undeca-1,10-dien-4-yn-6-ol | 538373-84-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: undeca-1,10-dien-4-yn-6-ol
• CAS: 538373-84-1
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: GOXBNEBJIPGFGK-UHFFFAOYSA-N

物化性质

• 沸点：
  251.4±35.0 °C(Predicted)
• 密度：
  0.904±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  undeca-1,10-dien-4-yn-6-ol 在 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 反应 18.0h， 以79%的产率得到undeca-1,10-dien-7-yn-6-one
  参考文献：
  名称：

  A General Approach to Medium Ring Alkynes by Using Metathesis of Cobalt Hexacarbonyl Containing Dienes

  摘要：

  The assembly of medium sized rings (7-9) was achieved by using the metathesis of dienes linked by a cobalt hexacarbonyl complexed alkyne with either Grubbs' or Schrock's catalysts. The products of metathesis were subjected to transformations involving the dicobalt hexacarbonyl complexes, for example, decomplexation to liberate cyclic alkynes or Pauson-Khand reaction.

  DOI：

  10.1021/jo030011l
• 作为产物：
  描述：

  1-(Trimethylsilyl)oct-7-en-1-yn-3-ol 在 氢氧化钾 、 甲基溴化镁 作用下， 以 四氢呋喃 、 甲醇 、 乙醚 为溶剂， 反应 26.0h， 生成 undeca-1,10-dien-4-yn-6-ol
  参考文献：
  名称：

  A General Approach to Medium Ring Alkynes by Using Metathesis of Cobalt Hexacarbonyl Containing Dienes

  摘要：

  The assembly of medium sized rings (7-9) was achieved by using the metathesis of dienes linked by a cobalt hexacarbonyl complexed alkyne with either Grubbs' or Schrock's catalysts. The products of metathesis were subjected to transformations involving the dicobalt hexacarbonyl complexes, for example, decomplexation to liberate cyclic alkynes or Pauson-Khand reaction.

  DOI：

  10.1021/jo030011l

文献信息

• A General Approach to Medium Ring Alkynes by Using Metathesis of Cobalt Hexacarbonyl Containing Dienes
  作者：David G. J. Young、Joseph A. Burlison、Ulf Peters

  DOI：10.1021/jo030011l

  日期：2003.5.1

  The assembly of medium sized rings (7-9) was achieved by using the metathesis of dienes linked by a cobalt hexacarbonyl complexed alkyne with either Grubbs' or Schrock's catalysts. The products of metathesis were subjected to transformations involving the dicobalt hexacarbonyl complexes, for example, decomplexation to liberate cyclic alkynes or Pauson-Khand reaction.