2-p-Methoxyphenyl-oxetan | 17492-22-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-p-Methoxyphenyl-oxetan
• 英文别名: 2-(4-methoxy-phenyl)-oxetane；2-(4-Methoxyphenyl)oxetane
• CAS: 17492-22-7
• 化学式: C₁₀H₁₂O₂
• 分子量: 164.204
• InChiKey: GDNYMUGGOHYACV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-p-Methoxyphenyl-oxetan 、 2-(dimethyl(oxo)-λ⁶-sulfaneylidene)- 1-phenylethan-1-one 在 三氟甲磺酸 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以50%的产率得到
  参考文献：
  名称：

  氧杂环丁烷和锍叶立德的强酸催化亲电扩环

  摘要：

  已经开发了使用 sulfoxonium ylides将氧杂环丁烷的强质子酸催化亲电子环扩展成反式-2,3-二取代四氢呋喃衍生物。该反应使用安全稳定的锍叶立德，在没有金属催化剂和惰性气体保护的情况下，立体定向地产生官能化的反式-2,3-二取代四氢呋喃衍生物。

  DOI：

  10.1016/j.mcat.2021.111687

文献信息

• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。
• ACTIVE RAY-CURABLE COMPOSITION, ACTIVE RAY-CURABLE INK AND IMAGE-FORMING METHOD
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1829936A1

  公开（公告）日：2007-09-05

  Disclosed is an actinic ray curable ink containing pigment, a photolytic acid generating agent and an epoxy compound represented by the following formula (1-1) or (1-2),

  本发明公开了一种含颜料、光解酸生成剂和由下式（1-1）或（1-2）表示的环氧化合物的光固化油墨、
• POLYMERIZABLE ACTINIC RADIATION CURABLE COMPOSITION, POLYMERIZATION METHOD, ACTINIC RADIATION CURABLE INK AND IMAGE FORMATION METHOD, AND INK JET RECORDING APPARATUS AND EPOXY COMPOUND
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1840148A1

  公开（公告）日：2007-10-03

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of -O-, -S-, -SO-, SO2- -CBr2-, -C(CBr3)2-, and -C(CF3)2-; R1 to R18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合的光辐射固化组合物，包含一种光酸生成化合物和一种由式 (1) 表示的环氧化合物： 其中 X 代表二价基团，选自由-O-、-S-、-SO-、SO2-、-CBr2-、-C(CBr3)2-和-C(CF3)2-组成的组；R1 至 R18 各自独立地代表氢原子、卤素原子、具有 1-8 个碳原子的烃基，条件是烃基可能含有氧原子或卤素原子，或具有 1-8 个碳原子的取代或未取代的烷氧基。
• INK SET FOR INK-JET RECORDING, POLYMERIZATION METHOD AND IMAGE FORMING METHOD
  申请人：Ookubo Kimihiko

  公开号：US20070219292A1

  公开（公告）日：2007-09-20

  An ink set for ink-jet recording comprising a yellow ink composition for ink-jet recording containing one or more types of yellow color materials, a magenta ink composition for ink-jet recording containing one or more types of magenta color materials, and a cyan ink composition for ink-jet recording conditioning one or more types of cyan color materials, wherein each ink composition contains one or more of a) a compound having one or more polymerizable groups, b) an infrared absorbing agent, and c) a polymerization initiator, and further, the infrared absorbing agent contained in the yellow ink composition for ink-jet recording differs from the infrared absorbing agent contained in the cyan ink composition for ink-jet recording.
• Actinic ray curable composition, actinic ray curable ink and image formation method employing the ink
  申请人：Watanabe Shinya

  公开号：US20090252895A1

  公开（公告）日：2009-10-08

  Disclosed is an actinic ray curable ink containing pigment, a photolytic acid generating agent and an epoxy compound represented by formula (1-1), wherein R 1 through R 18 independently represent a hydrogen atom, a halogen atom, a hydrocarbon group, a hydrocarbon group having a halogen atom or an oxygen atom, or a substituted or unsubstituted alkoxy group.