triethyl 1,3-diphenyl-1,2,2-propanetricarboxylate | 104958-18-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: triethyl 1,3-diphenyl-1,2,2-propanetricarboxylate
• 英文别名: triethyl 1,3-diphenylpropane-1,2,2-tricarboxylate；1,3-diphenyl-propane-1,2,2-tricarboxylic acid triethyl ester；1,3-Diphenyl-propan-1,2,2-tricarbonsaeure-triaethylester；triethyl 1-benzyl-2-phenylethane-1,1,2-tricarboxylate
• CAS: 104958-18-1
• 化学式: C₂₄H₂₈O₆
• 分子量: 412.483
• InChiKey: VMEYTTUOXJKDDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.69
• 重原子数：
  30.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  78.9
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  triethyl 1,3-diphenyl-1,2,2-propanetricarboxylate 在 氢氧化钾 作用下， 以 1,4-二氧六环 、 水 、 乙二醇 为溶剂， 反应 10.0h， 以73%的产率得到erythro-(1R^*,2R^*)-1,3-diphenylpropane-1,2-dicarboxylic acid
  参考文献：
  名称：

  Maslennikova, L. V.; Sladkov, V. I.; Suvorov, N. N., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 2.2, p. 377 - 380

  摘要：

  DOI：
• 作为产物：
  描述：

  α-溴苯乙酸乙酯 、 苄基丙二酸二乙酯 在 乙醇 、 sodium ethanolate 作用下， 生成 triethyl 1,3-diphenyl-1,2,2-propanetricarboxylate
  参考文献：
  名称：

  Koegl; Becker, Justus Liebigs Annalen der Chemie, 1928, vol. 465, p. 212,232

  摘要：

  DOI：

文献信息

• Sladkov, V. I.; Maslennikova, L. V.; Suvorov, N. N., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, # 12, p. 2373 - 2378
  作者：Sladkov, V. I.、Maslennikova, L. V.、Suvorov, N. N.

  DOI：——

  日期：——
• EPR dose reconstruction of two Kazakh villages near the Semipalatinsk nuclear test site
  作者：A. A. Romanyukha、M. Desrosiers、O. Sleptchonok、C. Land、N. Luckyanov、B. I. Gusev

  DOI：10.1007/bf03166116

  日期：2002.9

  Electron paramagnetic resonance (EPR) dose reconstruction has been performed on archived tooth samples from residents of two villages near the Semipalatinsk nuclear test site in Kazakstan. The context of this work is a large multidisciplinary study of thyroid disease prevalence and radiation dose among long-term residents of villages near that nuclear test site, in which EPR is used for biodosimetric validation of the gamma-ray component of dose reconstruction algorithms applied to the data for various villages whose residents were exposed to radioactive fallout during 1949-1962, the period of above-ground atomic bomb testing. The tooth samples, nine from the village of Kainar and 23 from the village of Znamenka, were extracted in 1964 and 1967, respectively, and stored indoors in closed boxes in Semipalatinsk. According to provided information, some time in the past, the teeth from Kainar were heated to 80degreesC for one day. Experiments carried out on 12 teeth from US sources to determine the effects of long-term storage and heat treatment found that EPR assay findings were not compromised for storage times less than 35 years and annealing at temperatures below 200degreesC. For tooth enamel samples prepared from molars and premolars the average reconstructed gamma dose was 390 +/- 70 mGy for Kainar residents and 95 +/- 40 mGy for Znamenka residents.
• MASLENNIKOVA, L. V.;SLADKOV, V. I.;SUVOROV, N. N., ZH. ORGAN. XIMII, 26,(1990) N, S. 441-445
  作者：MASLENNIKOVA, L. V.、SLADKOV, V. I.、SUVOROV, N. N.

  DOI：——

  日期：——
• SLADKOV, V. I.;MASLENNIKOVA, L. V.;SUVOROV, N. N., ZH. ORGAN. XIMII, 1985, 21, N 12, 2594-2600
  作者：SLADKOV, V. I.、MASLENNIKOVA, L. V.、SUVOROV, N. N.

  DOI：——

  日期：——