[(Z)-3-phenylbuta-1,3-dien-1-yl]benzene | 21035-05-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: [(Z)-3-phenylbuta-1,3-dien-1-yl]benzene
• 英文别名: (Z)-1,3-diphenyl-1,3-butadiene；cis-1,3-diphenyl-1,3-butadiene；(Z)-1,3-Diphenyl-1,3-butadien；cis-1,3-Diphenyl-butadien-(1,3)；cis-1.3-Diphenyl-butadien-(1.3)；1,3-Diphenyl-cis-butadiene；[(1Z)-3-phenylbuta-1,3-dienyl]benzene
• CAS: 21035-05-2
• 化学式: C₁₆H₁₄
• 分子量: 206.287
• InChiKey: SWMVJOXVIGSMEN-SEYXRHQNSA-N

物化性质

• 沸点：
  140-150 °C(Press: 0.01 Torr)
• 密度：
  1.010±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [(Z)-3-phenylbuta-1,3-dien-1-yl]benzene 生成 1,r-3,t-4-triphenyl-c-4-<(Z)-styryl>-1-cyclohexene
  参考文献：
  名称：

  MULZER, JOHANN;KUHL, UWE;HUTTNER, GOTTFRIED;EVERTZ, KASPAR, CHEM. BER., 121,(1988) N2, C. 2231-2238

  摘要：

  DOI：
• 作为产物：
  描述：

  triphenyl(2-phenylprop-2-enylidene)-λ5-phosphane 、 苯甲醛 以37%的产率得到
  参考文献：
  名称：

  MULZER, J.;BRUENTRUP, G.;KUEHL, U.;HARTZ, G., CHEM. BER., 1982, 115, N 11, 3453-3469

  摘要：

  DOI：

文献信息

• Highly-functionalized arene synthesis based on palladium on carbon-catalyzed aqueous dehydrogenation of cyclohexadienes and cyclohexenes
  作者：Naoki Yasukawa、Hiroki Yokoyama、Masahiro Masuda、Yasunari Monguchi、Hironao Sajiki、Yoshinari Sawama

  DOI：10.1039/c7gc03819d

  日期：——

  Transition metal-catalyzed dehydrogenation is a clean oxidation method requiring no additional oxidants. We have accomplished a heterogeneous Pd/C-catalyzed aqueous dehydrogenation of 1,4-cyclohexadienes and cyclohexenes to give the corresponding highly-functionalized arenes. Furthermore, various arenes could be efficiently constructed in a one-pot manner via a Diels–Alder reaction and the following

  过渡金属催化的脱氢是一种清洁的氧化方法，不需要其他氧化剂。我们已经完成了Pd / C催化的1,4-环己二烯和环己烯的异水脱氢反应，得到了相应的高度官能化的芳烃。此外，可以通过Diels-Alder反应和随后的脱氢反应以一锅法高效地构建各种芳烃。
• A stable ?-silyl carbocation with allyl conjugation
  作者：Joseph B. Lambert、Chunqing Liu、Timur Kouliev

  DOI：10.1002/poc.531

  日期：2002.9

  The carbocation Et3SiCH2C+Ph(CHCHPh) has been found to be stable at room temperature with tetrakis(pentafluorophenyl)borate as the anion and benzene as the solvent. The cation constitutes the first stable β-silyl carbocation in which positive charge is delocalized both allylically and benzylically. Copyright © 2002 John Wiley & Sons, Ltd.

  发现碳正离子Et 3 SiCH 2 C + Ph（CH CHPh）在室温下稳定，以四（五氟苯基）硼酸根为阴离子，苯为溶剂。阳离子构成第一个稳定的β-甲硅烷基碳正离子，其中正电荷在烯丙基和苄基上均离域。版权所有©2002 John Wiley＆Sons，Ltd.
• Mulzer, Johann; Bruentrup, Gisela; Kuehl, Uwe, Chemische Berichte, 1982, vol. 115, # 11, p. 3453 - 3469
  作者：Mulzer, Johann、Bruentrup, Gisela、Kuehl, Uwe、Hartz, Georg

  DOI：——

  日期：——
• Nickel-Catalyzed Dehydrogenative [4 + 2] Cycloaddition of 1,3-Dienes with Nitriles
  作者：Masato Ohashi、Ippei Takeda、Masashi Ikawa、Sensuke Ogoshi

  DOI：10.1021/ja208162w

  日期：2011.11.16

  Pyridines, which comprise one of the most important classes of the six-membered heterocyclic compounds, are widely distributed in nature, and the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction of two alkynes and a nitrile is one of the most powerful methods for preparing versatile, highly substituted pyridine derivatives. However, the lack of chemo- and regioselectivity is still a crucial issue associated with fully intermolecular [2 + 2 + 2] cycloaddition. The present study developed the Ni(0)-catalyzed intermolecular dehydrogenative [4 + 2] cycloaddition reaction of 1,3-butadienes with nitrites to give a variety of pyridines regioselectively.
• Mulzer, Johann; Kuehl, Uwe; Huttner, Gottfried, Chemische Berichte, 1988, vol. 121, p. 2231 - 2238
  作者：Mulzer, Johann、Kuehl, Uwe、Huttner, Gottfried、Evertz, Kaspar

  DOI：——

  日期：——