3-Methoxycarbonyl-3-methylpentanoic acid | 43010-65-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-Methoxycarbonyl-3-methylpentanoic acid
• 英文别名: 3-(Carbomethoxy)-3-methylpentanoic acid；(+/-)-2-ethyl-2-methyl-succinic acid-1-methyl ester；(+/-)-2-Aethyl-2-methyl-bernsteinsaeure-1-methylester；2-Ethyl-2-methyl-bernsteinsaeure-1-methylester；3-Methyl-3-aethyl-carbomethoxy-propionsaeure；3-Methyl-3-methoxycarbonyl-n-valeriansaeure
• CAS: 43010-65-7
• 化学式: C₈H₁₄O₄
• 分子量: 174.197
• InChiKey: VMGDCNRPLRPMQT-UHFFFAOYSA-N

物化性质

• 熔点：
  35.8-36.3 °C(Solv: ligroine (8032-32-4))
• 沸点：
  96-97 °C(Press: 1 Torr)
• 密度：
  1.091 g/cm3(Temp: 23 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-Methoxycarbonyl-3-methylpentanoic acid 在 草酰氯 、 potassium carbonate 作用下， 以 氯仿 、 水 、 苯 为溶剂， 反应 1.25h， 生成 N-<2-(Indol-3-yl)ethyl>-3-methoxycarbonyl-3-methylpentaneamide
  参考文献：
  名称：

  Hajicek, Josef; Holubek, Jiri; Trojanek, Jan, Collection of Czechoslovak Chemical Communications, 1982, vol. 47, # 10, p. 2749 - 2762

  摘要：

  DOI：
• 作为产物：
  描述：

  methyl 2-ethyl-2-methyl-4-pentenoate 生成 3-Methoxycarbonyl-3-methylpentanoic acid
  参考文献：
  名称：

  Canney, Daniel J.; Levine, Jeffrey A.; Lu, Hwang-Fun, Synthetic Communications, 1990, vol. 20, # 13, p. 2065 - 2073

  摘要：

  DOI：

文献信息

• COLORING CURABLE RESIN COMPOSITION, CURED FILM, COLOR FILTER, METHOD FOR MANUFACTURING COLOR FILTER, SOLID-STATE IMAGING DEVICE, IMAGE DISPLAY DEVICE, COMPOUND, AND CATION
  申请人：FUJIFILM Corporation

  公开号：US20160376234A1

  公开（公告）日：2016-12-29

  The present invention provides a colored curable resin composition that exhibits good heat resistance and durability in a sputtering process, a cured film, a color filter, a method for manufacturing a color filter, a solid-state image device, an image display device, a compound, and a cation. The colored curable resin composition contains a colorant represented by Formula (1), Formula (2), or Formula (3), a resin, a polymerizable compound, and a polymerization initiator. In Formula (1), R 101 and R 102 each independently represent a hydrogen atom or a substituent, R 103 to R 106 each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group, R 107 to R 111 each independently represent a hydrogen atom or a substituent, n1 to n4 each independently represent an integer of 0 to 4, n5 represents an integer of 0 to 6, X represents an anion or is not present, and at least one of R 101 , . . . , or R 111 includes an anion; and in the case where R 101 and R 102 represent hydrogen atoms, R 103 represents an aryl group having a substituent at at least the ortho-position.

  本发明提供了一种在溅射工艺中具有良好耐热性和耐久性的着色可固化树脂组合物、固化膜、色滤光器、制造色滤光器的方法、固态图像设备、图像显示设备、化合物和阳离子。该着色可固化树脂组合物含有由公式(1)、公式(2)或公式(3)表示的着色剂、树脂、可聚合化合物和聚合引发剂。在公式(1)中，R101和R102各自独立地表示氢原子或取代基，R103至R106各自独立地表示氢原子、烷基、芳基或杂芳基，R107至R111各自独立地表示氢原子或取代基，n1至n4各自独立地表示0至4的整数，n5表示0至6的整数，X表示阴离子或不出现，且至少R101、…或R111中包括阴离子；且在R101和R102表示氢原子的情况下，R103表示在至少邻位具有取代基的芳基。
• Meroterpenoids—II
  作者：A.S.C.Prakasa Rao、V.K. Bhalla、U.R. Nayak、Sukh Dev

  DOI：10.1016/0040-4020(73)80072-9

  日期：1973.1

  Bakuchiol, a terpene phenol from Psoralea corylifolia Linn has only one asymmetric centre. By suitable correlation with (+)-linalool on the one hand and, with (+)-3-methyl-3-methoxy-carbonyl-n-valeria acid on the other, it has been shown to possess (S)-chirality.

  补骨脂（Psoralea corylifolia Linn）的萜烯苯酚（Bakuchiol）只有一个不对称中心。通过一方面与（+）-芳樟醇和另一方面与（+）-3-甲基-3-甲氧基-羰基-正戊酸的合适的相关性，已显示具有（S）-手性。
• The absolute configurations of the alkaloids of <i>Physostigma venenosum</i> seeds
  作者：R B Longmore、B Robinson

  DOI：10.1111/j.2042-7158.1969.tb08360.x

  日期：2011.4.12

  The absolute configuration of physostigmine has been established by correlating the configuration of its C-3a atom with that of the asymmetric carbon atom in (+)-3-ethyl-3-methoxycarbonyl-3-methylpropionic acid. Comparison of the optical rotatory dispersion spectra of physostigmine, Na-norphysostigmine, geneserine, physovenine and eseramine have shown that all five alkaloids have the same absolute configurations.

  摘要 通过将physostigmine的C-3a原子的构型与(+)-3-乙基-3-甲氧羰基-3-甲基丙酸的不对称碳原子的构型相对应，已经确定了physostigmine的绝对构型。比较physostigmine、Na-norphysostigmine、generine、physovenine和eseramine的旋光色散光谱表明，这五种生物碱具有相同的绝对构型。
• Absolute configuration of 2,7-diazaspiro[4,4]nonane. A reassignment
  作者：C. G. Overberger、David Wei Wang、Richard K. Hill、Grant R. Krow、David W. Ladner

  DOI：10.1021/jo00326a031

  日期：1981.6
• 1333. The chemistry of fungi. Part LI. The absolute configuration of C-13 in rosenono- and rosolo-lactone: rosololactone
  作者：M. R. Cox、G. A. Ellestad、A. J. Hannaford、I. R. Wallwork、W. B. Whalley、B. Sjöberg

  DOI：10.1039/jr9650007257

  日期：——