菲-1,2-二醇 | 19551-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 菲-1,2-二醇
• 英文名称: 1.2-Dihydroxy-phenanthren
• 英文别名: 1,2-Dihydroxyphenanthrene；phenanthrene-1,2-diol
• CAS: 19551-04-3
• 化学式: C₁₄H₁₀O₂
• 分子量: 210.232
• InChiKey: HNMUTKMLCMUDSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

ADMET

代谢

菲-1,2-二醇是菲在人身体内的已知代谢物。

Phenanthrene-1,2-diol is a known human metabolite of phenanthrene.

来源:NORMAN Suspect List Exchange

反应信息

• 作为反应物：
  描述：

  菲-1,2-二醇 在 三氯化铁 作用下， 以 盐酸 为溶剂， 以63%的产率得到1,2-菲醌
  参考文献：
  名称：

  Synthesis of the non-K-region o-quinones and dihydrodiols of polycyclic aromatic hydrocarbons from the corresponding phenols

  摘要：

  DOI：

  10.1021/jo01310a029
• 作为产物：
  描述：

  1,2-菲醌 在 溶剂黄146 、 锌 作用下， 生成 菲-1,2-二醇
  参考文献：
  名称：

  THE POTENTIALS AND THE DECOMPOSITION REACTIONS OF ORTHO QUINONES IN ACID SOLUTION

  摘要：

  DOI：

  10.1021/ja01353a053

文献信息

• Preparation of dihydroxy polycyclic aromatic hydrocarbons and activities of two dioxygenases in the phenanthrene degradative pathway
  作者：Kaci L. Erwin、William H. Johnson、Andrew J. Meichan、Christian P. Whitman

  DOI：10.1016/j.abb.2019.108081

  日期：2019.9

  Dihydroxy phenanthrene, fluoranthene, and pyrene derivatives are intermediates in the bacterial catabolism of the corresponding parent polycyclic aromatic hydrocarbon (PAH). Ring-opening of the dihydroxy species followed by a series of enzyme-catalyzed reactions generates metabolites that funnel into the Krebs Cycle with the eventual production of carbon dioxide and water. One complication in delineating

  二羟基菲，荧蒽和pyr衍生物是相应母体多环芳烃（PAH）细菌分解代谢中的中间体。二羟基物质的开环，随后进行一系列的酶催化反应，生成代谢物，这些代谢物进入克雷布斯循环，最终产生二氧化碳和水。描绘这些途径并将其用于有用目的的一个复杂之处在于，最初的酶促加工过程会产生多种具有多种开环可能性和产物的二羟基PAH。作为解决该问题的系统努力的一部分，合成了八种二羟基物质，并将其表征为二甲氧基或二乙酸酯衍生物。在菲的菲降解途径中用两种双加氧酶检查了几种二羟基化合物。Vanbaalenii分枝杆菌PYR-1。PhdF处理了一个3,4-二羟基菲，其k cat / K m为6.0×10 6  M -1 s -1，该值与该途径中PhdF的注释功能一致。PhdI处理的k cat / K m为3.1×10 5  M -1 s -1的1-羟基-2-萘甲酸，也与该途径中的拟议作用一致。这些观察结果为vanbaaleni
• LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
  申请人：DE BOER Eric Johannes Maria

  公开号：US20090062493A1

  公开（公告）日：2009-03-05

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R 4 )—P(R 1 )(R 2 )═N(R 3 )  (I) wherein: the R 1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R 2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

  本发明涉及一种配体及其在烯烃单体寡聚催化剂中的应用，该配体具有通式（I）： P(R4)—P(R1)(R2)═N(R3)  (I) 其中： R1基团选自烃基、取代烃基、杂原子烃基和取代杂原子烃基； R2基团选自烃基、取代烃基、杂原子烃基和取代杂原子烃基； R3选自氢、烃基、取代烃基、杂原子烃基、取代杂原子烃基、硅基或其衍生物； R4基团为可选取代的烷二氧、烷二硫或烷二氨基结构，通过烷二氧、烷二硫或烷二氨基结构的两个氧、硫或氮原子与磷原子结合，或者为可选取代的芳二氧、芳二硫或芳二氨基结构，通过芳二氧、芳二硫或芳二氨基结构的两个氧、硫或氮原子与磷原子结合。
• Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers
  申请人：DE BOER Eric Johannes Maria

  公开号：US20110288356A1

  公开（公告）日：2011-11-24

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand comprising the product formed by reacting i) a compound having the general formula (III); (R 1 )(R 2 )P—N(R 3 )—R 5 (III); and ii) a compound of the formula X—P(R 4 ), preferably at a temperature in the range of from −30 to 200° C.

  本发明涉及一种配体及其在寡聚烯烃单体催化剂中的使用，该配体包括通过反应以下化合物形成的产物：i) 具有通式（III）的化合物；(R1)(R2)P—N(R3)—R5(III)；和ii) 通式为X—P(R4)的化合物，优选温度在-30至200℃范围内。
• CATALYST SYSTEMS FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
  申请人：Shell Oil Company

  公开号：US20140107304A1

  公开（公告）日：2014-04-17

  The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (IV); (R 8 )(R 1 )P—N(R 3 )—P(R 4 )  (IV).

  本发明涉及一种配体及其在寡聚烯烃单体催化剂中的应用，该配体具有通式（IV）；(R8)(R1)P—N(R3)—P(R4)  (IV)。
• Phenanthrene based polyimide resin
  申请人：Coal Industry (Patents) Limited

  公开号：EP0036710A1

  公开（公告）日：1981-09-30

  A polyimide resin is made by converting a phenanthrene to its 9,10 diol derivative, reacting the derivative with formaldehyde to give a methylene bridged reaction product, oxidising the reaction product to produce a polycarboxylated product, and reacting the polycarboxylated product with an aromatic diamine to form the polyimide resin. The invention also includes the resin, the reaction product and the polycarboxylated product. The resin will be useful as a lamp capping cement, a high temperature insulator, in copper clad printed circuit boards, in glass or asbestor laminates for use as compressor blades.

  一种聚酰亚胺树脂的制造方法是将菲转化为其 9,10 二醇衍生物，使该衍生物与甲醛反应生成亚甲基桥接反应产物，氧化该反应产物生成聚羧化产物，再使该聚羧化产物与芳香族二胺反应生成聚酰亚胺树脂。本发明还包括树脂、反应产物和聚羧化产物。 这种树脂可用作灯的封盖胶合剂、高温绝缘体、覆铜印刷电路板、用作压缩机叶片的玻璃或石棉层压板。