2-dicyanomethylene-2,5-dihydrotellurophene | 183309-02-6

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: 2-dicyanomethylene-2,5-dihydrotellurophene
• 英文别名: 2-(2H-tellurophen-5-ylidene)propanedinitrile
• CAS: 183309-02-6
• 化学式: C₇H₄N₂Te
• 分子量: 243.722
• InChiKey: VTOQUZNUTSHCFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.98
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-dicyanomethylene-2,5-dihydrotellurophene 在 氢氧化钾 、 potassium hexacyanoferrate(III) 、 β-丙氨酸 作用下， 以 乙酸酐 、 苯 为溶剂， 生成 2-{5-[2,3-Bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-cyclopropylidene]-5H-tellurophen-2-ylidene}-malononitrile
  参考文献：
  名称：

  基于新型碲烯扩展的[3]辐射烯受体的金属电荷转移配合物的晶体结构和导电性能

  摘要：

  制备了具有 TTF 的新型碲苯扩展的 [3]radialene 型受体的金属电荷转移配合物。通过X射线晶体分析和热电功率测量证明通过受体柱发生一维金属传导。

  DOI：

  10.1246/cl.1997.627
• 作为产物：
  描述：

  2-iodotellurophene 、 丙二腈 在 bis-triphenylphosphine-palladium(II) chloride sodium hydride 作用下， 生成 2-dicyanomethylene-2,5-dihydrotellurophene
  参考文献：
  名称：

  Efficient Synthesis of 2-Iodo and 2-Dicyanomethyl Derivatives of Thiophene, Selenophene, Tellurophene, and Thieno[3,2-b]thiophene

  摘要：

  An effective synthesis of 2-iodothiophene, 2-iodotellurophene, and 2-iodothieno[3,2-b]thiophene and a Pd-catalyzed carbon-carbon coupling reaction of these iodo derivatives as well as 2-iodoselenophene with malononitrile affording novel thienyl-, tellurienyl-, thieno[3,2-b]thienyl-, and selenienylmalononitrile are described. These heteroarylmalononitriles are important synthons for the preparation of 2-dicyanomethylene-2,5-dihydroheterophene chromophores.

  DOI：

  10.3987/com-96-7517

文献信息

• Efficient Synthesis of 2-Iodo and 2-Dicyanomethyl Derivatives of Thiophene, Selenophene, Tellurophene, and Thieno[3,2-b]thiophene
  作者：Kazuko Takahashi、Shinji Tarutani

  DOI：10.3987/com-96-7517

  日期：——

  An effective synthesis of 2-iodothiophene, 2-iodotellurophene, and 2-iodothieno[3,2-b]thiophene and a Pd-catalyzed carbon-carbon coupling reaction of these iodo derivatives as well as 2-iodoselenophene with malononitrile affording novel thienyl-, tellurienyl-, thieno[3,2-b]thienyl-, and selenienylmalononitrile are described. These heteroarylmalononitriles are important synthons for the preparation of 2-dicyanomethylene-2,5-dihydroheterophene chromophores.
• Crystal Structure and Conducting Property of a Metallic Charge-Transfer Complex Based on a Novel Tellurophene-Extended [3]Radialene Acceptor
  作者：Shinji Tarutani、Takehiko Mori、Hatsumi Mori、Shoji Tanaka、Kazuko Takahashi

  DOI：10.1246/cl.1997.627

  日期：1997.7

  A metallic charge-transfer complex of a novel tellurophene-extended [3]radialene type acceptor with TTF was prepared. The one-dimensional metallic conduction was proved to occur through the acceptor column by X-ray crystal analysis and thermoelectric power measurement.

  制备了具有 TTF 的新型碲苯扩展的 [3]radialene 型受体的金属电荷转移配合物。通过X射线晶体分析和热电功率测量证明通过受体柱发生一维金属传导。