate
  参考文献：
  名称：

  Anderson, Susan; Constable, Edwin C.; Seddon, Kenneth R., Journal of the Chemical Society, Dalton Transactions, 1985, p. 2247 - 2262

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-二氧化-2,2'-联吡啶 在 盐酸 、 ammonium metavanadate 、 Dowex 50W-X₈ 、 硫酸 、 三氧化硫 、 硝酸 、 碳酸氢钠 、 溶剂黄146 、 乙酰氯 、 sodium sulfite 、 锌 作用下， 以 乙醇 、 水 为溶剂， 反应 46.0h， 生成 [2,2'-联吡啶]-4,4'-二磺酸钠盐
  参考文献：
  名称：

  Anderson, Susan; Constable, Edwin C.; Seddon, Kenneth R., Journal of the Chemical Society, Dalton Transactions, 1985, p. 2247 - 2262

  摘要：

  DOI：

文献信息

• Interaction of Sulfonated Ruthenium(II) Polypyridine Complexes with Surfactants Probed by Luminescence Spectroscopy
  作者：David García-Fresnadillo、Guillermo Orellana

  DOI：10.1002/1522-2675(20010919)84:9<2708::aid-hlca2708>3.0.co;2-m

  日期：2001.9.19

  measurements. [Ru(pbbs)2(pta)]2− (5a) displayed cooperative self-aggregation in aqueous medium at concentrations above 1.3 μM; the observed association was enhanced in the presence of either β-cyclodextrin or NaCl. This amphiphilic RuII compound showed the strongest interaction with all the detergents tested: nucleation of surfactant molecules around the luminescent probe was observed below their respective

  新型阴离子 [RuL2L']2- 配合物，其中 L 代表 (1,10-phenanthroline-4,7-diyl)bis(benzosulfonate) (pbbs; 3a) 或 (2,2'-bipyridine)-4,4' -二磺酸盐 (bpds; 3b)，L' 是 N-(1,10-phenanthrolin-5-yl)tetradecanamide (pTA; 2a) 或 N-(1,10-phenanthrolin-5-yl)aceTAmide (paa; 2b) ) 合成，并通过电子吸收、发光光谱、发射寿命测定研究了它们与原型表面活性剂十二烷基硫酸钠 (SDS)、十六烷基三甲基溴化铵 (CTAB) 和 Triton X-100 (TX-100) 的相互作用，和 O2 淬火测量。[Ru(pbbs)2(pTA)]2- (5a) 在浓度高于 1.3 μM 的水性介质中表现出协同自聚集；在存在
• Oxidative carbonylation of amine using water-soluble palladium catalysts in biphasic media
  作者：Mahesh R. Didgikar、Sunil S. Joshi、Sunil P. Gupte、Makarand M. Diwakar、Raj M. Deshpande、Raghunath V. Chaudhari

  DOI：10.1016/j.molcata.2010.10.018

  日期：2011.1

  Application of water-soluble palladium catalysts for oxidative carbonylation of aniline to N,N' diphenyl urea (DPU) has been reported. The water-soluble palladium catalysts prepared from sulfonated N-containing ligands were found to be highly stable under reaction conditions and easily recyclable due to insoluble urea product in the reaction medium. This is in contrast to the sulfonated phosphine ligands, which are vulnerable to oxidation under reaction conditions, showing poor activity and stability. Commercially available as well as laboratory synthesized ligands were used for preparing water-soluble palladium catalysts, for oxidative carbonylation of aniline. The best activity was obtained for Pd complex with disodium 2,2'-bipyridine-4,4'-disulfonate (Bipy-DS) ligand. Under optimized conditions Pd(BipyDS)Pd(OAc)(2) catalyst gave TOF of similar to 210h(-1) with aniline conversion of similar to 97% with similar to 91% selectivity for N.N'-diphenyl urea. It was found that the catalyst was easily reusable up to five times, with negligible loss in the catalytic activity. The effect of reaction parameters was investigated and a plausible reaction mechanism has been proposed. (C) 2010 Elsevier B.V. All rights reserved.