5-(Hydroxymethyl)-methyl-cyclohexen | 117015-79-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(Hydroxymethyl)-methyl-cyclohexen
• 英文别名: (3-Methylcyclohex-3-en-1-yl)methanol
• CAS: 117015-79-9
• 化学式: C₈H₁₄O
• 分子量: 126.199
• InChiKey: NPYBERWOEMVZCJ-UHFFFAOYSA-N

物化性质

• 沸点：
  183.4±9.0 °C(Predicted)
• 密度：
  0.925±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-(Hydroxymethyl)-methyl-cyclohexen 在 N-溴代丁二酰亚胺(NBS) 、 硫酸 、 2-(3-环己烯基)乙醇 作用下， 以 甲醇 为溶剂， 反应 3.0h， 以59%的产率得到2-Brom-4-hydroxymethyl-1-methoxy-1-methyl-cyclohexan
  参考文献：
  名称：

  Haufe, Guenter; Gierscher, Fritz; Koehler, Guenther, Journal fur praktische Chemie (Leipzig 1954), 1987, vol. 329, # 5, p. 817 - 823

  摘要：

  DOI：

文献信息

• EPOXY-OXETANE COMPOUND, METHOD FOR SYNTHESIZING SAME, AND USE OF SAID COMPOUND
  申请人：SHIKOKU CHEMICALS CORPORATION

  公开号：US20200270236A1

  公开（公告）日：2020-08-27

  The purpose of the present invention is to provide: a novel curable compound which can be expected to be used as a raw material for photocurable resins and thermosetting resins; a method for synthesizing said compound; a resin composition containing said compound; and a cured product thereof. This compound is an epoxy-oxetane compound represented by a formula, and this compound has a structure in which two epoxycyclohexyl groups (groups in which an oxirane ring and a cyclohexane ring are condensed) are bonded to an oxetane ring via a connector having one ether bond. In formula (I′), R 1 to R 3 may be the same as, or different from, each other, and each denote a hydrogen atom or a methyl group. n is 1 or 2.

  本发明的目的是提供一种新型可固化化合物，可望用作光固化树脂和热固化树脂的原料；一种合成该化合物的方法；含有该化合物的树脂组合物；以及其固化产物。该化合物是一种由公式表示的环氧-氧杂环己烷化合物，该化合物具有两个环氧环己基团（氧环烷环与环己烷环结合）通过一个具有一个醚键的连接器连接到一个氧杂环己烷环的结构。在公式（I′）中，R1至R3可能相同，也可能不同，每个代表一个氢原子或一个甲基基团。n为1或2。
• Trifunctional unsaturated compounds and derivatives thereof
  申请人：UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

  公开号：EP0481476A2

  公开（公告）日：1992-04-22

  Novel trifunctional unsaturated compounds and mixtures thereof and their derivatives as well as a method for preparing the unsaturated compounds from unsaturated anhydrides and unsaturated alcohols. The unsaturated compounds are used to prepare novel cycloaliphatic epoxide compositions that have utility as coatings, inks, sealants, and adhesives that can be cured under ambient conditions, by thermal means, and by radiation technology.

  新型三官能团不饱和化合物及其混合物和衍生物，以及用不饱和酸酐和不饱和醇制备不饱和化合物的方法。这些不饱和化合物可用于制备新型环脂族环氧化物组合物，该组合物可用作涂料、油墨、密封剂和粘合剂，可在环境条件下通过热力或辐射技术固化。
• ALICYCLIC EPOXY COMPOUND AND METHOD FOR PRODUCING SAME
  申请人：Daicel Corporation

  公开号：EP2891652A1

  公开（公告）日：2015-07-08

  Provided is a novel epoxide that is highly soluble in organic solvents, is lowly volatile, contains a highly reactive epoxy group, and still resists polymerization by itself. The cycloaliphatic epoxide according to the present invention is a cycloaliphatic epoxide represented by Formula (1) : where R1 to R11 are each independently selected from hydrogen and C1-C4 straight or branched chain alkyl; and Ra represents C8-C23 branched chain alkyl. Ra is preferably C8-C17 branched chain alkyl.

  本发明提供了一种新型环氧化物，该环氧化物在有机溶剂中的溶解度高，挥发性低，含有高活性环氧基团，并且自身仍能抗聚合。 本发明的环脂族环氧化物是由式（1）表示的环脂族环氧化物： 其中 R1 至 R11 各自独立地选自氢和 C1-C4 直链或支链烷基；Ra 代表 C8-C23 支链烷基。Ra 最好是 C8-C17 支链烷基。
• Epoxy-oxetane compound, method for synthesizing same, and use of said compound
  申请人：SHIKOKU CHEMICALS CORPORATION

  公开号：US10913731B2

  公开（公告）日：2021-02-09

  The purpose of the present invention is to provide: a novel curable compound which can be expected to be used as a raw material for photocurable resins and thermosetting resins; a method for synthesizing said compound; a resin composition containing said compound; and a cured product thereof. This compound is an epoxy-oxetane compound represented by a formula, and this compound has a structure in which two epoxycyclohexyl groups (groups in which an oxirane ring and a cyclohexane ring are condensed) are bonded to an oxetane ring via a connector having one ether bond. In formula (I′), R1 to R3 may be the same as, or different from, each other, and each denote a hydrogen atom or a methyl group. n is 1 or 2.

  本发明的目的是提供：一种可用作光固化树脂和热固性树脂原料的新型可固化化合物；一种合成上述化合物的方法；一种含有上述化合物的树脂组合物；及其固化产品。该化合物是由式表示的环氧氧杂环丁烷化合物，该化合物具有这样的结构：两个环氧环己基（环氧乙烷环和环己烷环缩合的基团）通过具有一个醚键的连接体键合到氧杂环丁烷环上。在式(I′)中，R1 至 R3 可以彼此相同或不同，并各自表示氢原子或甲基。
• HAUFE, GUNTER;GIERSCHER, FRITZ;KOHLER, GUNTHER;SCHULZE, KLAUS, J. PRAKT. CHEM., 329,(1987) N 5, 817-823
  作者：HAUFE, GUNTER、GIERSCHER, FRITZ、KOHLER, GUNTHER、SCHULZE, KLAUS

  DOI：——

  日期：——