3,4-Bis-{2-[2-(2-decyloxy-ethoxy)-ethoxy]-ethoxy}-benzaldehyde | 656821-30-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4-Bis-{2-[2-(2-decyloxy-ethoxy)-ethoxy]-ethoxy}-benzaldehyde
• 英文别名: 3,4-Bis(2-(2-(2-(decyloxy)ethoxy)ethoxy)ethoxy)benzaldehyde；3,4-bis[2-[2-(2-decoxyethoxy)ethoxy]ethoxy]benzaldehyde
• CAS: 656821-30-6
• 化学式: C₃₉H₇₀O₉
• 分子量: 682.979
• InChiKey: SBJFTKBVJUOWFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  48
• 可旋转键数：
  39
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  90.9
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  肌氨酸 、 足球烯 、 3,4-Bis-{2-[2-(2-decyloxy-ethoxy)-ethoxy]-ethoxy}-benzaldehyde 以 氯苯 为溶剂， 反应 2.0h， 以41%的产率得到
  参考文献：
  名称：

  The self-assembly of gold nanoparticles with C60 nanospheres: fabrication and optical liming effect

  摘要：

  A new amphiphilic-like C-60 derivative (DTMF) with hydrophobic-hydrophilic-hydrophobic structure was synthesized and characterized. DTMF can form nanospheres with an average size of 50-100 nm in water. Gold nanoparticles with similar to10 nm diameters are self-assembled onto the surface of DTMF nanospheres via the in situ reduction of HAuCl4 in the aqueous solution of DTMF nanospheres. The optical limiting performance of the aqueous solution of DTMF nanospheres is improved by the formation of the DTMF-Au nano-assemblies. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2003.09.150
• 作为产物：
  描述：

  三聚乙二醇单癸醚 在 三溴化磷 、 potassium carbonate 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 生成 3,4-Bis-{2-[2-(2-decyloxy-ethoxy)-ethoxy]-ethoxy}-benzaldehyde
  参考文献：
  名称：

  The self-assembly of gold nanoparticles with C60 nanospheres: fabrication and optical liming effect

  摘要：

  A new amphiphilic-like C-60 derivative (DTMF) with hydrophobic-hydrophilic-hydrophobic structure was synthesized and characterized. DTMF can form nanospheres with an average size of 50-100 nm in water. Gold nanoparticles with similar to10 nm diameters are self-assembled onto the surface of DTMF nanospheres via the in situ reduction of HAuCl4 in the aqueous solution of DTMF nanospheres. The optical limiting performance of the aqueous solution of DTMF nanospheres is improved by the formation of the DTMF-Au nano-assemblies. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2003.09.150

文献信息

• The self-assembly of gold nanoparticles with C60 nanospheres: fabrication and optical liming effect
  作者：Pu Zhang、Shuang Zhang、Junxin Li、Dongfang Liu、Zhi-Xin Guo、Cheng Ye、Daoben Zhu

  DOI：10.1016/j.cplett.2003.09.150

  日期：2003.12

  A new amphiphilic-like C-60 derivative (DTMF) with hydrophobic-hydrophilic-hydrophobic structure was synthesized and characterized. DTMF can form nanospheres with an average size of 50-100 nm in water. Gold nanoparticles with similar to10 nm diameters are self-assembled onto the surface of DTMF nanospheres via the in situ reduction of HAuCl4 in the aqueous solution of DTMF nanospheres. The optical limiting performance of the aqueous solution of DTMF nanospheres is improved by the formation of the DTMF-Au nano-assemblies. (C) 2003 Elsevier B.V. All rights reserved.