| 225928-67-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 225928-67-6
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: WLTGHTJWTNTUMC-HJWRWDBZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.52
• 重原子数：
  15.0
• 可旋转键数：
  6.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  在 palladium on activated charcoal 盐酸 、 N,N-二甲基丙烯基脲 、 正丁基锂 、 氢气 作用下， 以 四氢呋喃 、 Petroleum ether 为溶剂， 反应 0.5h， 生成 methyl dimethyl-11,11-oleate
  参考文献：
  名称：

  Studies related to in vivo CH activation: Synthesis and influence of 8,8- and 11,11-dimethyl oleic and 11,11-dimethyl linoleic acids on Δ12-desaturation of C. sorokiniana

  摘要：

  The synthesis of three acids was achieved using the Wittig reaction in order to study their in vivo influence on the Delta 12-desaturase of Chlorella sorokiniana. It was shown that the introduction of two methyls near the double bond prevent the desaturation of these exogenous acids while they seem to be accurately incorporated. This functionality could be of interest for the design of new thiaoleic acids as probes of the different oxidation processes. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)01166-1
• 作为产物：
  描述：

  n-溴代已基三苯基膦 、 2-(1,3-dioxolan-2-yl)-2-methylpropanal 在 N,N-二甲基丙烯基脲 、 正丁基锂 作用下， 生成
  参考文献：
  名称：

  Studies related to in vivo CH activation: Synthesis and influence of 8,8- and 11,11-dimethyl oleic and 11,11-dimethyl linoleic acids on Δ12-desaturation of C. sorokiniana

  摘要：

  The synthesis of three acids was achieved using the Wittig reaction in order to study their in vivo influence on the Delta 12-desaturase of Chlorella sorokiniana. It was shown that the introduction of two methyls near the double bond prevent the desaturation of these exogenous acids while they seem to be accurately incorporated. This functionality could be of interest for the design of new thiaoleic acids as probes of the different oxidation processes. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)01166-1