[RuHCl(bis(pyrazol-1-yl)methane)(cycloocta-1,5-diene)] | 152391-12-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [RuHCl(bis(pyrazol-1-yl)methane)(cycloocta-1,5-diene)]
• 英文别名: [RuHCl(1,5-cyclooctadiene)(bis(pyrazol-1-yl)methane)]；[RuHCl(1,5-cyclooctadiene)](bis(pyrazol-1-yl)methane)；chloro(hydrido)ruthenium;(1Z,5Z)-cycloocta-1,5-diene;1-(pyrazol-1-ylmethyl)pyrazole
• CAS: 152391-12-3
• 化学式: C₁₅H₂₁ClN₄Ru
• 分子量: 393.882
• InChiKey: YCBNTWSJQRJLSA-SUESZSCISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [RuHCl(bis(pyrazol-1-yl)methane)(cycloocta-1,5-diene)] 、 K(2-phenoxy-bis(pyrazol-1-yl)methane) 以 四氢呋喃 为溶剂， 以50%的产率得到RuH(κ(3)-2-phenoxy-bis(pyrazol-1-yl)methane)(1,5-cyclooctadiene)
  参考文献：
  名称：

  氢化钌与衍生自甲烷的杂蝎子配体的配合物：2-苯氧基-双（吡唑-1-基）甲烷。配体在取代和质子转移反应中的半不稳定作用

  摘要：

  络合物[期RuH（κ 3 -bpzmPhO）（COD）]（1）通过反应合成[期RuH（COD）（NH 2 NME 2）3 ] [BPH 4 ]与2-苯氧基-双钾盐（吡唑-1-基）甲烷（bpzmPhOK）。这种配位体采用κ 3 - Ñ，Ñ，Ò上的金属中心配位使人想起的通常trispyrazolylborate络合物中观察到的情况。络合物1以两种处于平衡状态的非对映异构体的混合物形式存在于溶液中。的反应1不同膦PME（3，PME 2 PH，PMePh2和PPh 3）已被研究。反应产物不仅取决于膦的性质，还取决于配合物：L的比率和温度。化学计量的二膦衍生物[期RuH（κ 1 - Ö -bpzmPhO）（鳕鱼）L- 2 ]（L = PME 3，PME 2 PH）和[期RuH（κ 3 -bpzmPhO）L- 2 ]（L = PME 3，PME 2制备了Ph，PMePh 2，PPh 3）。类似地，式[tetraphosphine衍生物顺-

  DOI：

  10.1016/j.poly.2003.11.023

文献信息

• Synthesis and spectroscopic studies of new hydridoruthenium complexes: catalytic reactions of [RuHCl(bpzm)(cod)] (bpzm = bis(pyrazol-1-yl)methane, cod = cycloocta-1,5-diene)
  作者：Félix A. Jalón、Antonio Otero、Ana Rodríguez、Mercedes Pérez-Manrique

  DOI：10.1016/0022-328x(95)05836-e

  日期：1996.2

  greatly depending on the reaction conditions. The complex trans-[RuHP(OMe)3}(bpzm)(cod)]CF3SOP3 (5a), which also readily isomerizes to cis[RuHP(OMe)3}(bpzm)(cod)]CF3SO3 (5b), was isolated from the reactions of 2 with P(OMe)3, or alternatively from the reaction of 1 with P(OMe)3 and AgCF3SO3. Finally, the reaction of 2 or 1 (in the presence of AgCF3SO3) with N-donors pyridine, 4-methylpyridine (4-picoline)

  [RuHCl（bpzm）（cod）]（1）（bpzm =双（吡唑-1-基）甲烷，cod =环辛-1,5-二烯）与一当量的AgCF 3 SO 3反应，得到三氟甲磺酸酯-含有[RuH（CF 3 SO 3）（bpzm）（cod）]（2）。2与PMe 2 Ph的反应允许合成反式-[RuH（PMe 2 Ph）（bpzm）（cod）] CF 3 SO 3（bd3a），该异构体易于异构化为顺式-[RuH（PMe 2 Ph）（ bpzm）（cod）] CF 3 SO 3（3b），而类似的反应是1在AgCF 3 SO 3的存在下，生成了一系列含膦的配合物，例如[RuH（CF 3 SO 3）（cod）（PMe 2 Ph）2 ]（4），该过程的产物在很大程度上取决于反应条件。复杂的反式-[RuH P（OMe）3 }（bpzm）（cod）] CF 3 SOP 3（5a），它也容易异构化为顺式[RuH P（OMe）3
• Three-centre dihydrogen bond with fast interchange between proton and hydride: a very active catalyst for D+–H2 exchange†
  作者：A. Caballero、F. A. Jalón

  DOI：10.1039/a803972k

  日期：——

  Protonation of a ruthenium hydride containing the hemilabile ligand PPh2py gave a complex with a three-centre dihydrogen bond (Ru–H···H–Py2), and this system exhibits a fast proton/hydride interchange and is a very active catalyst for D+–H2 exchange.

  对含有半亲和配体 PPh2py 的氢化钌进行质子化处理后，得到了一种具有三中心二氢键（RuâHÂ-Â-Â-HâPy2）的配合物，该体系表现出快速的质子/氢化物交换，是一种非常活跃的 D+âH2 交换催化剂。
• A study of the coordination ability of 2,5-di(2-pyridyl)phospholes on Ru centres
  作者：Agustı́n Caballero、Félix A Jalón、Blanca R Manzano、Mathieu Sauthier、Loı̈c Toupet、Régis Réau

  DOI：10.1016/s0022-328x(02)01803-x

  日期：2002.12

  The coordination behaviour of the readily available 1-phenyl-2,5-di(2-pyridyl)phosphole (NPN) toward Ru centres was investigated. Neutral and ionic compounds of formula [RuCl(p-cymene)(NPN)]TfO (TfO = CF3SO3)... (1), [RuCl(p -cyme-ne)(NPN)]BF4 (2), [RuCl(C6Me6)(NPN)]TfO (3), RuCp'Cl(NPN) [CP' = C5H5 (4), C5Me5 (5)], Ru(C5Me5)(sigma(1)-C8H13)(NPN) (6), RUCl2(NPN)(2) (7) and RuCIH(cod)(NPN) (cod = 1,5-cyclooctadiene) (8) were obtained. Two diastereomers were obtained for 1, 2 and 4, (a, b) while three were found in the case of 8 (a-c). According to NMR spectroscopy, the 2,5-bis(2-pyridyl)phosphole acts as a 1,4-P,N chelate ligand in all cases. This behaviour was confirmed by an X-ray diffraction study performed on complex 1a. Proton transfer studies on complex 8 demonstrated the influence of the molecular structure on the ability to form dihydrogen bridges. (C) 2002 Elsevier Science B.V. All rights reserved.
• Jalon, Felix A.; Lopez-Agenjo, Ana; Manzano, Blanca R., Journal of the Chemical Society, Dalton Transactions
  作者：Jalon, Felix A.、Lopez-Agenjo, Ana、Manzano, Blanca R.、Moreno-Lara, Montserrat、Rodriguez, Ana、et al.

  DOI：——

  日期：——