nitrido{bis-N,N'-(salicylaldehyde)ethylenediiminato}chromium(V) | 80711-18-8

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: nitrido{bis-N,N'-(salicylaldehyde)ethylenediiminato}chromium(V)
• 英文别名: [chromium(V)(N)(2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate]；[Cr(N)salen)]
• CAS: 80711-18-8
• 化学式: C₁₆H₁₄CrN₃O₂
• 分子量: 332.302
• InChiKey: DDZMDTLLCLNTRV-SNTCFBDDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  nitrido{bis-N,N'-(salicylaldehyde)ethylenediiminato}chromium(V) 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 二氯甲烷 为溶剂， 以69%的产率得到chlorido-2κCl-[2(η4)-1,5-cyclooctadiene](2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ4O,N,N',O')-μ-nitrido-1:2κ2N:N-chromium(V)rhodium(I)
  参考文献：
  名称：

  Synthesis and molecular structure of Cr(salen)(μ-N)RhCl(COD): the first example of a heterobimetallic nitride-bridged complex containing chromium

  摘要：

  Five-coordinate Cr(N)(salen) {salen is 2,2 '-[ethane-1,2-diylbis-(nitrilomethylidyne)]diphenolate} reacts with [RhCl(COD)](2) (COD is 1,5-cyclooctadiene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2 kappa Cl-[2(eta(4))-1,5-cyclooctadiene]{2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]-diphenolato-1 kappa O-4,N,N ',O '}-mu-nitrido-1:2 kappa N-2:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C8H12)]. The Cr-N bond of 1.5936 (14) angstrom is elongated by only 0.035 angstrom compared to the terminal Cr-N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)degrees] and the Rh-N bond of 1.9594 ( 14) angstrom is very short for a monodentate nitrogen-donor ligand, indicating significant pi-acceptor character of the Cr N group.

  DOI：

  10.1107/s0108270110018238
• 作为产物：
  描述：

  Na[Cr(N,N'-bis(salicylidene)ethyleneiminate)(N3)2] 以 乙腈 为溶剂， 生成 nitrido{bis-N,N'-(salicylaldehyde)ethylenediiminato}chromium(V)
  参考文献：
  名称：

  Azuma, Nagao; Imori, Yohko; Yoshida, Hironobu, Inorganica Chimica Acta, 1997, vol. 266, # 1, p. 29 - 36

  摘要：

  DOI：

文献信息

• Heterobimetallic Nitride Complexes from Terminal Chromium(V) Nitride Complexes: Hyperfine Coupling Increases with Distance
  作者：Jesper Bendix、Christian Anthon、Magnus Schau-Magnussen、Theis Brock-Nannestad、Johan Vibenholt、Muniza Rehman、Stephan P. A. Sauer

  DOI：10.1002/anie.201008153

  日期：2011.5.2

  stronger: Terminal chromium(V) nitride complexes (see picture) react with low‐valent platinum‐metal complexes as well as with main‐group Lewis acids to yield nitride‐bridged systems. Rigorous fitting of the EPR data shows that the superhyperfine coupling of the chromium(V) center with the 14N nuclear spin approximately doubles in response to the formation of a CrN bridge. This effect also exists in computations

  更长，更强：末端铬（V）氮化物络合物（见图）与低价铂金属络合物以及主路易斯酸反应生成氮化物桥接体系。EPR数据的严格拟合表明，铬（V）中心与14 N核自旋的超超精细偶联响应于CrN桥的形成而近似加倍。在假定CrN键加长的计算中也存在这种效应。
• The preparation of nitridomanganese and nitridochromium macrocyclic complexes by complete intermetal nitrogen atom transfer from nitridomanganese octaethylporphyrin
  作者：Frank L. Neely、Lawrence A. Bottomley

  DOI：10.1016/s0020-1693(00)80751-3

  日期：1992.2

  Atom transfer reactions involve the net transfer of an atom and one or more electrons from a donor molecule to an acceptor [l]. Over the past two decades, metal-centered oxygen atom transfer reactions have been intensively studied. Oxygen atom transfer from M=O containing donor complexes to olefins, paraffins and other substrates has been achieved and a consistent mechanistic picture is beginning to

  原子转移反应涉及原子和一个或多个电子从供体分子到受体的净转移[1]。在过去的二十年中，对以金属为中心的氧原子转移反应进行了深入研究。氧原子已从含M = O的供体配合物转移至烯烃，石蜡和其他底物，并且已经出现了一致的机理图[2]。相对较少的非氧杂原子转移的例子已有报道。在大多数情况下，这种转移是不完全的，即原子被供体金属和受体基团共享。霍尔姆已经描述了这种类型的配合物作为部分原子转移的例子[1]。