2,7-bis(2,4′-bipyridin-5-yl)triphenylene | 1394813-62-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,7-bis(2,4′-bipyridin-5-yl)triphenylene
• 英文别名: 2,7-di([2,4'-bipyridin]-5-yl)triphenylene；2-Pyridin-4-yl-5-[7-(6-pyridin-4-ylpyridin-3-yl)triphenylen-2-yl]pyridine；2-pyridin-4-yl-5-[7-(6-pyridin-4-ylpyridin-3-yl)triphenylen-2-yl]pyridine
• CAS: 1394813-62-7
• 化学式: C₃₈H₂₄N₄
• 分子量: 536.635
• InChiKey: ZDCWLNFPCAAJKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  42
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,7-二溴苯并菲 在 四(三苯基膦)钯 、 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 、 potassium carbonate 作用下， 以 1,4-二氧六环 、 乙醇 、 水 、 甲苯 为溶剂， 反应 34.0h， 生成 2,7-bis(2,4′-bipyridin-5-yl)triphenylene
  参考文献：
  名称：

  EP2679581

  摘要：

  公开号：

文献信息

• Molecular Design of High-molecular-orientation Electron-transport Materials and Application to Organic Light-emitting Diodes
  作者：Kazunori Togashi、Yuta Sagara、Takuma Yasuda、Chihaya Adachi

  DOI：10.1246/cl.130150

  日期：2013.6.5

  Two novel electron-transport materials (ETMs), 2,3′-Bpy-TP and 2,4′-Bpy-TP, with high horizontal molecular orientation to substrates, were synthesized. It was shown by measuring the IR absorption spectra of their deposited thin films that C–H···N hydrogen bonds are formed between the 2,3′-Bpy-TP molecules and between the 2,4′-Bpy-TP molecules. It was also shown that there is a closed relationship between their molecular orientations and the driving voltages of electron-only devices (EODs) using them as electron-transport layers (ETLs).

  研究人员合成了两种新型电子传输材料（ETM）--2,3′-Bpy-TP 和 2,4′-Bpy-TP，这两种材料的分子与基底的水平取向度很高。通过测量其沉积薄膜的红外吸收光谱表明，2,3′-Bpy-TP 分子之间以及 2,4′-Bpy-TP 分子之间形成了 C-H-N 氢键。研究还表明，它们的分子取向与使用它们作为电子传输层（ETL）的纯电子器件（EOD）的驱动电压之间存在着封闭的关系。
• COMPOUND HAVING SUBSTITUTED TRIPHENYLENE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Adachi Chihaya

  公开号：US20140034936A1

  公开（公告）日：2014-02-06

  An organic compound having an excellent electron injection and transport performance is provided as a material for a low-power-consumption organic electroluminescent device. A low-power-consumption organic electroluminescent device is also provided by using the compound. The compound is a compound of general formula (1) or (2) having a substituted bipyridyl and triphenylene ring structure. The organic electroluminescent device includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes, and uses the compound as constituent material of at least one of the organic layers.

  本发明提供了一种具有优异的电子注入和传输性能的有机化合物，作为低功耗有机电致发光器件的材料。通过使用该化合物，还提供了一种低功耗有机电致发光器件。该化合物是一般式（1）或（2）的化合物，具有取代的联吡啶和三苯基烯环结构。该有机电致发光器件包括一对电极和夹在电极对之间的一个或多个有机层，并将该化合物用作至少一个有机层的组分材料。
• Compound having substituted triphenylene ring structure, and organic electroluminescent device
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：US10026903B2

  公开（公告）日：2018-07-17

  An organic compound having an excellent electron injection and transport performance is provided as a material for a low-power-consumption organic electroluminescent device. A low-power-consumption organic electroluminescent device is also provided by using the compound. The compound is a compound of general formula (1) or (2) having a substituted bipyridyl and triphenylene ring structure. The organic electroluminescent device includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes, and uses the compound as constituent material of at least one of the organic layers.

  提供了一种具有优异电子注入和传输性能的有机化合物，作为低功耗有机电致发光器件的材料。通过使用该化合物，还提供了一种低功耗有机电致发光器件。该化合物是通式（1）或（2）的化合物，具有取代的联吡啶和三亚苯环结构。该有机电致发光器件包括一对电极和夹在这对电极之间的一个或多个有机层，并使用该化合物作为至少一个有机层的组成材料。
• EP2679581B1
  申请人：——

  公开号：EP2679581B1

  公开（公告）日：2017-08-09
• ORGANIC ELECTROLUMINESCENCE DEVICE AND MONOAMINE COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20190237668A1

  公开（公告）日：2019-08-01

  An organic electroluminescence device includes a first electrode, a hole transport region on the first electrode, an emission layer on the hole transport region, an electron transport region on the emission layer, and a second electrode on the electron transport region. The hole transport region includes a monoamine compound represented by the following Formula 1: