Benzenemethanethiol, 3,5-bis(phenylmethoxy)- | 260964-92-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Benzenemethanethiol, 3,5-bis(phenylmethoxy)-
• 英文别名: [3,5-bis(phenylmethoxy)phenyl]methanethiol
• CAS: 260964-92-9
• 化学式: C₂₁H₂₀O₂S
• 分子量: 336.455
• InChiKey: JBLXQHIRLNZOIL-UHFFFAOYSA-N

物化性质

• 沸点：
  508.6±45.0 °C(Predicted)
• 密度：
  1.163±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  19.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Benzenemethanethiol, 3,5-bis(phenylmethoxy)- 、 [Au₂₃(cyclohexanethiolate)₁₆]^-[tetraoctylammonium]⁺ 以 二氯甲烷 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Decorating an anisotropic Au₁₃ core with dendron thiolates: enhancement of optical absorption and photoluminescence

  摘要：

  我们成功地将第二代（D2SH）多苯基醚树状硫烷（poly(benzyl ether)dendron-thiols）介入到[Au₂₃(ScC₆H₁₁)₁₆]⁻的Au₁₃核心中，同时保持了几何结构。

  DOI：

  10.1039/d1cc05235g
• 作为产物：
  描述：

  3,5-二苄氧基苄溴 在 硫脲 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 4.0h， 以91%的产率得到Benzenemethanethiol, 3,5-bis(phenylmethoxy)-
  参考文献：
  名称：

  Decorating an anisotropic Au₁₃ core with dendron thiolates: enhancement of optical absorption and photoluminescence

  摘要：

  我们成功地将第二代（D2SH）多苯基醚树状硫烷（poly(benzyl ether)dendron-thiols）介入到[Au₂₃(ScC₆H₁₁)₁₆]⁻的Au₁₃核心中，同时保持了几何结构。

  DOI：

  10.1039/d1cc05235g

文献信息

• Active oxygen eliminator and production method thereof
  申请人：Matsunami Yuki

  公开号：US20060099232A1

  公开（公告）日：2006-05-11

  The object of the present invention is to provide an active oxygen eliminator having high active oxygen elimination effect and can be widely used in foods, drinks, and cosmetics as well as to provide the method for producing the active oxygen eliminator. To this end, the present invention provides an active oxygen eliminator which includes composite particles produced by bonding a platinum group element to dendritic molecules or having the platinum group element included in the dendritic molecules and also provides a method for producing the active oxygen eliminator which includes forming the composite particles by bonding the platinum group element to the dendritic molecules or having the platinum group element included in the dendritic molecules.

  本发明的目的是提供一种具有高活性氧消除效果的活性氧消除剂，可以广泛用于食品、饮料、化妆品，并提供制造活性氧消除剂的方法。为此，本发明提供了一种活性氧消除剂，包括通过将铂族元素与树枝状分子结合或将铂族元素包含在树枝状分子中而产生的复合粒子，同时还提供了一种制造活性氧消除剂的方法，包括通过将铂族元素与树枝状分子结合或将铂族元素包含在树枝状分子中来形成复合粒子。
• WO2007/46575
  申请人：——

  公开号：——

  公开（公告）日：——
• Toward the continuous-flow synthesis of chiral tertiary alcohols by enantioselective addition of organozinc reagents to ketones using nanosize isoborneol ligands
  作者：Vicente J. Forrat、Diego J. Ramón、Miguel Yus

  DOI：10.1016/j.tetasy.2008.02.002

  日期：2008.3

  The catalytic enantio selective addition of different organozinc reagents, such as alkyl or in situ generated phenylzinc derivatives to simple aryl ketones, was accomplished using titanium tetraisopropoxide and chiral ligands derived from trans-1-arenesulfonylamino-2-isoborneolsulfonylamidocyclohexane and Frechet-type dendrons with up to 2.5 nin of diameter, giving the corresponding tertiary alcohols with enantioselectivities up to >99%. A simple and efficient procedure for the synthesis of the ligands used is also described, involving the radical addition of the corresponding thiol dendron to the chiral styryl-isoborneol derivative. (C) 2008 Elsevier Ltd. All rights reserved.
• Use of an active oxygen eliminator
  申请人：FUJIFILM Corporation

  公开号：EP1656840B1

  公开（公告）日：2008-05-14
• LIQUID METAL EMULSION
  申请人：Raccurt Olivier

  公开号：US20140147959A1

  公开（公告）日：2014-05-29

  The invention relates to a liquid metal emulsion. The emulsion according to the invention includes a liquid metal selected from among gallium, indium, and the alloys thereof, and a solvent that is an alkanethiol. The invention is useful in particular in the field of manufacturing thin films.