10-Methyl-9-dodecyl acetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 10-Methyl-9-dodecyl acetate
• 英文别名: 10-methyl-dodecyl acetate；10R-Methyldodecyl acetate；10-methyldodecyl acetate
• 化学式: C₁₅H₃₀O₂
• 分子量: 242.402
• InChiKey: WUVOJIMYHUYERX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (9-hydroxynonyl)triphenylphosphonium bromide 在 palladium on activated charcoal 吡啶 、 氢气 、 dimsyl sodium 作用下， 以 四氢呋喃 、 甲醇 、 二甲基亚砜 为溶剂， 反应 2.5h， 生成 10-Methyl-9-dodecyl acetate
  参考文献：
  名称：

  An easy synthesis of the sex pheromones 10-methyldodecyl acetate and its homologues.

  摘要：

  DOI：

  10.1271/bbb1961.46.1925

文献信息

• Liquid active substance slow releasing device
  申请人：NITTO DENKO CORPORATION

  公开号：EP0315994A1

  公开（公告）日：1989-05-17

  A liquid active substance slow releasing device comprising a thermoplastic polyester resin having a glass transition point of from 5°C to 80°C and an evaporative liquid active substance having a limited solubility for the aforesaid thermoplastic resin, said device being an opaque resin molding of the thermoplastic resin having dispersed therein the liquid active substance as fine droplets in an amount over the saturation solubility and becoming substantially transparent when the amount of the liquid active substance in the resin molding is reduced.

  一种液态活性物质缓释装置，由玻璃化转变点为 5°C 至 80°C 的热塑性聚酯树脂和对上述热塑性树脂具有有限溶解度的蒸发性液态活性物质组成，所述装置为热塑性树脂的不透明树脂模塑件，其中以超过饱和溶解度的微小液滴形式分散有液态活性物质，当树脂模塑件中的液态活性物质的量减少时，该装置变得基本透明。
• COMMUNICATION-DISTURBING AGENTS AND METHOD FOR DISTURBING COMMUNICATION
  申请人：Shin-Etsu Chemical Company, Ltd.

  公开号：EP0962137A1

  公开（公告）日：1999-12-08

  When a communication disruptant containing (Z)-11-tetradecen-1-yl acetate as the only active ingredient is continually used for a period of 5 to 10 years, a phenomenon has been observed in which its communication-disrupting effect on insect pests, particularly of the family Tortricidae, living in the field or the like through successive generations is reduced. Accordingly, it is eagerly desired to develop a new communication disruptant which is also effective for such fields where the communication-disrupting effect (on insect pests, particularly of the family Tortricidae, living there through successive generations) has been reduced. The present invention provides, for use in the control of insect pests having (Z)-11-tetradecen-1-yl acetate contained in their sex pheromone, a communication disruptant containing (Z)-11-tetradecen-1-yl acetate and the maximum component in the composition of the sex pheromone excepting (Z)-11-tetradecen-1-yl acetate, wherein the weight percentage of the maximum component in the communication disruptant is equal to a value obtained by multiplying the weight percentage of the maximum component in the sex pheromone by a number in the range of 2/100 to 50/100.

  当持续使用以(Z)-11-十四烯-1-基乙酸酯为唯一有效成分的通讯干扰剂 5 至 10 年时，已观察到一种现象，即其对生活在田间或类似地方的害虫（特别是蓟马科害虫）的通讯干扰效果逐代降低。因此，人们迫切希望开发出一种新的通讯干扰剂，这种干扰剂对此类田地的通讯干扰效果（对生活在田地中的害虫，特别是蓟马科害虫的连续世代干扰效果）也有所降低。本发明为防治性信息素中含有(Z)-11-十四烯-1-基乙酸酯的害虫，提供了一种含有(Z)-11-十四烯-1-基乙酸酯和除(Z)-11-十四烯-1-基乙酸酯之外的性信息素组合物中最大成分的通讯干扰剂、其中，通讯干扰剂中最大成分的重量百分比等于性信息素中最大成分的重量百分比乘以 2/100 至 50/100 范围内的一个数字所得的值。
• Sustained release dispenser comprising two or more sex pheromone substances and a pest control method
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1459626A1

  公开（公告）日：2004-09-22

  Provided are a sustained release dispenser which can control the release of sex pheromone simultaneously toward two or more species of insect pests and can also release the sex pheromone in response to the generation period of insect pest and the pest control method toward two or more insect pests. Provided specifically is a sex pheromone sustained release dispenser comprising two or more sex pheromone substances, each substance being aliphatic derivative having 10 to 20 carbons, and first and second chambers wherein some or all of the sex pheromone substance having a smallest carbon number excluding a carbon number in a functional group is contained in a first polymer chamber and the remainder is contained in a second polymer chamber. Provided also is a pest control method for using the sex pheromone sustained release dispenser.

  本发明提供了一种性信息素持续释放分配器，该分配器可控制同时向两种或两种以上害虫释放性信息素，还可根据害虫的生成期释放性信息素，以及针对两种或两种以上害虫的害虫控制方法。特别提供了一种性信息素持续释放分配器，包括两种或两种以上的性信息素物质，每种物质都是具有 10 至 20 个碳原子的脂肪族衍生物，以及第一和第二室，其中具有最小碳原子数（不包括官能团中的碳原子数）的性信息素物质的一部分或全部包含在第一聚合物室中，其余部分包含在第二聚合物室中。还提供了一种使用性信息素持续释放分配器的害虫控制方法。
• SUSTAINED-RELEASE PHEROMONE PREPARATION
  申请人：Sankei Chemical Co., Ltd.

  公开号：EP1676480A1

  公开（公告）日：2006-07-05

  It is an object of the present invention to provide a sustained release pheromone formulation, which is not affected by the air temperature, is able to release a sex pheromone at a constant rate, does not require troublesome recovery after use, and does not pollute the environment. The present invention provides a sustained release pheromone formulation characterized by comprising a pheromone contained in a crystalline mineral.

  本发明的目的是提供一种不受气温影响、能以恒定的速率释放性信息素、使用后不需要麻烦的回收、不污染环境的持续释放信息素制剂。本发明提供了一种持续释放信息素制剂，其特征在于包含在晶体矿物中的信息素。
• Acetate-containing mating disruptant and mating distruption method using the same
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2191717A2

  公开（公告）日：2010-06-02

  Provided are a mating disruptant having an improved mating disruption effect against pest insects. Specifically, provided is a mating disruptant for the control of pest insects whose natural sex pheromone composition is substantially free of an alcohol and comprises one or more acetates, the disruptant comprising the one or more acetates and an alcohol or alcohols which can be derived from the one or more acetate, wherein an amount of each of the alcohol or alcohols is from 0.5 to 10% by weight relative to an amount of each deriving acetate; and a mating disruption method using the mating disruptant. The alcohol which can be derived from the acetate is an alcohol obtainable by hydrolysis of the acetate and means an alcohol component of the ester derived from an acid and the alcohol.

  本发明提供了一种交配干扰剂，其对害虫的交配干扰效果有所改善。具体地说，提供了一种用于防治害虫的交配干扰剂，其天然性信息素组合物基本上不含酒精，并包括一种或多种醋酸盐，该干扰剂包括一种或多种醋酸盐和可从一种或多种醋酸盐衍生的一种或多种醇，其中每种醇的用量相对于每种衍生醋酸盐的用量为 0.5%至 10%（按重量计）；以及一种使用该交配干扰剂的交配干扰方法。可从乙酸酯衍生的醇是可通过乙酸酯水解获得的醇，是指从酸和醇衍生的酯的醇组分。