threo-9,10-dihydroxyhexadecane-1,16-dioic acid | 3100-38-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: threo-9,10-dihydroxyhexadecane-1,16-dioic acid
• 英文别名: threo-7,8-Dihydroxy-hexadecandisaeure-(1,16)；threo-7,8-dihydroxy-hexadecanedioic acid；threo-7,8-Dihydroxy-hexadecandisaeure；(+/-)-threo-6.7-Dihydroxy-tetradecan-dicarbonsaeure-(1.14)；(7R,8R)-7,8-dihydroxyhexadecanedioic acid
• CAS: 3100-38-7；18287-31-5；18287-32-6；37179-67-2；37179-69-4；124399-58-2
• 化学式: C₁₆H₃₀O₆
• 分子量: 318.411
• InChiKey: DVIKJRSTGGXNJP-ZIAGYGMSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  threo-9,10-dihydroxyhexadecane-1,16-dioic acid 在 吡啶 、 lead(IV) acetate 、 copper diacetate 作用下， 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Subramanian; Sharma, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1989, vol. 28, # 7, p. 551 - 555

  摘要：

  DOI：
• 作为产物：
  描述：

  9,10,16-三羟基十六烷酸 在 硫酸 、 丙酮 作用下， 生成 threo-9,10-dihydroxyhexadecane-1,16-dioic acid
  参考文献：
  名称：

  Nagel; Mertens, Chemische Berichte, 1936, vol. 69, p. 2050

  摘要：

  DOI：

文献信息

• The use of thiophen as a chain-extender. Part IV. Synthetic dihydroxyacids
  作者：J. F. McGhie、W. A. Ross、D. H. Laney、J. M. Barker

  DOI：10.1039/j39680000001

  日期：——

  ecanoic, 5,6-dihydroxy-12-methyltetradecanoic, 5,6-dihydroxytetradecanedioic, 7,8-dihydroxyhexadecanedioic, and 9,10-dihydroxyoctadecanedioic acid by the desulphurisation of suitable substituted thiophens is described. The preparation of some derivatives of these acids is also described.

  4,5-二羟基十三烷酸，5,6-二羟基十四烷酸，9,10-二羟基十八烷酸，5,6-二羟基-12-甲基十三烷酸，5,6-二羟基-12-甲基十四烷酸，5,6-二羟基十四烷二酸，7,8的合成描述了通过合适的取代噻吩的脱硫而生成的-二羟基十六烷二酸和9，10-二羟基十八烷二酸。还描述了这些酸的一些衍生物的制备。
• High-Temperature Tensile Deformation of Glass-Doped 3Y-TZP
  作者：Philip H. Imamura、Neal D. Evans、Taketo Sakuma、Martha L. Mecartney

  DOI：10.1111/j.1151-2916.2000.tb01688.x

  日期：2000.12

  Amorphous grain boundary phases in 3‐mol%‐yttria‐stabilized zirconia ceramics (3Y‐TZP) were studied to determine the influence of intergranular amorphous silicate phases on tensile superplasticity at temperatures of 1300–1500°C. Controlled additions (1 wt%) of compositionally distinct barium silicate and borosilicate phases were used. The initial grain sizes of the pure, barium silicate added, and borosilicate‐added samples were 0.45, 0.55, and 0.55 μm, respectively. Systems with added barium silicate and borosilicate glass both exhibited a 60% reduction in flow stress as compared with pure 3Y‐TZP, with the lower‐viscosity barium silicate system exhibiting a slightly greater reduction in flow stress. The higher‐viscosity borosilicate glass/3Y‐TZP materials exhibited the greatest elongation to failure, while the barium silicate/3Y‐TZP materials had the least elongation. Yttrium was found to segregate to grain boundaries in the pure and borosilicate‐containing samples, and both yttrium and barium were found to segregate to grain boundaries in the barium silicate containing samples. No silicon was observed along two‐grain boundaries in any of the samples, even those containing pockets of glass. The difference in deformation behavior may be due to a combination of viscosity of the glass addition, grain boundary segregation, and grain boundary bond character.
• SUBMMANNAN, G. B. V.;SHARMA, RAJIN, INDIAN J. CHEM. B , 28,(1989) N, C. 551-555
  作者：SUBMMANNAN, G. B. V.、SHARMA, RAJIN

  DOI：——

  日期：——
• Nagel; Mertens, Chemische Berichte, 1936, vol. 69, p. 2050
  作者：Nagel、Mertens

  DOI：——

  日期：——
• Subramanian; Sharma, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1989, vol. 28, # 7, p. 551 - 555
  作者：Subramanian、Sharma

  DOI：——

  日期：——