2,7-diformyl-9,10-dihydrophenanthrene | 42480-96-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,7-diformyl-9,10-dihydrophenanthrene
• 英文别名: 9,10-Dihydrophenanthrene-2,7-dicarbaldehyde
• CAS: 42480-96-6
• 化学式: C₁₆H₁₂O₂
• 分子量: 236.27
• InChiKey: XLQUZTCFOQDYPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,7-diformyl-9,10-dihydrophenanthrene 在 盐酸 、 sodium hydroxide 、 air 、 对甲苯磺酸 、 C.I.酸性橙108 作用下， 以 甲醇 、 乙醇 、 二氯甲烷 为溶剂， 反应 26.0h， 生成 2,7-bis(1,8-diethyl-2,3,4,5,6,7-hexamethylporphyrinyl)-9,10-dihydrophenanthrene
  参考文献：
  名称：

  具有聚苯撑基的双卟啉供体-受体化合物中的电子转移显示出弱的距离依赖性

  摘要：

  已经合成了一系列亚苯基桥连的双卟啉加合物，包含一个、两个或三个苯桥。提供了完整的合成细节。为了研究光化学电子转移，加入了混合金属，锌在一个卟啉大环中，而 Fe III（双咪唑）在另一个大环中。当光激发时，一个电子从 Zn 转移到 Fe III

  DOI：

  10.1021/ja00041a047
• 作为产物：
  描述：

  2,7-bis(bromomethyl)-9,10-dihydrophenanthrene 在 碳酸氢钠 、 二甲基亚砜 作用下， 反应 4.0h， 生成 2,7-diformyl-9,10-dihydrophenanthrene
  参考文献：
  名称：

  New quadrupolar fluorophores with high two-photon excited fluorescence

  摘要：

  新型四极荧光团具有增强的双光子激发荧光，是根据一种分子工程方法设计的，该方法基于由刚性共轭核心（二氢菲或二噻吩）构建的推拉拉伸分子。

  DOI：

  10.1039/a906182g

文献信息

• New quadrupolar fluorophores with high two-photon excited fluorescence
  作者：Lionel Ventelon、Mireille Blanchard-Desce、Laurent Moreaux、Jerome Mertz

  DOI：10.1039/a906182g

  日期：——

  New quadrupolar fluorophores that exhibit enhanced two-photon excited fluorescence were designed according to a molecular engineering approach based on push-push and pull-pull elongated molecules built from a rigid conjugated core (either dihydrophenanthrene or dithienothiophene).

  新型四极荧光团具有增强的双光子激发荧光，是根据一种分子工程方法设计的，该方法基于由刚性共轭核心（二氢菲或二噻吩）构建的推拉拉伸分子。
• US4013713A
  申请人：——

  公开号：US4013713A

  公开（公告）日：1977-03-22
• [EN] DYNAMERS: POLYMERIC MATERIALS EXHIBITING REVERSIBLE FORMATION AND COMPONENT EXCHANGE<br/>[FR] DYNAMERES: MATERIAUX POLYMERIQUES A FORMATION REVERSIBLE ET A ECHANGE DE COMPOSANTS
  申请人：LEHN JEAN-MARIE

  公开号：WO2004003044A2

  公开（公告）日：2004-01-08

  Alternating co-polymers involving the polycondensation of dihydrazides or diamines with dialdehydes reversibly exchange either one or both of their fundamental repeating monomer units in the presence of different monomer units. Furthermore, upon exchange of one of the repeating monomer units, the original monomer unit displaced can be re-introduced into the polymer, or the remaining unexchanged original monomer unit may also be interchanged. The polymers subjected to monomer exchange/interchange exhibit vastly different physical properties than those of the original unexchanged polymer. These dynamic, reversible polymers are therefore able to incorporate, decorporate or reshuffle their constituting monomers, in particular, with respect to environmental physical or chemical factors (heat, light, chemical entities, etc.). They thus have combinatorial features and represent adaptive materials.
• Electron transfer in bis-porphyrin donor-acceptor compounds with polyphenylene spacers shows a weak distance dependence
  作者：Anna Helms、David Heiler、George McLendon

  DOI：10.1021/ja00041a047

  日期：1992.7

  containing one, two, or three phenyl bridges. Complete synthetic details are provided. For studies of photochemical electron transfer, mixed metals were incorporated, with zinc in one porphyrin macrocycle and Fe III (bis-imidazole) in the other macrocycle. When photoexcited, an electron is transferred from Zn to Fe III

  已经合成了一系列亚苯基桥连的双卟啉加合物，包含一个、两个或三个苯桥。提供了完整的合成细节。为了研究光化学电子转移，加入了混合金属，锌在一个卟啉大环中，而 Fe III（双咪唑）在另一个大环中。当光激发时，一个电子从 Zn 转移到 Fe III
• Nanoscale Push-Push Dihydrophenanthrene Derivatives as Novel Fluorophores for Two-Photon-Excited Fluorescence
  作者：Lionel Ventelon、Sandrine Charier、Laurent Moreaux、Jerome Mertz、Mireille Blanchard-Desce

  DOI：10.1002/1521-3773(20010601)40:11<2098::aid-anie2098>3.0.co;2-0

  日期：2001.6.1

  Outperforming fluorescein by far, elongated fluorophores (e.g. 1) give rise to large two-photon absorption cross-sections σ2 in the visible-red or NIR region and high quantum fluorescence yields Φ (see figure; GM = 10-50 cm4 s photon-1 ). This opens interesting prospects in the field of two-photon microscopy imaging of cell membranes.