N-[2-(2'-methyl-1'-propenyl)]benzylidene-4-methyl-benzenesulfonamide | 250250-39-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[2-(2'-methyl-1'-propenyl)]benzylidene-4-methyl-benzenesulfonamide
• CAS: 250250-39-6
• 化学式: C₁₈H₁₉NO₂S
• 分子量: 313.42
• InChiKey: VSMMWILXQLCTGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.23
• 重原子数：
  22.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  46.5
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  N-[2-(2'-methyl-1'-propenyl)]benzylidene-4-methyl-benzenesulfonamide 在 potassium carbonate 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.25h， 生成 C-2'-(2-methyl-1-propenyl)phenyl N-4-methylphenylsulfonyloxaziridine
  参考文献：
  名称：

  The Endocyclic Restriction Test:  Oxygen Transfer from N-Sulfonyl Oxaziridines to Alkenes

  摘要：

  [GRAPHICS]The transition state for the transfer of oxygen from N-sulfonyl oxaziridines to alkenes has been investigated experimentally using the endocyclic restriction test. Molecules containing oxaziridines and alkenes were prepared and the ability of each system to intramolecularly transfer oxygen was evaluated, The results are consistent with a transition state in which N-O bond cleavage is more advanced than C-O bond cleavage.

  DOI：

  10.1021/ol990969w
• 作为产物：
  描述：

  [(2-溴苯基)甲基]三苯基-鏻溴化物 在 碘 、 sodium ethanolate 、 magnesium 、 1,2-二溴乙烷 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 14.83h， 生成 N-[2-(2'-methyl-1'-propenyl)]benzylidene-4-methyl-benzenesulfonamide
  参考文献：
  名称：

  The Endocyclic Restriction Test:  Oxygen Transfer from N-Sulfonyl Oxaziridines to Alkenes

  摘要：

  [GRAPHICS]The transition state for the transfer of oxygen from N-sulfonyl oxaziridines to alkenes has been investigated experimentally using the endocyclic restriction test. Molecules containing oxaziridines and alkenes were prepared and the ability of each system to intramolecularly transfer oxygen was evaluated, The results are consistent with a transition state in which N-O bond cleavage is more advanced than C-O bond cleavage.

  DOI：

  10.1021/ol990969w