perylene tetracarboxylic acid bis(1,1,1,3,3,5,5-heptamethyltrisiloxanyl propylimide) | 1395396-44-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: perylene tetracarboxylic acid bis(1,1,1,3,3,5,5-heptamethyltrisiloxanyl propylimide)
• 英文别名: N,N'-di(3-(1,1,1-3,3-5,5-trisiloxanyl)propyl)perylene-3,4:9,10-tetracarboxylic acid bisimide；PTCBI；7,18-Bis[3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]propyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；7,18-bis[3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]propyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1395396-44-7
• 化学式: C₄₄H₆₂N₂O₈Si₆
• 分子量: 915.498
• InChiKey: AEQPONJGZWEJPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.26
• 重原子数：
  60
• 可旋转键数：
  16
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 、 zinc diacetate 作用下， 以 喹啉 、 5,5-dimethyl-1,3-cyclohexadiene 、 甲苯 为溶剂， 反应 10.0h， 生成 perylene tetracarboxylic acid bis(1,1,1,3,3,5,5-heptamethyltrisiloxanyl propylimide)
  参考文献：
  名称：

  Liquid–crystalline perylene tetracarboxylic acid bisimide bearing oligosiloxane chains with high electron mobility and solubility

  摘要：

  Liquid-crystalline perylene tetracarboxylic acid bisimide derivatives 1 and 2 bearing 1,1,1,2,2,3,3-heptamethyltrisiloxane chains at the end of alkyl side-chains have been synthesized. Compound 1 having four trisiloxane chains exhibits a hexagonal columnar phase at room temperature. Time-of-flight measurement reveals that the electron mobility in the columnar phase of compound 1 exceeds 10 (3) cm(2) V (1) s (1) at room temperature. In contrast, compound 2 bearing two trisiloxane chains is not mesomorphic. These two compounds are soluble in various organic solvents except for alcohols and thin films can be produced by a spin-coating method. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.orgel.2012.05.027

文献信息

• PERYLENE TETRACARBOXYLIC ACID BISIMIDE DERIVATIVE, n-TYPE SEMICONDUCTOR, PROCESS FOR PRODUCING n-TYPE SEMICONDUCTOR, AND ELECTRONIC DEVICE
  申请人：National University Corporation Kagawa University

  公开号：EP2695885B1

  公开（公告）日：2017-02-22
• Liquid–crystalline perylene tetracarboxylic acid bisimide bearing oligosiloxane chains with high electron mobility and solubility
  作者：Masahiro Funahashi、Akinari Sonoda

  DOI：10.1016/j.orgel.2012.05.027

  日期：2012.9

  Liquid-crystalline perylene tetracarboxylic acid bisimide derivatives 1 and 2 bearing 1,1,1,2,2,3,3-heptamethyltrisiloxane chains at the end of alkyl side-chains have been synthesized. Compound 1 having four trisiloxane chains exhibits a hexagonal columnar phase at room temperature. Time-of-flight measurement reveals that the electron mobility in the columnar phase of compound 1 exceeds 10 (3) cm(2) V (1) s (1) at room temperature. In contrast, compound 2 bearing two trisiloxane chains is not mesomorphic. These two compounds are soluble in various organic solvents except for alcohols and thin films can be produced by a spin-coating method. (C) 2012 Elsevier B. V. All rights reserved.