3,8-diisopropyl-2,9-dimethyl-deca-4,6-diyne-3,8-diol | 113560-52-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,8-diisopropyl-2,9-dimethyl-deca-4,6-diyne-3,8-diol
• 英文别名: 3,8-Diisopropyl-2,9-dimethyl-deca-4,6-diin-3,8-diol；2,9-dimethyl-3,8-di(propan-2-yl)deca-4,6-diyne-3,8-diol
• CAS: 113560-52-4
• 化学式: C₁₈H₃₀O₂
• 分子量: 278.435
• InChiKey: CWAVXMKBESEBGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.08
• 重原子数：
  20.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  40.46
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  3-异丙基-4-甲基-1-炔基-3-戊醇 在 ammonium chloride 、 水 、 copper(l) chloride 作用下， 生成 3,8-diisopropyl-2,9-dimethyl-deca-4,6-diyne-3,8-diol
  参考文献：
  名称：

  来自加热的组氨酸-葡萄糖模型系统的抗氧化剂。铜（II）结合能力的研究

  摘要：

  AbstractThe metal binding ability of Maillard reaction products (MRP) was investigated by spectrophotometric monitoring for complex/chelate formation. In addition, the antioxidant activity of MRP, in the presence of Cu(II), was evaluated on a lipid model system consisting of sunflower seed oil/water (1∶2). Results from the Rancimat test indicated a significant decrease in pro‐oxidant ability of Cu(II) in the presence of MRP in contrast to histidine alone, whether heated or not. Results from the diphenylpicrylhydrazyl method showed that, in contrast to histidine (heated or not), the antiradical ability of MRP is reduced in the presence of Cu(II), but depends on the reaction time between MRP and Cu(II).

  DOI：

  10.1007/s11746-001-0392-y