n-Dotriacontanyl acetate | 23811-94-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: n-Dotriacontanyl acetate
• 英文别名: dotriacontanyl acetate；acetic acid dotriacontyl ester；Essigsaeure-dotriacontylester；Essigsaeuredotriacontanylester；11-Dotriacontylacetat；Dotriacontanolacetat；dotriacontyl acetate
• CAS: 23811-94-1
• 化学式: C₃₄H₆₈O₂
• 分子量: 508.913
• InChiKey: RHYMLBTYRGLVEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.4
• 重原子数：
  36
• 可旋转键数：
  32
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  n-Dotriacontanoic acid methyl ester 在 吡啶 、 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 n-Dotriacontanyl acetate
  参考文献：
  名称：

  Kuwahara, Yasumasa, Agricultural and Biological Chemistry, 1980, vol. 44, # 6, p. 1297 - 1300

  摘要：

  DOI：

文献信息

• 8-Hydroxydotriacontan-30-one and other constituents from Duboisia myoporoides
  作者：Yogendra N. Shukla、Raghunath S. Thakur

  DOI：10.1016/s0031-9422(00)80500-2

  日期：1984.1
• Ovipositional Responses of <i>Chilo partellus</i> (Swinhoe) (Lepidoptera:  Pyralidae) to Natural Products from Leaves of Two Maize (<i>Zea mays</i> L.) Cultivars
  作者：Anupam K. Varshney、B. Ravindra Babu、Ashok K. Singh、Hari C. Agarwal、Subhash C. Jain

  DOI：10.1021/jf0211074

  日期：2003.7.1

  Ovipositional responses of Chilo partellus (Swinhoe) (Lepidoptera: Pyralidae) to hexane extracts of leaves of two maize (Zea mays L.) cultivars, one resistant (Kisan) and one susceptible (Basilocal), were studied in two-choice bioassays. Gravid females laid a significantly higher percentage of eggs on substrates smeared with extract of Basilocal leaves (HEBL) (69%) than on those smeared with extracts of Kisan leaves (HEKL) (31%). Several chemicals were isolated from HEKL, three of which were characterized as dotriacontanol, heptadecanol, and nonadecanol. These chemicals were either absent or were present in very small amounts in HEBL, but in HEKL they were detected in much larger amounts. Each isolated chemical was tested for its effect on C. partellus oviposition in two-choice bioassays. Maximum ovipositional deterrence (90%) was observed for the compound MR-22a, followed in decreasing order by nonadecanol, MR-7, and heptadecanol. The identity of the remaining compounds is being investigated. The results indicate that the relative resistance of Kisan maize compared to Basilocal is partly due to the presence of certain ovipositional deterrents in its leaves.
• STEPHANOU, EURIPIDES G., FRESENIUS J. ANAL. CHEM., 339,(1991) N0, C. 780-784
  作者：STEPHANOU, EURIPIDES G.

  DOI：——

  日期：——
• Kuwahara, Yasumasa, Agricultural and Biological Chemistry, 1980, vol. 44, # 6, p. 1297 - 1300
  作者：Kuwahara, Yasumasa

  DOI：——

  日期：——