Methyl 4-[[7,18-bis[2,6-di(propan-2-yl)phenyl]-14,22,26-tris(4-methoxycarbonylphenoxy)-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaen-11-yl]oxy]benzoate | 1312021-89-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Methyl 4-[[7,18-bis[2,6-di(propan-2-yl)phenyl]-14,22,26-tris(4-methoxycarbonylphenoxy)-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaen-11-yl]oxy]benzoate
• CAS: 1312021-89-8
• 化学式: C₈₀H₆₆N₂O₁₆
• 分子量: 1311.41
• InChiKey: PZIBPJWQROAQCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.9
• 重原子数：
  98
• 可旋转键数：
  22
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  217
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  Methyl 4-[[7,18-bis[2,6-di(propan-2-yl)phenyl]-14,22,26-tris(4-methoxycarbonylphenoxy)-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaen-11-yl]oxy]benzoate 在 水 、 sodium hydroxide 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 2.0h， 以100%的产率得到4-[[14,22,26-Tris(4-carboxyphenoxy)-7,18-bis[2,6-di(propan-2-yl)phenyl]-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaen-11-yl]oxy]benzoic acid
  参考文献：
  名称：

  Monovalent, Clickable, Uncharged, Water-Soluble Perylenediimide-Cored Dendrimers for Target-Specific Fluorescent Biolabeling

  摘要：

  Herein we report the synthesis of water-soluble polyglycerol-dendronized perylenediimides with a single reactive group that undergoes high-yielding click reactions. Single-molecule studies and target-specific biolabeling are reported, including the highly specific labeling of proteins on the surface of living bacterial and mammalian cells.

  DOI：

  10.1021/ja2009136
• 作为产物：
  描述：

  对羟基苯甲酸甲酯 、 染料红620 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 15.0h， 以74%的产率得到Methyl 4-[[7,18-bis[2,6-di(propan-2-yl)phenyl]-14,22,26-tris(4-methoxycarbonylphenoxy)-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaen-11-yl]oxy]benzoate
  参考文献：
  名称：

  Monovalent, Clickable, Uncharged, Water-Soluble Perylenediimide-Cored Dendrimers for Target-Specific Fluorescent Biolabeling

  摘要：

  Herein we report the synthesis of water-soluble polyglycerol-dendronized perylenediimides with a single reactive group that undergoes high-yielding click reactions. Single-molecule studies and target-specific biolabeling are reported, including the highly specific labeling of proteins on the surface of living bacterial and mammalian cells.

  DOI：

  10.1021/ja2009136

文献信息

• HIGHLY EFFICIENT MOLECULES SHOWING RESONANT ENERGY TRANSFER
  申请人：PHILIPS LIGHTING HOLDING B.V.

  公开号：US20170268746A1

  公开（公告）日：2017-09-21

  The invention provides a lighting device comprising a light source configured to provide light source light having a blue light component and a light converter configured to convert at least part of the light source light into converter light, wherein the light converter comprises a polymeric matrix ( 22 ) with a luminescent material, wherein the luminescent material comprises a luminescent molecule ( 300 ) comprising a first group ( 310 ) able to absorb at least part of the blue light component, and a second group ( 320 ) able to emit luminescent molecule light having a red light component, wherein the first group ( 310 ) is configured to transfer at least part of the energy acquired by the absorption of said blue light component to the second group ( 320 ) for generation of said luminescent molecule light having a red light component.