2,3-Dichloroanthracene-1,4-dione | 14681-17-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3-Dichloroanthracene-1,4-dione
• 英文别名: 2,3-dichloro-1,4-anthracenedione；2,3-dichloro-1,4-anthraquinone；2,3-Dichlor-anthrachinon-(1,4)；2,3-Dichlor-1,4-anthrachinon；Dichlor-1.4-anthrachinon
• CAS: 14681-17-5
• 化学式: C₁₄H₆Cl₂O₂
• 分子量: 277.106
• InChiKey: VPPOIATZCIIXJD-UHFFFAOYSA-N

物化性质

• 沸点：
  406.4±45.0 °C(Predicted)
• 密度：
  1.53±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3-Dichloroanthracene-1,4-dione 在 potassium carbonate 作用下， 以 乙醇 、 丙酮 为溶剂， 反应 5.0h， 生成 2,3-Dicyano-1,4-dimethoxyanthracene
  参考文献：
  名称：

  The synthesis of a symmetrically substituted α-octa(isopentoxy)anthralocyanine

  摘要：

  我们合成了δ-八（异戊氧基）蒽花青素，发现它具有前所未有的低能量 Q 波段吸收和较低的第一氧化电位。

  DOI：

  10.1039/a703454g
• 作为产物：
  描述：

  1,4-蒽醌 在 氯 作用下， 以 溶剂黄146 为溶剂， 生成 2,3-Dichloroanthracene-1,4-dione
  参考文献：
  名称：

  The synthesis of a symmetrically substituted α-octa(isopentoxy)anthralocyanine

  摘要：

  我们合成了δ-八（异戊氧基）蒽花青素，发现它具有前所未有的低能量 Q 波段吸收和较低的第一氧化电位。

  DOI：

  10.1039/a703454g

文献信息

• Structure engineering: extending the length of azaacene derivatives through quinone bridges
  作者：Zilong Wang、Zongrui Wang、Yecheng Zhou、Peiyang Gu、Guangfeng Liu、Kexiang Zhao、Lina Nie、Qingsheng Zeng、Jing Zhang、Yongxin Li、Rakesh Ganguly、Naoki Aratani、Li Huang、Zheng Liu、Hiroko Yamada、Wenping Hu、Qichun Zhang

  DOI：10.1039/c8tc00628h

  日期：——

  A novel quinone bridged large azaacene exhibits an electron mobility of 0.22 cm² V⁻¹ s⁻¹ through molecular stacking structure engineering.

  一种新型的喹喔醌桥联的大型氮杂芳烃通过分子堆积结构工程展现出0.22 cm² V⁻¹ s⁻¹的电子迁移率。
• Quinone-Based, Redox-Active Resorcin[4]arene Cavitands
  作者：Igor Pochorovski、Corinne Boudon、Jean-Paul Gisselbrecht、Marc-Olivier Ebert、W. Bernd Schweizer、François Diederich

  DOI：10.1002/anie.201106031

  日期：2012.1.2

  Catch it if you can! Redox‐active resorcin[4]arene cavitands with quinone walls can be reversibly reduced to the hydroquinone form, influencing their host–guest complexation strength. Specifically, a top‐covered triptycenequinone cavitand forms kinetically stable complexes with cycloalkanes; this complexation is weaker in the reduced hydroquinone form.

  如果可以的话赶上它！具有醌壁的氧化还原活性间苯二酚[4]芳烃空洞可被可逆地还原为对苯二酚形式，影响它们的主客体络合强度。特别是，顶部覆盖的三烯醌卡维酮与环烷烃形成动力学稳定的络合物。在还原的对苯二酚形式中，这种络合作用较弱。
• Imaging film and film-forming composition, method for recording electromagnetic radiation, quinone compounds and method of synthesizing quinone compounds
  申请人：ENERGY CONVERSION DEVICES, INC.

  公开号：EP0098020A2

  公开（公告）日：1984-01-11

  Imaging films and film-forming compositions are provided which include a reducible tellurium compound, a reductant precursor, a source of labile hydrogen incorporated in a matrix. The reductant precursors are of the formulae or where Y1 is alkoxy, Y2 is chloro or alkoxy and Y3 is hydrogen, chloro or alkoxy. Methods are provided for synthesizing the reductant precursors.

  提供了成像薄膜和成膜组合物，其中包括一种可还原的碲化合物、一种还原剂前体、一种结合在基质中的易变氢源。 还原剂前体的式子为 Y1 是烷氧基，Y2 是氯或烷氧基，Y3 是氢、氯或烷氧基。 提供了合成还原剂前体的方法。
• Process for the production of an aromatic hydrazo compound
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0391606A1

  公开（公告）日：1990-10-10

  A process for the production of an aromatic hydrazo compound, which comprises carrying out catalytic reduction of an aromatic nitro compound with hydrogen in an alkali metal hydroxide aqueous solution in the presence of a noble metal catalyst at a high temperature under a high pressure, wherein the catalytic reduction is carried out by using, as a hydrogen-donating solvent, a cyclic hydrocarbon formed of 1 to 4 aromatic rings as a basic skeleton and having hydrogen atoms attached to at least two places of the aromatic ring(s).

  一种芳香族偶氮化合物的生产工艺，包括在高温高压下，在贵金属催化剂存在下，在碱金属氢氧化物水溶液中用氢气对芳香族硝基化合物进行催化还原，其中催化还原是通过使用由 1 至 4 个芳香环形成的环状烃作为基本骨架，并在芳香环的至少两处连接有氢原子作为供氢溶剂来进行的。
• Syntheses, electrochemistry and molecular modeling of N,N′-dicyanoquinonediimine (DCNQI) derivatives of substituted 1,4-anthracenediones: precursors for organic metals.
  作者：Elena Barranco、Nazario Martín、José L. Segura、Carlos Seoane、Pilar de la Cruz、Fernando Langa、Araceli Gonzalez、José M. Pingarrón

  DOI：10.1016/s0040-4020(01)80405-1

  日期：1993.5

  The title compounds (10) have been obtained from the corresponding 1,4-anthracenedione derivatives (3), prepared by different synthetic routes, by reaction with bis(trimethylsilyl)carbodiimide (BTC). The cyclic voltammetry of these compounds (3 and 10) reveals the presence of two reduction waves to the corresponding anion-radical and dianion. The acceptor ability of compounds 10 can be modulated by the presence of substituents on the DCNQI ring. The syn/anti isomers have been studied by molecular mechanics and the results are in good agreement with the H-1-NMR high resolution spectral data.