Zn(1-(4',5,5'-trimethyl-2,2'-bi-1,3-dithiol-4-yl)butane-2,4-dionate)2(C5H5N)2 | 1094040-51-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Zn(1-(4',5,5'-trimethyl-2,2'-bi-1,3-dithiol-4-yl)butane-2,4-dionate)2(C5H5N)2
• 英文别名: Zn(TTFSacac)2(C5H5N)2
• CAS: 1094040-51-3
• 化学式: C₃₆H₃₆N₂O₄S₈Zn
• 分子量: 882.611
• InChiKey: ZOAAQCSSJUPBSD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-(4',5,5'-trimethyl-2,2'-bi-1,3-dithiol-4-yl)butane-2,4-dione 以 四氢呋喃 、 吡啶 、 甲醇 为溶剂， 生成 Zn(1-(4',5,5'-trimethyl-2,2'-bi-1,3-dithiol-4-yl)butane-2,4-dionate)2(C5H5N)2
  参考文献：
  名称：

  Chelating ability of a conjugated redox active tetrathiafulvalenyl-acetylacetonate ligand

  摘要：

  A novel tetrathiafulvalene (TTF) bearing a conjugated beta-diketone moiety (TTFacacH) has been synthesized and fully characterized. The chelating ability of its enolate anion (TTFacac) has been investigated with [M-II(OAc)(2)center dot xH(2)O](OAc = acetate and M = Zn, Cu and Ni) leading to complexes, where the metal center is coordinated by two TTFacac. Modulation of the redox properties of the TTF can be achieved through the simple change of the two apical ligands which completed the octahedral coordination geometry. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.07.003