α-nitro-β-dimethylaminoacrolein | 58261-64-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: α-nitro-β-dimethylaminoacrolein
• 英文别名: 3-(dimethylamino)-2-nitro-2-propenal；3-(Dimethylamino)-2-nitroprop-2-enal；3-(dimethylamino)-2-nitroprop-2-enal
• CAS: 58261-64-6
• 化学式: C₅H₈N₂O₃
• 分子量: 144.13
• InChiKey: QMNYUNPFAPOSAL-UHFFFAOYSA-N

物化性质

• 熔点：
  79-80 °C(Solv: methanol (67-56-1))
• 沸点：
  356.9±32.0 °C(Predicted)
• 密度：
  1.182±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  66.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  α-nitro-β-dimethylaminoacrolein 在 水 作用下， 以 甲醇 为溶剂， 反应 0.5h， 以75%的产率得到dimethylammonium salt of nitromalonaldehyde
  参考文献：
  名称：

  Unusual reactions of ?-nitro-?-dimethylaminoacrolein

  摘要：

  DOI：

  10.1007/bf00950150
• 作为产物：
  描述：

  dimethylammonium salt of nitromalonaldehyde 以 甲醇 为溶剂， 反应 0.17h， 以65%的产率得到α-nitro-β-dimethylaminoacrolein
  参考文献：
  名称：

  Unusual reactions of ?-nitro-?-dimethylaminoacrolein

  摘要：

  DOI：

  10.1007/bf00950150

文献信息

• Novel bipyridine derivatives
  申请人：Kuwabara Hirokazu

  公开号：US20050085642A1

  公开（公告）日：2005-04-21

  The invention provides a bipyridine derivative useful as an intermediate for pharmaceutical products, agricultural chemicals, electrophotographic photosensitive materials, dyes and the like, which is a bipyridine derivative represented by the general formula (I) and a salt thereof: wherein R1 represents an alkyl group with 2 to 20 carbon atoms having a substituent, substituted or unsubstituted aminomethyl group, trifluoromethyl group, substituted or unsubstituted thiomethyl group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted carbonyl group, substituted sulfonyl group, unsubstituted or monosubstituted carbamoyl group, unsubstituted or monosubstituted sulfamoyl group, substituted or unsubstituted thiol group, unsubstituted or monosubstituted amino group, substituted carbonylamino group, substituted or unsubstituted ureido group, nitro group, cyano group, formyl group or an equivalent thereof, iodine atom or fluorine atom.

  该发明提供了一种对制药产品、农药化学品、电子感光材料、染料等具有中间体作用的双吡啶衍生物，其为一种由通式（I）表示的双吡啶衍生物及其盐：其中R1代表具有取代基的2至20个碳原子的烷基基团，取代或未取代氨甲基基团，三氟甲基基团，取代或未取代硫甲基基团，取代或未取代烯基基团，取代或未取代烷氧基团，取代或未取代芳氧基团，取代羰基团，取代磺酰基团，未取代或单取代的氨甲酰基团，未取代或单取代的磺酰胺基团，取代或未取代硫醇基团，未取代或单取代的氨基团，取代羰基氨基团，取代或未取代脲基团，硝基基团，氰基团，甲酰基团或其等效物，碘原子或氟原子。
• Bipyridine Derivatives
  申请人：Fujifilm Finechemicals Co., Ltd.

  公开号：US07301029B2

  公开（公告）日：2007-11-27

  The invention provides a bipyridine derivative useful as an intermediate for pharmaceutical products, agricultural chemicals, electrophotographic photosensitive materials, dyes and the like, which is a bipyridine derivative represented by the general formula (I) and a salt thereof: wherein R1 represents an alkyl group with 2 to 20 carbon atoms having a substituent, substituted or unsubstituted aminomethyl group, trifluoromethyl group, substituted or unsubstituted thiomethyl group, substituted or unsubstituted alkenyl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted carbonyl group, substituted sulfonyl group, unsubstituted or monosubstituted carbamoyl group, unsubstituted or monosubstituted sulfamoyl group, substituted or unsubstituted thiol group, unsubstituted or monosubstituted amino group, substituted carbonylamino group, substituted or unsubstituted ureido group, nitro group, cyano group, formyl group or an equivalent thereof, iodine atom or fluorine atom.

  本发明提供了一种双吡啶衍生物，可用作制药产品、农药、电子感光材料、染料等的中间体，其为一种由通式（I）表示的双吡啶衍生物及其盐：其中R1代表具有取代基的2至20个碳原子的烷基，取代或未取代的氨甲基基团、三氟甲基基团、取代或未取代的硫甲基基团、取代或未取代的烯基基团、取代或未取代的烷氧基团、取代或未取代的芳氧基团、取代的羰基团、取代的磺酰基团、未取代或单取代的氨基甲酰基团、未取代或单取代的磺酰胺基团、取代或未取代的硫醇基团、未取代或单取代的氨基团、取代的羰基氨基团、取代或未取代的脲基团、硝基团、氰基团、甲酰基团或其等效物、碘原子或氟原子。
• Synthese von 5-Acyl- und 5-Nitroazulenen
  作者：Theodor Severin、Ingolf Ipach

  DOI：10.1055/s-1979-28900

  日期：——
• Unusual reactions of ?-nitro-?-dimethylaminoacrolein
  作者：Zh. A. Krasnaya、T. S. Stytsenko、V. S. Bogdanov、E. D. Daeva

  DOI：10.1007/bf00950150

  日期：1985.7