萘并(1,2-b)环氧乙烯 | 277-50-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 萘并(1,2-b)环氧乙烯
• 英文名称: naphthalene-1,2-oxide
• 英文别名: Naphth(1,2-b)oxirene；naphtho[1,2-b]oxirene
• CAS: 277-50-9
• 化学式: C₁₀H₆O
• 分子量: 142.157
• InChiKey: YDRQTXULVDCOJX-UHFFFAOYSA-N

物化性质

• 沸点：
  257.4±7.0 °C(Predicted)
• 密度：
  1.313±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2932999099

反应信息

• 作为反应物：
  描述：

  萘并(1,2-b)环氧乙烯 以 甲醇 为溶剂， 生成 benzopentafulvenone
  参考文献：
  名称：

  激光闪光光解法对六元环邻重氮酮进行沃尔夫重排的动力学

  摘要：

  DOI：

  10.1021/j100348a028
• 作为产物：
  描述：

  2-diazo-1,2-naphthoquinone 以 甲醇 为溶剂， 生成 萘并(1,2-b)环氧乙烯
  参考文献：
  名称：

  激光闪光光解法对六元环邻重氮酮进行沃尔夫重排的动力学

  摘要：

  DOI：

  10.1021/j100348a028

文献信息

• SUBSTITUTED OR UNSUBSTITUTED ALLYL GROUP-CONTAINING MALEIMIDE COMPOUND, PRODUCTION METHOD THEREFOR, AND COMPOSITION AND CURED PRODUCT USING SAID COMPOUND
  申请人：DIC CORPORATION

  公开号：US20200325101A1

  公开（公告）日：2020-10-15

  Bismaleimides (BMI) exhibit excellent heat resistance (high Tg and high resistance to thermal decomposition) compared to epoxy resins and phenolic resins, and therefore, in recent years, more attention is paid to bismaleimides as a resin material for the next-generation devices represented by SiC power semiconductors, in addition to the investigation on the use of bismaleimides for electronic material applications. As such, conventional BMI's are known as highly heat-resistant resins; however, there is a demand for a resin having higher heat resistance for advanced material applications and the like. Thus, an object of the invention is to provide a novel maleimide compound having superior heat resistance. Disclosed is a substituted or unsubstituted allyl group-containing maleimide compound having a structure with three or more benzene rings, having one or more groups each having a substituted or unsubstituted allyl group, and having one or more maleimide groups.

  亚苯基马来酰亚胺化合物，具有三个或更多苯环的结构，含有一个或多个取代或未取代的烯丙基团，以及一个或多个马来酰亚胺基团，具有卓越的耐热性。
• METHOD FOR PRODUCING CYANOGEN-HALIDE, CYANATE ESTER COMPOUND AND METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20150299110A1

  公开（公告）日：2015-10-22

  A method for efficiently producing a cyanogen halide with suppressed side effects, and a method for producing a high-purity cyanate ester compound at a high yield includes contacting a halogen molecule with an aqueous solution containing hydrogen cyanide and/or a metal cyanide, so that the hydrogen cyanide and/or the metal cyanide is allowed to react with the halogen molecule in the reaction solution to obtain the cyanogen halide, wherein more than 1 mole of the hydrogen cyanide or the metal cyanide is used based on 1 mole of the halogen molecule, and when an amount of substance of an unreacted hydrogen cyanide or an unreacted metal cyanide is defined as mole (A) and an amount of substance of the generated cyanogen halide is defined as mole (B), the reaction is terminated in a state in which (A):(A)+(B) is between 0.00009:1 and 0.2:1.

  一种用于高效生产抑制副作用的氰卤化物，以及以高收率生产高纯度氰酸酯化合物的方法包括将卤素分子与含有氢氰酸和/或金属氰化物的水溶液接触，使得氢氰酸和/或金属氰化物与卤素分子在反应溶液中发生反应以获得氰卤化物，其中基于1摩尔卤素分子使用超过1摩尔的氢氰酸或金属氰化物，当未反应的氢氰酸或未反应的金属氰化物的物质量定义为摩尔(A)，生成的氰卤化物的物质量定义为摩尔(B)，反应在(A)：(A)+(B)介于0.00009:1和0.2:1之间的状态中终止。
• Substitution and addition reactions of organic substrates with hypofluorous acid
  作者：Laura E. Andrews、Raymond Bonnett、Evan H. Appelman

  DOI：10.1016/s0040-4020(01)96457-9

  日期：1985.1

  The chemical reactions of hypofluorous acid with aromatic and olefinic substrates show considerable variety. Hypofluorous acid reacts with naphthalene to give 1-naphthol, 2-naphthol and 1,4-naphtho-quinone; with benzo[b]thiophen to give the 1,1-dioxide; with trans-stilbene to give threo-2-fluoro-1-hydroxy-1, 2-diphenylethane, benzophenone and diphenylacetaldehyde; and with cholesteryl acetate to give

  次氟酸与芳香族和烯烃类底物的化学反应显示出相当大的多样性。次氟酸与萘反应生成1-萘酚，2-萘酚和1,4-萘醌; 与苯并[b]噻吩生成1，1-二氧化物；用反式-二苯乙烯得到苏--2-氟-1-羟基-1、2-二苯乙烷，二苯甲酮和二苯乙醛。并与乙酸胆固醇酯反应得到两个环氧化物（α：β= 6.3：1）和两个氟代醇（6β-氟-5β-o1和5α-氟-6β-o1）。
• OXAZINE COMPOUND, COMPOSITION AND CURED PRODUCT
  申请人：DIC Corporation

  公开号：US20180362479A1

  公开（公告）日：2018-12-20

  The present invention provides an oxazine compound which contains a group having an aromatic ring structure and a plurality of specified carbon-carbon double bond structure so as to achieve an object. The present invention further provides a composition containing the oxazine compound of the present invention, a cured product containing the composition, and a laminate having a layer of the cured product. The present invention further still provides a composition for a heat-resistant material and a composition for an electronic material, which contain the composition containing the oxazine compound of the present invention so as to achieve the object.

  本发明提供了一种含有芳香环结构和多个指定碳-碳双键结构的噁嗪化合物，以达到目的。本发明还提供了一种含有本发明的噁嗪化合物的组合物，一种含有该组合物的固化产物以及具有固化产物层的层压板。本发明还进一步提供了一种耐热材料的组合物和一种电子材料的组合物，其中包含本发明的噁嗪化合物组合物以达到目的。
• Oxazine compound, composition and cured product
  申请人：DIC Corporation

  公开号：US10399312B2

  公开（公告）日：2019-09-03

  The present invention provides an oxazine compound which contains a group having an aromatic ring structure and a plurality of specified carbon-carbon double bond structure so as to achieve an object. The present invention further provides a composition containing the oxazine compound of the present invention, a cured product containing the composition, and a laminate having the cured product layer. The present invention further still provides a composition for a heat-resistant material and a composition for an electronic material, which contain the composition containing the oxazine compound of the present invention so as to achieve an object.

  本发明提供了一种含有芳香环结构和多个特定碳-碳双键结构的噁嗪化合物，以达到一定目的。本发明还提供了一种包含本发明的噁嗪化合物的组合物、包含该组合物的固化产物以及具有固化产物层的层压板。本发明还进一步提供了一种用于耐热材料的组合物和用于电子材料的组合物，其中包含本发明的噁嗪化合物组合物，以达到一定目的。