[Ru(III)(ethylenebis(salicylimine))(cyanide)2][Ni(II)(1,4,8,11-tetraazacyclotetradecane)](perchlorate)*(water)*(acetonitrile) | 914102-95-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Ru(III)(ethylenebis(salicylimine))(cyanide)2][Ni(II)(1,4,8,11-tetraazacyclotetradecane)](perchlorate)*(water)*(acetonitrile)
• CAS: 914102-95-7
• 化学式: C₂H₃N*C₂₈H₃₈N₈NiO₂Ru*ClO₄*H₂O
• 分子量: 836.941
• InChiKey: NMCSYJRAGZEEDD-GYIUUBFTSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,4,8,11-tetraazacyclotetradecane)nickel(II) perchlorate 、 sodium[ruthenium(III)(ethylenebis(salicylimine))(cyanide)2]*1.5(water) 、 水 、 乙腈 以 水 、 乙腈 为溶剂， 生成 [Ru(III)(ethylenebis(salicylimine))(cyanide)2][Ni(II)(1,4,8,11-tetraazacyclotetradecane)](perchlorate)*(water)*(acetonitrile)
  参考文献：
  名称：

  Magnetic and structural properties of a cyano-bridged 1D ruthenium(III)–nickel(II) coordination polymer

  摘要：

  Reaction of [Ni(cyclam)](ClO4)(2) (cyclam = 1,4,8,1 1-tetraazacyclotetradecane) with Na[Ru(salen)(CN)(2)] (2) (salen = ethylenebis(salicylimine)) generated the ID coordination polymer [Ru(III)(salen)(CN)(2)][Ni(II)(cyclam)](ClO4) (1). X-ray diffraction studies of 1 revealed a structure consisting of alternating Ni(II) and Ru(III) ions bridged by cyanide ligands. The cyano C-terminus remained bound to the Ru(III) center while the perchlorate anion induced a deviation from linearity along the Ru-CN-Ni axis. Structural characterization of 2 disclosed a 2D framework where the sodium counterions bridge between [Ru(salen)(CN)(2)] units. Magnetic measurements of I indicate ferromagnetic coupling between Ni(II) and Ru(III) with no long-range magnetic order above 3 K. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.024