3-（（（6-（4-溴苯氧基）己氧基）甲基）-3-乙基氧杂环丁烷 | 860815-31-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 3-（（（6-（4-溴苯氧基）己氧基）甲基）-3-乙基氧杂环丁烷
• 英文名称: Oxetane, 3-[[[6-(4-bromophenoxy)hexyl]oxy]methyl]-3-ethyl-
• 英文别名: 3-[6-(4-bromophenoxy)hexoxymethyl]-3-ethyloxetane
• CAS: 860815-31-2
• 化学式: C₁₈H₂₇BrO₃
• 分子量: 371.315
• InChiKey: KUSBZNVHBRCXIB-UHFFFAOYSA-N

物化性质

• 沸点：
  440.3±25.0 °C(Predicted)
• 密度：
  1.201±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  22
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-（（（6-（4-溴苯氧基）己氧基）甲基）-3-乙基氧杂环丁烷 、 联苯胺 在 Pd₂dba3/P(tBu)3 complex sodium t-butanolate 作用下， 以 甲苯 为溶剂， 生成 4-[4-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexoxy]-N-[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexoxy]phenyl]anilino]phenyl]-N,N-bis[4-[6-[(3-ethyloxetan-3-yl)methoxy]hexoxy]phenyl]aniline
  参考文献：
  名称：

  用于蓝磷光有机发光二极管的新型可交联空穴导体。

  摘要：

  DOI：

  10.1002/anie.200605055

文献信息

• Cross Linked Organic Conductive Layer
  申请人：Gough Neil

  公开号：US20110245429A1

  公开（公告）日：2011-10-06

  The present invention provides various compounds, compositions, methods, and processes for forming a cross-linked conductive polymeric layer in an electronic device.

  本发明提供了各种化合物、组合物、方法和过程，用于在电子设备中形成交联导电聚合层。
• ORGANIC ELECTRONICS MATERIAL, INK COMPOSITION, AND ORGANIC ELECTRONICS ELEMENT
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP3528300A1

  公开（公告）日：2019-08-21

  One embodiment relates to an organic electronic material containing a charge transport polymer or oligomer, wherein the charge transport polymer or oligomer has a nitrogen atom and an aromatic hydrocarbon group ArF that is bonded to the nitrogen atom and is substituted with a fluorine atom, and also has a structural unit containing a carbazole structure.

  一个实施方案涉及一种含有电荷传输聚合物或低聚物的有机电子材料，其中电荷传输聚合物或低聚物具有一个氮原子和一个与氮原子键合并被氟原子取代的芳香烃基团 ArF，还具有一个含有咔唑结构的结构单元。
• Crosslinkable TAPC-Based Hole-Transport Materials for Solution-Processed Organic Light-Emitting Diodes with Reduced Efficiency Roll-Off
  作者：Georgios Liaptsis、Klaus Meerholz

  DOI：10.1002/adfm.201201197

  日期：2013.1.21

  Abstract1‐Bis[4‐[N,N‐di(4‐tolyl)amino]phenyl]‐cyclohexane (TAPC) has been widely used in xerography and organic light‐emitting diodes (OLEDs), but derivatives are little known. Here, a new series of solution‐processable, crosslinkable hole conductors based on TAPC with varying highest occupied molecular orbital (HOMO) energies from −5.23 eV to −5.69 eV is implemented in blue phosphorescent OLEDs. Their superior perfomance compared with the well‐known N4,N4,N4′,N4′‐tetraphenylbiphenyl‐4,4′‐diamine (TPDs) analogues regarding hole‐injection and mobility, electron and exciton blocking capabilities, efficiency, and efficiency roll‐off is demonstrated. Overall, the TAPC‐based devices feature higher luminous and power efficiency over a broader range of brightness levels and reduced efficiency roll off. A systematic broadening of the emission zone is observed as the hole‐injection barrier between the anode and the hole‐transporting layer increased.
• ORGANIC ELECTRONIC MATERIAL, INK COMPOSITION CONTAINING SAME, AND ORGANIC THIN FILM, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, AND DISPLAY DEVICE FORMED THEREWITH
  申请人：Showa Denko Materials Co., Ltd.

  公开号：EP2439804B1

  公开（公告）日：2021-07-21
• New Crosslinkable Hole Conductors for Blue-Phosphorescent Organic Light-Emitting Diodes
  作者：Philipp Zacharias、Malte C. Gather、Markus Rojahn、Oskar Nuyken、Klaus Meerholz

  DOI：10.1002/anie.200605055

  日期：2007.6.4