7,18-Bis(2-ethylhexyl)-11,22-bis[4-(1,2,2-trifluoroethenoxy)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone | 1269063-77-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 7,18-Bis(2-ethylhexyl)-11,22-bis[4-(1,2,2-trifluoroethenoxy)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone
• 英文别名: 7,18-bis(2-ethylhexyl)-11,22-bis[4-(1,2,2-trifluoroethenoxy)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone
• CAS: 1269063-77-5
• 化学式: C₅₆H₄₈F₆N₂O₈
• 分子量: 990.996
• InChiKey: QZJKXWXZGLWOTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  72
• 可旋转键数：
  20
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  4-(trifluorovinyloxy)phenol 、 N，N'-双（2-乙基己氧基）-1,7-二溴-3,4,9,10-per二酰亚胺 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 12.0h， 以85%的产率得到7,18-Bis(2-ethylhexyl)-11,22-bis[4-(1,2,2-trifluoroethenoxy)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone
  参考文献：
  名称：

  Thermally Polymerized Rylene Nanoparticles

  摘要：

  Rylene dyes functionalized with varying numbers of phenyl trifluorovinyl ether (TFVE) moieties were subjected to a thermal emulsion polymerization to yield shape-persistent, water-soluble chromophore nanoparticles. Perylene and terrylene diimide derivatives containing either two or four phenyl TFVE functional groups were synthesized and subjected to thermal emulsion polymerization in tetraglyme. Dynamic light scattering measurements indicated that particles with sizes ranging from 70 to 100 nm were obtained in tetraglyme, depending on monomer concentration. The photophysical properties of individual monomers were preserved in the nanoemulsions, and emission colors could be tuned between yellow, orange, red, and deep red. The nanoparticles were found to retain their shape upon dissolution into water, and the resulting water suspensions displayed moderate to high fluorescence quantum yield:

  DOI：

  10.1021/ma2000866

文献信息

• Thermally Polymerized Rylene Nanoparticles
  作者：Trisha L. Andrew、Timothy M. Swager

  DOI：10.1021/ma2000866

  日期：2011.4.12

  Rylene dyes functionalized with varying numbers of phenyl trifluorovinyl ether (TFVE) moieties were subjected to a thermal emulsion polymerization to yield shape-persistent, water-soluble chromophore nanoparticles. Perylene and terrylene diimide derivatives containing either two or four phenyl TFVE functional groups were synthesized and subjected to thermal emulsion polymerization in tetraglyme. Dynamic light scattering measurements indicated that particles with sizes ranging from 70 to 100 nm were obtained in tetraglyme, depending on monomer concentration. The photophysical properties of individual monomers were preserved in the nanoemulsions, and emission colors could be tuned between yellow, orange, red, and deep red. The nanoparticles were found to retain their shape upon dissolution into water, and the resulting water suspensions displayed moderate to high fluorescence quantum yield: