3-（（（6-（4-溴苯基）己氧基）甲基）-3-乙基氧杂环丁烷 | 746633-97-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-（（（6-（4-溴苯基）己氧基）甲基）-3-乙基氧杂环丁烷
• 英文名称: 3-[6-(4-bromophenyl)hexyloxymethyl]-3-ethyloxetane
• 英文别名: 3-[6-(4-bromophenyl)hexoxymethyl]-3-ethyloxetane
• CAS: 746633-97-6
• 化学式: C₁₈H₂₇BrO₂
• 分子量: 355.315
• InChiKey: QFJPFDDEHBKJJF-UHFFFAOYSA-N

物化性质

• 沸点：
  424.3±25.0 °C(Predicted)
• 密度：
  1.178±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  21
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-（（（6-（4-溴苯基）己氧基）甲基）-3-乙基氧杂环丁烷 、 联苯胺 在 Pd₂dba3/P(tBu)3 complex sodium t-butanolate 作用下， 以 甲苯 为溶剂， 生成 4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]-N-[4-[4-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]-N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]anilino]phenyl]phenyl]-N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]phenyl]aniline
  参考文献：
  名称：

  用于蓝磷光有机发光二极管的新型可交联空穴导体。

  摘要：

  DOI：

  10.1002/anie.200605055
• 作为产物：
  描述：

  、 对溴碘苯 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 水 、 氯化铵 作用下， 以 四氢呋喃 为溶剂， 反应 16.17h， 以41%的产率得到3-（（（6-（4-溴苯基）己氧基）甲基）-3-乙基氧杂环丁烷
  参考文献：
  名称：

  [EN] REACTIVE MESOGENIC CHARGE TRANSPORT COMPOUNDS CONTAINING AT LEAST TWO THIOPHENE GROUPS
  [FR] COMPOSES MESOGENES REACTIFS A PROPRIETES DE TRANSPORT DE CHARGE

  摘要：

  公开号：

  WO2005080369A3

文献信息

• Reactive mesogenic charge transport compounds
  申请人：Heeney Martin

  公开号：US20050184274A1

  公开（公告）日：2005-08-25

  The invention relates to new reactive mesogenic compounds with charge transport properties comprising at least two thiophene groups, their use as semiconductors or charge transport materials, in optical, electro-optical or electronic devices like for example liquid crystal displays, optical films, organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as RFID tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices, and to a field effect transistor, light emitting device or ID tag comprising the reactive mesogenic charge transport compounds.

  本发明涉及一种新的具有电荷传输性质的反应性介向化合物，包括至少两个噻吩基团，其用作半导体或电荷传输材料，用于光学、电光或电子设备，例如液晶显示器、光学薄膜、有机场效应晶体管（FET或OFET）用于薄膜晶体管液晶显示器和集成电路器件，例如RFID标签、平面显示器中的电致发光器件以及光伏和传感器器件，以及包括反应性介向电荷传输化合物的场效应晶体管、发光器件或ID标签。
• Reactive mesogenic charge transport compounds containing at least two thiophene groups
  申请人：Merck Patent GmbH

  公开号：EP1903036A1

  公开（公告）日：2008-03-26

  The invention relates to new reactive mesogenic compounds with charge transport properties comprising at least two thiophene groups, their use as semiconductors or charge transport materials, in optical, electro-optical or electronic devices like for example liquid crystal displays, opiicai films, organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as RFID tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices, and to a field effect transistor, light emitting device or ID tag comprising the reactive mesogenic charge transport compounds.

  本发明涉及至少含有两个噻吩基团的具有电荷传输特性的新型活性介源化合物，它们可用作光学、电子光学或电子设备中的半导体或电荷传输材料，例如液晶显示器、鸦片胶片、用于薄膜晶体管液晶显示器和集成电路设备（如 RFID 标签）的有机场效应晶体管（FET 或 OFET）、平板显示器中的电致发光器件以及光电器件、用于薄膜晶体管液晶显示器和集成电路设备（如 RFID 标签）的有机场效应晶体管 （FET 或 OFET）、平板显示器中的电致发光器件、光电和传感器设备，以及包含活性介源电荷传输化合物 的场效应晶体管、发光器件或 ID 标签。
• Crosslinkable TAPC-Based Hole-Transport Materials for Solution-Processed Organic Light-Emitting Diodes with Reduced Efficiency Roll-Off
  作者：Georgios Liaptsis、Klaus Meerholz

  DOI：10.1002/adfm.201201197

  日期：2013.1.21

  Abstract1‐Bis[4‐[N,N‐di(4‐tolyl)amino]phenyl]‐cyclohexane (TAPC) has been widely used in xerography and organic light‐emitting diodes (OLEDs), but derivatives are little known. Here, a new series of solution‐processable, crosslinkable hole conductors based on TAPC with varying highest occupied molecular orbital (HOMO) energies from −5.23 eV to −5.69 eV is implemented in blue phosphorescent OLEDs. Their superior perfomance compared with the well‐known N4,N4,N4′,N4′‐tetraphenylbiphenyl‐4,4′‐diamine (TPDs) analogues regarding hole‐injection and mobility, electron and exciton blocking capabilities, efficiency, and efficiency roll‐off is demonstrated. Overall, the TAPC‐based devices feature higher luminous and power efficiency over a broader range of brightness levels and reduced efficiency roll off. A systematic broadening of the emission zone is observed as the hole‐injection barrier between the anode and the hole‐transporting layer increased.
• REACTIVE MESOGENIC CHARGE TRANSPORT COMPOUNDS CONTAINING AT LEAST TWO THIOPHENE GROUPS
  申请人：Merck Patent GmbH

  公开号：EP1725541A2

  公开（公告）日：2006-11-29
• US7674397B2
  申请人：——

  公开号：US7674397B2

  公开（公告）日：2010-03-09