8-(1,3-Dioxolan-2-yl)naphthalene-2-carboxylic acid | 489426-53-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-(1,3-Dioxolan-2-yl)naphthalene-2-carboxylic acid
• CAS: 489426-53-1
• 化学式: C₁₄H₁₂O₄
• 分子量: 244.247
• InChiKey: AQXYAJDSUCIDMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  8-(1,3-Dioxolan-2-yl)naphthalene-2-carboxylic acid 在 盐酸 、 caesium carbonate 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 生成 [4-[(8-Formylnaphthalene-2-carbonyl)oxymethyl]phenyl]methyl 8-formylnaphthalene-2-carboxylate
  参考文献：
  名称：

  Synthesis and binding behavior of a Zn(II)-porphyrin having calix[5]arene cap

  摘要：

  The synthesis and binding behavior of a Zn(II)-porphyrin having a calix[5]arene cap are presented. In order to synthesize such a bridged porphyrin, 5,15-bis(7-carboxy-1-naphthyl)-10,20-diphenylporphyrin having the syn arrangement of two naphthalene rings has been prepared. Amidation of the porphyrin and calix[5]arene having two amino functions and subsequent treatment of Zn(OAc)(2) gave a calix[5]arene capped Zn-porphyrin. Calix[5]arene-Zn-porphyrin was found to bind 4-methylpyridine much stronger than TPP-Zn. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01655-6
• 作为产物：
  描述：

  对甲基苯磺酸-2-萘酯 在 2,4,6-三甲基吡啶 、 palladium diacetate 、 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 lithium hydroxide 、 sodium hydroxide 、 氢气 、 溴 、 铁粉 、 对甲苯磺酸 、 三乙胺 、 三苯基膦 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 、 二氯甲烷 、 水 、 溶剂黄146 、 N,N-二甲基甲酰胺 、 苯 为溶剂， 生成 8-(1,3-Dioxolan-2-yl)naphthalene-2-carboxylic acid
  参考文献：
  名称：

  Synthesis and binding behavior of a Zn(II)-porphyrin having calix[5]arene cap

  摘要：

  The synthesis and binding behavior of a Zn(II)-porphyrin having a calix[5]arene cap are presented. In order to synthesize such a bridged porphyrin, 5,15-bis(7-carboxy-1-naphthyl)-10,20-diphenylporphyrin having the syn arrangement of two naphthalene rings has been prepared. Amidation of the porphyrin and calix[5]arene having two amino functions and subsequent treatment of Zn(OAc)(2) gave a calix[5]arene capped Zn-porphyrin. Calix[5]arene-Zn-porphyrin was found to bind 4-methylpyridine much stronger than TPP-Zn. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01655-6

文献信息

• Synthesis and binding behavior of a Zn(II)-porphyrin having calix[5]arene cap
  作者：Hajime Iwamoto、Yoshiko Yukimasa、Yoshimasa Fukazawa

  DOI：10.1016/s0040-4039(02)01655-6

  日期：2002.11

  The synthesis and binding behavior of a Zn(II)-porphyrin having a calix[5]arene cap are presented. In order to synthesize such a bridged porphyrin, 5,15-bis(7-carboxy-1-naphthyl)-10,20-diphenylporphyrin having the syn arrangement of two naphthalene rings has been prepared. Amidation of the porphyrin and calix[5]arene having two amino functions and subsequent treatment of Zn(OAc)(2) gave a calix[5]arene capped Zn-porphyrin. Calix[5]arene-Zn-porphyrin was found to bind 4-methylpyridine much stronger than TPP-Zn. (C) 2002 Elsevier Science Ltd. All rights reserved.