bis(perfluoro-2,5-dimethyl-3,6-dioxanonanoyl)peroxide | 133414-70-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: bis(perfluoro-2,5-dimethyl-3,6-dioxanonanoyl)peroxide
• 英文别名: perfluoro-2,5-dimethyl-3,6-dioxanonanoyl peroxide；perfluoro-2,5-dimethyl-3,6-dioxa-nonanoyl peroxide；Bis[1-oxo-2,5-bis(trifluoromethyl)undecafluoro-3,6-dioxanonane-1-yl] peroxide；[2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propanoyl] 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propaneperoxoate
• CAS: 133414-70-7
• 化学式: C₁₈F₃₄O₈
• 分子量: 990.139
• InChiKey: LEQCMDRIOPTEDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  60
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  42

反应信息

• 作为反应物：
  描述：

  2-[(4-氯苯基)氨基]萘-1,4-二酮 、 bis(perfluoro-2,5-dimethyl-3,6-dioxanonanoyl)peroxide 以 二氯甲烷 、 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 4.0h， 以50%的产率得到2-(4-chloroanilino)-3-(trifluoroacetyl)-1,4-naphthoquinone
  参考文献：
  名称：

  Perfluoroalkylquinones. Synthesis Using Bis(perfluoroalkanoyl) Peroxides, Absorption Bands, and Solubility

  摘要：

  1,4-苯并蒽醌、萘并蒽醌和 9,10-蒽醌与双（全氟烷酰基）过氧化物的反应生成了相应的全氟烷基化衍生物。2-甲基和 2-[4-(氯苯胺基)]-1,4-萘醌与双(氧代全氟烷酰基)过氧化物的反应分别产生了二氯甲基和三氟甲基衍生物。全氟烷基化萘醌和蒽醌染料的吸收带显示出轻微的低色移。全氟烷基化蒽醌染料在正己烷中的溶解度远高于非全氟烷基化蒽醌染料。

  DOI：

  10.1246/bcsj.68.1042

文献信息

• Synthesis of fluorine-containing organosilicon oligomers
  作者：Hideo Sawada、Masaharu Nakayama

  DOI：10.1039/c39910000677

  日期：——

  New fluorine-containing organosilicon oligomers, RF(CH2CHSiR3)xRFx= 2 or 3, RF= C3F7 or CF(CF3)[OCF2CF(CF3)]YOC3F7, y= 0 or 1; R = OMe or Me} were obtained by the reactions of fluoroalkanoyl peroxides with the corresponding vinylsilanes in excellent to moderate yields under very mild conditions.

  新型含氟有机硅低聚物 RF(CH2CHSiR3)xRFx= 2 或 3，RF= C3F7 或 CF(CF3)[OCF2CF(CF3)]YOC3F7，y= 0 或 1；R = OMe 或 Me}是在非常温和的条件下，通过氟烷酰过氧化物与相应的乙烯基硅烷反应获得的，产率从极好到中等。
• A polymer comprising fluoroalkyl group, a method of preparation thereof, a surface active agent, a surface treatment agent and a coating composition
  申请人：NOF CORPORATION

  公开号：EP0537669A1

  公开（公告）日：1993-04-21

  A polymer comprising fluoroalkyl group has a structure in which one or two parts of the fluoroalkyl group at the one or both ends of the molecule are linked to a part of alkylene groups or alkylene groups substituted with halogen, a part of alkylene group substituted with functional groups, such as halogen, cyano group, alkylsulfonic acid group, amidoalkylsulfonic acid group, carboxylic acid group, carboxyl group, oxycarbonyl group, ether group, epoxy group and the like, and/or a part of silicone group. A method of preparation of the polymer comprising fluoroalkyl group contains reaction of a fluoroalkanoyl peroxide with a monomer comprising the functional group or a monomer comprising silicone group. A surface active agent comprises fluoroalkyl group and caroxylic acid salt group. A surface treatment agent comprises the polymer comprising fluoroalkyl group, hydrolysis products thereof, hydrolytic condensation products thereof, and mixtures thereof. A coating composition comprises the polymer comprising fluoroalkyl group. The polymer comprising fluoroalkyl group has excellent water repellency, oil repellency and weatherability because the fluoroalkyl group is introduced into the molecule through carbon-carbon linkage.

  包含氟烷基的聚合物具有如下结构：分子一端或两端的氟烷基的一部分或两部分与亚烷基或被卤素取代的亚烷基的一部分、被官能团（如卤素、氰基、烷基磺酸基、氨基烷基磺酸基、羧酸基、羧基、氧羰基、醚基、环氧基等）取代的亚烷基的一部分和/或硅酮基的一部分相连接。包含氟烷基的聚合物的制备方法包括过氧化氟烷酰与包含官能团的单体或包含硅酮基的单体反应。一种表面活性剂包括氟烷基和甲酸盐基。表面处理剂包括含氟烷基的聚合物、其水解产物、水解缩合产物及其混合物。一种涂料组合物，包括含氟烷基的聚合物。含氟烷基的聚合物具有优异的防水性、防油性和耐候性，因为氟烷基是通过碳-碳连接引入分子中的。
• DENTAL POLYMERIZABLE COMPOSITION
  申请人：Kuraray Medical Inc.

  公开号：EP1787623A1

  公开（公告）日：2007-05-23

  A dental polymerizable composition comprising (a) a fluorine compound comprising a chain polymer having a main chain comprising a monomer unit having a hydrophilic group, and terminal groups comprising a fluoroalkyl group at each of both ends of the main chain; (b) a polymerizable monomer; and (c) a polymerization initiator. The dental polymerizable composition can be suitably used, for example, for dental composite resins, such as dental composite filler materials, crowning materials, and bonding materials; dental adhesive agents, such as teeth-straightening adhesive agents, cavity-coating adhesive agents, and tooth fissure sealing materials; denture base materials, denture base mucosal adjusting materials, fissure sealants, coating agents applied to tooth surface or dental prosthetic, surface glazes, and the like, and especially for various coating applications, for example, a fissure sealant, a coating agent to tooth surface or dental prosthetic, surface stains or a surface glaze, a hypersensitive inhibitor, a dental manicure, or the like.

  一种牙科可聚合组合物，包括(a)氟化合物，其链聚合物的主链由具有亲水基团的单体单元组成，末端基团包括位于主链两端的氟烷基；(b)可聚合单体；以及(c)聚合引发剂。牙科可聚合组合物可适当用于牙科复合树脂，例如牙科复合填充材料、牙冠材料和粘接材料；牙科粘接剂，例如牙齿矫正粘接剂、龋齿涂层粘接剂和牙缝密封材料；义齿基托材料、义齿基托粘膜调节材料、窝沟封闭剂、涂在牙齿表面或义齿上的涂层剂、表面釉料等，特别是用于各种涂层应用，例如窝沟封闭剂、涂在牙齿表面或义齿上的涂层剂、表面染色剂或表面釉料、超敏抑制剂、牙齿修整剂等。
• Synthesis of aromatic compounds containing perfluoro-oxa-alkyl groups
  作者：Hideo Sawada、Masaharu Nakayama

  DOI：10.1016/s0022-1139(00)80311-5

  日期：1991.1

  Perfluoro-oxa-alkanoyl peroxides[[C3F7O(CF(CF3)CF2O)nCF(CF3)CO2]2, n = 0, 1, 2] smoothly reacted with thiophene and furan under mild conditions to affor 2-perfluoro-oxa-alkylthiophenes and furnas in good yields. Perfluoro-oxa-alkylations of benzene and pyrrole were also found to proceed by the use of these peroxides. Furthermore, these peroxides were found to be applied to direct aromatic perfluoro-oxa-alkylations of polystyrene.
• Dental polymerizable composition
  申请人：Kuraray Noritake Dental Inc.

  公开号：EP1787623B1

  公开（公告）日：2014-03-26