N-phenyl-4-(5-phenylthiophen-2-yl)aniline | 1085434-10-1

• 物质功能分类: 医药中间体 - 杂环化合物 - 噻吩类化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-phenyl-4-(5-phenylthiophen-2-yl)aniline
• CAS: 1085434-10-1
• 化学式: C₂₂H₁₇NS
• 分子量: 327.45
• InChiKey: IWKPSHKZSJYUPA-UHFFFAOYSA-N

物化性质

• 沸点：
  497.3±33.0 °C(Predicted)
• 密度：
  1.188±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-phenyl-4-(5-phenylthiophen-2-yl)aniline 、 1,5-二溴萘 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 、 水 作用下， 以 甲苯 、 四氢呋喃 为溶剂， 反应 2.0h， 以65%的产率得到N1,N5-diphenyl-N1,N5-bis(4-(5-phenylthiophen-2-yl)phenyl)naphthalene-1,5-diamine
  参考文献：
  名称：

  WO2008/133459

  摘要：

  公开号：
• 作为产物：
  描述：

  苯胺 、 2-(4-溴苯基)-5-苯基噻吩 在 tris-(dibenzylideneacetone)dipalladium(0) sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 8.0h， 生成 N-phenyl-4-(5-phenylthiophen-2-yl)aniline
  参考文献：
  名称：

  AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

  摘要：

  本发明提供了一种具有特定结构的新型芳香胺衍生物以及一种有机电致发光器件，其中有机薄膜层包括至少一个发光层的单层或多层，被插入在阴极和阳极之间，上述有机薄膜层中的至少一层，特别是注入孔层中含有上述芳香胺衍生物的单一成分或混合成分。使用上述芳香胺衍生物可以实现一种有机电致发光器件，降低操作电压，使分子不易结晶，并提高有机EL器件的产量，并具有长寿命。

  公开号：

  US20080108832A1

文献信息

• AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：Yabunouchi Nobuhiro

  公开号：US20080108832A1

  公开（公告）日：2008-05-08

  The present invention provides a novel aromatic amine derivative having a specific structure and an organic electroluminescence device in which an organic thin film layer comprising a single layer or plural layers including at least a light emitting layer is interposed between a cathode and an anode, wherein at least one layer in the above organic thin film layer, particularly a hole injecting layer contains the aromatic amine derivative described above in the form of a single component or a mixed component. Use of the aromatic amine derivative described above materialize an organic electroluminescence device which reduces an operating voltage and makes molecules less liable to be crystallized and which enhances a yield in producing the organic EL device and has a long lifetime.

  本发明提供了一种具有特定结构的新型芳香胺衍生物以及一种有机电致发光器件，其中有机薄膜层包括至少一个发光层的单层或多层，被插入在阴极和阳极之间，上述有机薄膜层中的至少一层，特别是注入孔层中含有上述芳香胺衍生物的单一成分或混合成分。使用上述芳香胺衍生物可以实现一种有机电致发光器件，降低操作电压，使分子不易结晶，并提高有机EL器件的产量，并具有长寿命。
• 신규한 아민계 화합물 및 이를 이용한 유기발광 소자
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20210015325A

  公开（公告）日：2021-02-10

  본 발명은 신규한 아민계 화합물 및 이를 이용한 유기발광 소자를 제공한다.

  本发明提供了一种新的胺类化合物及其用于有机发光器件的方法。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：YABUNOUCHI Nobuhiro

  公开号：US20090066235A1

  公开（公告）日：2009-03-12

  Provided are an organic electroluminescent device including an aromatic amine derivative formed of a specific structure having a thiophene structure and an organic thin film layer interposed between a cathode and an anode and formed of one layer or a plurality of layers including at least a light emitting layer, in which at least one layer of the organic thin film contains the aromatic amine derivative alone or as a component of a mixture, the organic electroluminescent device in which molecules hardly crystallize, and which decreases a driving voltage, can be produced with improved yields upon the production of the organic electroluminescent device, and has a long lifetime, and an aromatic amine derivative realizing the organic electroluminescent device.

  提供了一种有机电致发光器件，包括一个具有噻吩结构的特定结构的芳香胺衍生物和一个有机薄膜层，该有机薄膜层位于阴极和阳极之间，形成为一个或多个层，包括至少一个发光层，其中有机薄膜的至少一层仅含有芳香胺衍生物或作为混合物的组分之一，该有机电致发光器件中分子几乎不结晶，降低了驱动电压，在生产有机电致发光器件时可以提高产量并具有长寿命，以及实现该有机电致发光器件的芳香胺衍生物。
• DIAMINE DERIVATIVES AND ORGANIC ELECTRONIC DEVICE USING THE SAME
  申请人：Jang Hye-Young

  公开号：US20100187504A1

  公开（公告）日：2010-07-29

  The present invention relates to a new diamine derivative, and an organic electronic device using the same. The diamine derivative according to the present invention can serve as a hole injecting, hole transporting, electron injecting, electron transporting, or light emitting material in an organic electronic device including an organic light emitting device. Particularly, it can serve as a light emitting dopant as used alone, in particular, a blue light emitting dopant. The organic electronic device according to the present invention exhibits excellent characteristics in terms of efficiency, drive voltage, life time, and stability.
• NEW HETEROCYCLIC DERIVATIVE AND ORGANIC LIGHT EMITTING DEVICE USING SAME
  申请人：Kim Ji-Eun

  公开号：US20120161612A1

  公开（公告）日：2012-06-28

  The present invention relates to a novel heterocyclic derivative and an organic light emitting device using the compound, and the heterocyclic derivative may largely improve a life span, efficiency, electrochemical stability and thermal stability of the organic light emitting device.