1-(2-乙基己基)吲哚 | 836682-40-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 1-(2-乙基己基)吲哚
• 英文名称: 1-(2-ethylhexyl)-1H-indole
• 英文别名: 1-(2-ethylhexyl)indole
• CAS: 836682-40-7
• 化学式: C₁₆H₂₃N
• mdl: MFCD19011441
• 分子量: 229.365
• InChiKey: BUIHQQHBTMFKCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-(2-乙基己基)吲哚 、 propionic acid 2-{(2-cyano-ethyl)-[4-(2-hydroxy-3,4-dioxo-cyclobut-1-enyl)-phenyl]-amino}-ethyl ester 以 甲苯 、 正丁醇 为溶剂， 反应 12.0h， 生成 (4Z)-2-[4-[2-cyanoethyl(2-propanoyloxyethyl)amino]phenyl]-4-[1-(2-ethylhexyl)indol-1-ium-3-ylidene]-3-oxocyclobuten-1-olate
  参考文献：
  名称：

  CORE-SHELL COMPOUND, PHOTOSENSITIVE RESIN COMPOSITION INCLUDING THE SAME, PHOTOSENSITIVE RESIN LAYER, COLOR FILTER AND CMOS IMAGE SENSOR

  摘要：

  一种核壳化合物，包括该核壳化合物的光敏树脂组合物，使用该光敏树脂组合物制造的光敏树脂层，包括该光敏树脂层的彩色滤光片以及包括该彩色滤光片的CMOS图像传感器，该核壳化合物包括一个包含三个或更多(meth)丙烯酸酯基团的方芘核心和包围方芘核心的壳层。

  公开号：

  US20220204775A1
• 作为产物：
  描述：

  吲哚 、 亚磷酸三(2-乙基己基)酯 在 4-硝基甲苯 作用下， 反应 5.0h， 以38%的产率得到1-(2-乙基己基)吲哚
  参考文献：
  名称：

  Efficient synthesis of N-alkyl-2,7-dihalocarbazoles by simultaneous carbazole ring closure and N-alkylation

  摘要：

  The N-alkyl-2,7-dihalocarbazole as the main product was formed by the reaction of 4,4'-dihalo-2-nitrobiphenyl with aromatic nitro compound and trialkyl phosphite. The presence and crucial role of aromatic nitro compound causes simultaneous carbazole ring closure and N-alkylation unlike the Ca-dogan ring closure where non-alkylated carbazole is formed as a main product. In addition, the mixture of aromatic nitro compound and trialkyl phosphite was found to be a possible N-alkylating agent for heterocycles, such as carbazole or indole. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.04.044

文献信息

• Bis resorcinyl triazine derivatives as protecting agents against UV radiation
  申请人：ISDIN, S.A.

  公开号：EP2210887A1

  公开（公告）日：2010-07-28

  The present invention relates to new compounds of general formula (I) where R1 is a ring system containing C and N, being at least one of them different from C; optionally being substituted; R2 and R2' are radicals, same or different, independently selected from linear or branched (C1-C4)alkyl, and-O-(C1-C4)alkyl; R3 and R3' are radicals, same or different, independently selected from hydrogen, (C1-C18)acyl radical, linear or branched (C1-C18)alkyl, and linear or branched (C2-C18)alkenyl; wherein the radical is optionally substituted. The physicochemical properties of said compounds allow them to be used as protecting agents against UV radiation.

  本发明涉及一般式为（I）的新化合物，其中R1是含有C和N的环系统，其中至少一个不同于C；可选地被取代；R2和R2'是基团，相同或不同，独立地选自线性或支链（C1-C4）烷基和-O-（C1-C4）烷基；R3和R3'是基团，相同或不同，独立地选自氢、（C1-C18）酰基基团、线性或支链（C1-C18）烷基和线性或支链（C2-C18）烯基；其中该基团可选地被取代。所述化合物的物理化学性质使它们能够用作防护剂来对抗紫外线辐射。
• KR2023/13508
  申请人：——

  公开号：——

  公开（公告）日：——
• US2023/2618
  申请人：——

  公开号：——

  公开（公告）日：——
• Efficient synthesis of N-alkyl-2,7-dihalocarbazoles by simultaneous carbazole ring closure and N-alkylation
  作者：Drahomír Výprachtický、Ivan Kmínek、Veronika Pokorná、Věra Cimrová

  DOI：10.1016/j.tet.2012.04.044

  日期：2012.6

  The N-alkyl-2,7-dihalocarbazole as the main product was formed by the reaction of 4,4'-dihalo-2-nitrobiphenyl with aromatic nitro compound and trialkyl phosphite. The presence and crucial role of aromatic nitro compound causes simultaneous carbazole ring closure and N-alkylation unlike the Ca-dogan ring closure where non-alkylated carbazole is formed as a main product. In addition, the mixture of aromatic nitro compound and trialkyl phosphite was found to be a possible N-alkylating agent for heterocycles, such as carbazole or indole. (C) 2012 Elsevier Ltd. All rights reserved.
• CORE-SHELL COMPOUND, PHOTOSENSITIVE RESIN COMPOSITION INCLUDING THE SAME, PHOTOSENSITIVE RESIN LAYER, COLOR FILTER AND CMOS IMAGE SENSOR
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20220204775A1

  公开（公告）日：2022-06-30

  A core-shell compound, a photosensitive resin composition including the same, a photosensitive resin layer manufactured using the photosensitive resin composition, a color filter including the photosensitive resin layer, and a CMOS image sensor including the color filter, the core-shell compound including a squarylium core including three or more (meth)acrylate groups and a shell surrounding the squarylium core.

  一种核壳化合物，包括该核壳化合物的光敏树脂组合物，使用该光敏树脂组合物制造的光敏树脂层，包括该光敏树脂层的彩色滤光片以及包括该彩色滤光片的CMOS图像传感器，该核壳化合物包括一个包含三个或更多(meth)丙烯酸酯基团的方芘核心和包围方芘核心的壳层。