Tetradeca-3,6-dien-1-ol | 392742-71-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Tetradeca-3,6-dien-1-ol
• CAS: 392742-71-1
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: BSQUGZUNPVDSFI-UHFFFAOYSA-N

物化性质

• 沸点：
  306.8±11.0 °C(Predicted)
• 密度：
  0.860±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Tetradeca-3,6-dien-1-ol 在 4-二甲氨基吡啶 、 间氯过氧苯甲酸 作用下， 生成 Acetic acid 2-[3-(3-heptyl-oxiranylmethyl)-oxiranyl]-ethyl ester
  参考文献：
  名称：

  Investigation of aliphatic dienes by chemical ionization with nitric oxide

  摘要：

  AbstractIt is shown that the position of the double bond close to the hydrocarbon end of an aliphatic diene functionalized at C(1) can readily be determined by chemical ionization with NO+. Owing to the low abundance of the ions characteristic for the position of the other double bond, its localization may be difficult. Measurement of the chemical ionization (nitric oxide as reagent gas) spectra of the corresponding epoxides or collision activation studies can help.

  DOI：

  10.1002/oms.1210261205
• 作为产物：
  描述：

  3-Undecen-1-ol 在 正丁基锂 、 pyridinium chlorochromate 作用下， 生成 Tetradeca-3,6-dien-1-ol
  参考文献：
  名称：

  Investigation of aliphatic dienes by chemical ionization with nitric oxide

  摘要：

  AbstractIt is shown that the position of the double bond close to the hydrocarbon end of an aliphatic diene functionalized at C(1) can readily be determined by chemical ionization with NO+. Owing to the low abundance of the ions characteristic for the position of the other double bond, its localization may be difficult. Measurement of the chemical ionization (nitric oxide as reagent gas) spectra of the corresponding epoxides or collision activation studies can help.

  DOI：

  10.1002/oms.1210261205

文献信息

• Investigation of aliphatic dienes by chemical ionization with nitric oxide
  作者：H. Budzikiewicz、St. Blech、B. Schneider

  DOI：10.1002/oms.1210261205

  日期：1991.12

  AbstractIt is shown that the position of the double bond close to the hydrocarbon end of an aliphatic diene functionalized at C(1) can readily be determined by chemical ionization with NO+. Owing to the low abundance of the ions characteristic for the position of the other double bond, its localization may be difficult. Measurement of the chemical ionization (nitric oxide as reagent gas) spectra of the corresponding epoxides or collision activation studies can help.