Methyl 3-undecenoate | 100288-68-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Methyl 3-undecenoate
• 英文别名: methyl (E)-undec-3-enoate
• CAS: 100288-68-4
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: UXEZTQUHDSYCQP-MDZDMXLPSA-N

物化性质

• 沸点：
  252.2±9.0 °C(Predicted)
• 密度：
  0.886±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  癸酸甲酯 在 sodium hydroxide 、 乙酸酐 、 三溴化磷 、 sodium hydride 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 sodium iodide 作用下， 以 甲醇 、 乙醚 、 N,N-二甲基甲酰胺 为溶剂， 反应 26.5h， 生成 Methyl 3-undecenoate
  参考文献：
  名称：

  Mohan, H Rama; Rao, A S, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1992, vol. 31, # 10, p. 698 - 700

  摘要：

  DOI：

文献信息

• Dhokte; Rao, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1990, vol. 29, # 12, p. 1089 - 1091
  作者：Dhokte、Rao

  DOI：——

  日期：——
• OGURA, KATSUYUKI;YAHATA, NOBUHIRO;HASHIZUME, KIMITOSHI;TSUYAMA, KOICHI;TA+, CHEM. LETT., 1983, N 5, 767-770
  作者：OGURA, KATSUYUKI、YAHATA, NOBUHIRO、HASHIZUME, KIMITOSHI、TSUYAMA, KOICHI、TA+

  DOI：——

  日期：——
• SALOMON, M. F.;PARDO, S. N.;SALOMON, R. G., J. AMER. CHEM. SOC., 1984, 106, N 13, 3797-3802
  作者：SALOMON, M. F.、PARDO, S. N.、SALOMON, R. G.

  DOI：——

  日期：——
• STABILIZED MENTHOL AND OTHER VOLATILE COMPOUND COMPOSITIONS AND METHODS
  申请人：Ghalili Babak

  公开号：US20210236436A1

  公开（公告）日：2021-08-05

  The present disclosure relates to a stabilized or more stable volatile compound, e.g., menthol, compositions and methods of making and using them including a mixture of a stabilizer compound of formula (I), for example, undecylenic acid methyl ester, undecylenic acid or a salt thereof and a volatile compound where the volatile compound is less susceptible to volatizing into a gas. wherein A is —(CH2) a -CH═CH—(CH 2) 5-a -H where a is from 0 to 5, —(CH2) b -CH═CH—(CH 2) 6-b -H where b is from 0 to 6, —(CH2) c -CH═CH—(CH 2) 7-c -H where c is from 0 to 7, —(CH2) d -CH═CH—(CH 2) 5-d -H where d is from 0 to 8, or —CH2) e -CH═CH—(CH 2) 9-d -H where d is from 0 to 9; B is hydrogen or C 1-5 alkyl; and pharmaceutically acceptable salts thereof where B is hydrogen.
• [EN] STABILIZED MENTHOL AND OTHER VOLATILE COMPOUND COMPOSITIONS AND METHODS<br/>[FR] MENTHOL STABILISÉ ET AUTRES COMPOSITIONS DE COMPOSÉS VOLATILS ET PROCÉDÉS
  申请人：GHALILI BABAK

  公开号：WO2021154979A1

  公开（公告）日：2021-08-05

  The present disclosure relates to a stabilized or more stable volatile compound, e.g., menthol, compositions and methods of making and using them including a mixture of a stabilizer compound of formula (I), for example, undecylenic acid methyl ester, undecylenic acid or a salt thereof and a volatile compound where the volatile compound is less susceptible to volatizing into a gas. Formula (I) wherein A is -(CH2)a-CH=CH-(CH 2)s-a-H where a is from 0 to 5, -(CH2)b-CH=CH-(CH 2)e-b-H where b is from 0 to 6, -(CH2)c-CH=CH-(CH 2)/-ο-Η where c is from 0 to 7, -(CH2)d-CH=CH-(CH 2)8-d-H where d is from 0 to 8, or -CH2)e-CH=CH-(CH 2)g-d-H where d is from 0 to 9; B is hydrogen or C1-5 alkyl; and pharmaceutically acceptable salts thereof where B is hydrogen.