N,N'-bis-n-propyl-1,6,7,12-tetrakis(4-n-butyloxyphenoxy)perylene-3,4,9,10-tetracarboxdiimide | 1234347-63-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis-n-propyl-1,6,7,12-tetrakis(4-n-butyloxyphenoxy)perylene-3,4,9,10-tetracarboxdiimide
• 英文别名: 11,14,22,26-Tetrakis(4-butoxyphenoxy)-7,18-dipropyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone；11,14,22,26-tetrakis(4-butoxyphenoxy)-7,18-dipropyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone
• CAS: 1234347-63-7
• 化学式: C₇₀H₇₀N₂O₁₂
• 分子量: 1131.33
• InChiKey: SHXRLCNAKLWIFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.5
• 重原子数：
  84
• 可旋转键数：
  28
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  149
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  N,N'-bis-n-propyl-1,6,7,12-tetrakis(4-n-butyloxyphenoxy)perylene-3,4,9,10-tetracarboxdiimide 在 potassium hydroxide 作用下， 以 水 、 异丙醇 为溶剂， 反应 24.0h， 以80%的产率得到1,6,7,12-tetrakis(4-n-butyloxyphenoxy)perylene-3,4,9,10-tetracarboxylic acid dianhydride
  参考文献：
  名称：

  Synthesis and Optical Properties ofn-Type Polymers Containing Perylene Moieties

  摘要：

  Three n-type polymers, Ppe01, Ppe02, and Ppe03, containing both perylene moieties and fluorine atoms were synthesized. The synthesiszed polymeric perylene derivatives with good compatibility for solution processes were chosen as new acceptor candidates for substitution of C-60 derivatives in poly(3-hexylthiophene)-based organic photovoltaic application, by considering the results based on good thermal stability, high electron affinity ranging from 3.81 to 3.96 eV, absorption property in visible region, and effective photoluminescence quenching in the blend films with P3HT. The potential of the synthesized perylene polymers was investigated by measuring the current-voltage property of the polymeric P3HT: Ppe01 OPV device.

  DOI：

  10.1080/15421406.2010.497101
• 作为产物：
  描述：

  2,9-二丙基-蒽并2,1,9-def:6,5,10-d'e'f'二异喹啉-1,3,8,10-四酮 在 磺酰氯 、 碘苯 、 碘 、 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 、 硝基苯 为溶剂， 反应 26.0h， 生成 N,N'-bis-n-propyl-1,6,7,12-tetrakis(4-n-butyloxyphenoxy)perylene-3,4,9,10-tetracarboxdiimide
  参考文献：
  名称：

  Synthesis and Optical Properties ofn-Type Polymers Containing Perylene Moieties

  摘要：

  Three n-type polymers, Ppe01, Ppe02, and Ppe03, containing both perylene moieties and fluorine atoms were synthesized. The synthesiszed polymeric perylene derivatives with good compatibility for solution processes were chosen as new acceptor candidates for substitution of C-60 derivatives in poly(3-hexylthiophene)-based organic photovoltaic application, by considering the results based on good thermal stability, high electron affinity ranging from 3.81 to 3.96 eV, absorption property in visible region, and effective photoluminescence quenching in the blend films with P3HT. The potential of the synthesized perylene polymers was investigated by measuring the current-voltage property of the polymeric P3HT: Ppe01 OPV device.

  DOI：

  10.1080/15421406.2010.497101

文献信息

• Synthesis and Optical Properties of<i>n</i>-Type Polymers Containing Perylene Moieties
  作者：Ki-Soo Kim、Seonju Jeong、Cham Kim、Hoyoung Kim、Yu Suk Yang、Jae Hong Kim、Younghwan Kwon、Weon-Pil Tai、Yoon Soo Han

  DOI：10.1080/15421406.2010.497101

  日期：2010.10.18

  Three n-type polymers, Ppe01, Ppe02, and Ppe03, containing both perylene moieties and fluorine atoms were synthesized. The synthesiszed polymeric perylene derivatives with good compatibility for solution processes were chosen as new acceptor candidates for substitution of C-60 derivatives in poly(3-hexylthiophene)-based organic photovoltaic application, by considering the results based on good thermal stability, high electron affinity ranging from 3.81 to 3.96 eV, absorption property in visible region, and effective photoluminescence quenching in the blend films with P3HT. The potential of the synthesized perylene polymers was investigated by measuring the current-voltage property of the polymeric P3HT: Ppe01 OPV device.