1-methylcyclohexyl vinyl ether | 1256139-75-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-methylcyclohexyl vinyl ether
• 英文别名: 1-Ethenoxy-1-methylcyclohexane
• CAS: 1256139-75-9
• 化学式: C₉H₁₆O
• 分子量: 140.225
• InChiKey: JEVYSAIVBOQNRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-甲基环己醇 、 乙炔 在 potassium hydroxide 作用下， 以 1,3-二甲基-2-咪唑啉酮 为溶剂， 130.0 ℃ 、176.52 kPa 条件下， 反应 10.4h， 生成 1-methylcyclohexyl vinyl ether
  参考文献：
  名称：

  METHOD FOR PRODUCING VINYL ETHER

  摘要：

  本文提供了一种从反应性较低的三级醇中高效制备高纯度乙烯醚的方法，其通过在碱存在下使用环状脲化合物或甘醇化合物或其混合物作为溶剂，反应乙炔和三级醇来实现，所述乙烯醚的化学式如下（1）。

  公开号：

  US20120083628A1

文献信息

• Resin composition
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0222157A2

  公开（公告）日：1987-05-20

  An ordinary temperature-curable resin composition comprising (A) a hydrolyzable silyl group-containing fluoroolefin copolymer obtained by polymerizing a monomeric mixture comprising a fluoroolefin as an essential component in the presence of a hydrolyzable silyl group-containing compound (B), a curing catalyst, and (C) an organic solvent.

  一种常温固化树脂组合物，包括(A)含可水解硅烷基的氟烯烃共聚物，该共聚物是在含可水解硅烷基的化合物(B)、固化催化剂和(C)有机溶剂的存在下，通过聚合以氟烯烃为主要成分的单体混合物而获得。
• Vinylidene fluoride copolymer and composition containing the same
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0458290A2

  公开（公告）日：1991-11-27

  A vinylidene fluoride copolymer comprising 50 to 90 % by mole of units having the formula (I):         -CH₂-CF₂-   (I) 1 to 30 % by mole of units having the formula (II): 1 to 30 % by mole of units having the formula (III): 1 to 30 % by mole of units having the formula (IV): and a composition comprising the copolymer as the main component. Since the copolymer is excellent in solvent solubility, it can be dissolved in a widely used solvent for coatings and it is not required to treat the film at a high temperature after coating. Moreover, the obtained film is excellent in adhesion to a substrate, glossiness, weatherability, stain resistance and corrosion resistance.

  一种亚乙烯基氟化物共聚物，由 50%至 90%（以摩尔计）具有式 (I) 的单元组成： -CH₂-CF₂- (I) 1-30%（摩尔）具有式 (II) 的单元： 1-30%（以摩尔计）具有式（III）的单元： 1-30%（以摩尔计）具有式（IV）的单元： 以及一种以该共聚物为主要成分的组合物。由于共聚物具有优异的溶剂溶解性，因此可以溶解在广泛使用的涂料溶剂中，涂膜后也无需高温处理。此外，获得的薄膜在与基材的附着力、光泽度、耐候性、抗污性和耐腐蚀性方面都非常出色。
• Fluorine-containing copolymer and curable composition containing the same
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0483750A1

  公开（公告）日：1992-05-06

  A fluorine-containing copolymer comprising: 30 to 85 % by mole of structural units (a): 1 to 30 % by mole of structural units (b): and 3 to 60 % by mole of structural units (c): and a curable composition containing the same. The copolymer is excellent in compatibility with curing agents and the obtained film therefrom is excellent in appearance, gloss, durability, and the like.

  含氟共聚物，包括30% 至 85% （以摩尔计）的结构单元 (a)： 1 至 30%（摩尔）的结构单元（b）： 和 3%至 60%（以摩尔计）的结构单元（c）： 的共聚物，以及含有这种共聚物的可固化组合物。该共聚物与固化剂的相容性极佳，由此获得的薄膜在外观、光泽度、耐久性等方面也非常出色。
• POWDER COATING RESIN COMPOSITION
  申请人：Dow Corning Toray Silicone Co., Ltd.

  公开号：EP0735118A1

  公开（公告）日：1996-10-02

  Resin composition for powder paints, that has an excellent curability and excellent electrostatic properties (wraparound) and that provides cured coatings having an excellent appearance, weathering resistance, and mechanical properties, comprising (A) epoxy-functional branched organopolysiloxane and (B) a compound bearing a functional group reactive with the epoxy group, wherein the component (A)/component (B) weight ratio is from 2/98 to 98/2, or comprising (A) epoxy-functional branched organopolysiloxane, (B) a compound bearing a functional group reactive with the epoxy group, and (C) a compound bearing a functional group reactive with the functional group in component (B), wherein the component (A)/(component (B) + component (C)) weight ratio is from 2/98 to 98/2.

  用于粉末涂料的树脂组合物，该组合物具有优异的固化性和优异的静电性能（包覆性），并能提供具有优异外观、耐候性和机械性能的固化涂料，该组合物由(A)环氧官能团支链有机聚硅氧烷和(B)带有与环氧基团反应的官能团的化合物组成、其中组分（A）/组分（B）的重量比为 2/98 至 98/2，或包括（A）环氧官能团支链有机聚硅氧烷，（B）带有与环氧基反应的官能团的化合物，以及（C）带有与组分（B）中的官能团反应的官能团的化合物，其中组分（A）/（组分（B）+组分（C））的重量比为 2/98 至 98/2。
• UNSATURATED GROUP-CONTAINING ESTER COMPOUND, POLYMER, THERMOSETTING RESIN COMPOSITION, AND CURED FILM
  申请人：Kyoeisha Chemical Co., Ltd.

  公开号：EP3640268A1

  公开（公告）日：2020-04-22

  It is an object of the present invention to provide an unsaturated group-containing ester compound which can be used as a raw material of a curable composition using transesterification reaction and which is inexpensive and has a good curability, and a polymer, a thermosetting resin composition, and a curable composition which containing the unsaturated group-containing ester compound, respectively. An unsaturated group-containing ester compound having a chemical structure represented by the following general formula (1). n1: 1 to 10 (in the formula, R1, R2, and R3 are the same or different and each is a hydrogen, an alkyl group, a carboxyl group, an alkyl ester group or a structure represented by R4-[COOR5]; R4 is an aliphatic, an alicyclic or an aromatic alkylene group with a number of atoms of 50 or less in the main chain, which may have one or more functional groups selected from the group consisting of an ester group, an ether group, an amide group, and a urethane and may have a side chain; R5 is an alkyl group having 50 or less carbon atoms; and in the compound represented by the general formula (1), the R4-[COOR5] group may be a lactone structure represented by the following general formula (1-1).) (Rx is a hydrocarbon group having 2 to 10 carbon atoms which may have a branched chain.)

  本发明的目的是提供一种可用作使用酯交换反应的可固化组合物的原料、价格低廉且具有良好固化性的含不饱和基团酯化合物，以及分别含有该含不饱和基团酯化合物的聚合物、热固性树脂组合物和可固化组合物。 含不饱和基团酯化合物的化学结构由以下通式（1）表示。 n1：1 至 10 (式中，R1、R2 和 R3 相同或不同，且各自为氢、烷基、羧基、烷基酯基或 R4-[COOR5] 所代表的结构； R4 是脂肪族、脂环族或芳香族亚烷基，其主链上的原子数不超过 50 个，可带有一个或多个官能团，这些官能团选自由酯基、醚基、酰胺基和氨基甲酸酯组成的组，并可带有侧链； R5 是具有 50 个或更少碳原子的烷基；在通式 (1) 所代表的化合物中，R4-[COOR5] 基团可以是由以下通式 (1-1) 所代表的内酯结构）。 (Rx 是具有 2 至 10 个碳原子的烃基，可以是支链）。