1,11-bis-diazo-undecane-2,10-dione | 69703-80-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,11-bis-diazo-undecane-2,10-dione
• 英文别名: 1,11-Bis-diazo-undecan-2,10-dion；1,11-Didiazoundecane-2,10-dione
• CAS: 69703-80-6
• 化学式: C₁₁H₁₆N₄O₂
• 分子量: 236.274
• InChiKey: VYNKVSSWBVJTKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  38.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,11-bis-diazo-undecane-2,10-dione 在 盐酸 、 氯仿 作用下， 生成 1,11-dichloro-undecane-2,10-dione
  参考文献：
  名称：

  Erlenmeyer; Buechler, Helvetica Chimica Acta, 1946, vol. 29, p. 1924,1927

  摘要：

  DOI：
• 作为产物：
  描述：

  重氮甲烷 、 壬二酰氯 以 乙醚 为溶剂， 生成 1,11-bis-diazo-undecane-2,10-dione
  参考文献：
  名称：

  Fahr,E., Justus Liebigs Annalen der Chemie, 1960, vol. 638, p. 1 - 32

  摘要：

  DOI：

文献信息

• Synthesis of some medium- and large-ring cycloalk-2-ene-1,4-diones by intramolecular coupling of αω-bis-diazoketones
  作者：Sunanta Kulkowit、M. Anthony McKervey

  DOI：10.1039/c39780001069

  日期：——

  In the presence of Cu(acac)2(Hacac = acetylacetone) some αω-bis-diazoketones couple intramolecularly with loss of nitrogen giving cycloalk-2-ene-1,4-diones; the enediones can be converted into fused ring cyclopentenones by successive treatment with sodium dithionite and sodium hydroxide.

  在Cu（acac）2（Hacac =乙酰丙酮）存在下，一些αω-双-二重氮酮在分子内与氮的损失偶合，得到环烷-2-烯-1,4-二酮；通过连二亚硫酸钠和氢氧化钠的连续处理，可将二烯酮转化为稠环环戊烯酮。
• A New General Route to Thiophenophanes:  Synthesis and Properties of [<i>n</i>](2,5)Thiophenophane-1,<i>n</i>-diones
  作者：Yuji Miyahara

  DOI：10.1021/jo060889n

  日期：2006.8.1

  A series of [ n]( 2,5) thiophenophane-1, n-diones ( 5) ( n = 9, 10, 12, 14, 16, and 20) were synthesized in a simple four-step route starting from the appropriate 1,omega-oligomethylenedicarboxylic acids. The bis-( halomethylketones) ( 6), which were obtained by successive treatment of the diacids with SOCl2, diazomethane, and HBr or HCl, were cyclized by Na2S under high dilution conditions. The obtained monomeric cyclic diketosulfides ( 4) were condensed with glyoxal in MeOH by slowly adding dilute NaOMe affording 5. The thiophene-2,5-dicarbonyl moiety of 5 ( n = 9) is significantly deformed as shown by X-ray crystallography, and the effect of the strain is reflected in the C=O stretching frequencies and the pi-pi* and the n-pi* absorptions.
• Canonica; Bacchetti, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1951, vol. <8>10, p. 479,484
  作者：Canonica、Bacchetti

  DOI：——

  日期：——
• Regiospecific synthesis of α-(phenylthio)ketones via rhodium(II) acetate catalysed addition of thiophenol to α-diazoketones
  作者：M. Anthony McKervey、Piniti Ratananukul

  DOI：10.1016/s0040-4039(00)87382-7

  日期：1982.1
• Schubert,H. et al., Journal fur praktische Chemie (Leipzig 1954), 1964, vol. 24, p. 132 - 142
  作者：Schubert,H. et al.

  DOI：——

  日期：——