1,1,3,4,4,4-Hexachlor-1-buten | 62897-30-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,3,4,4,4-Hexachlor-1-buten
• 英文别名: 2,3-di-H-hexachlorobuten-1；1.1.3.4.4.4-Hexachlor-2-buten；1,1,3,4,4,4-Hexachlor-but-1-en；1,1,3,4,4,4-Hexachlor-buten-(1)；2H,3H-hexachloro-but-1-ene；2H,3H-Hexachlor-but-1-en；1,1,3,4,4,4-hexachloro-but-1-ene；1,1,3,4,4,4-Hexachlorobut-1-ene
• CAS: 62897-30-7
• 化学式: C₄H₂Cl₆
• 分子量: 262.778
• InChiKey: GPDIHHYAKSUUOE-UHFFFAOYSA-N

物化性质

• 沸点：
  98 °C(Press: 12 Torr)
• 密度：
  1.676±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,3,4,4,4-Hexachlor-1-buten 在 氢氧化钾 作用下， 生成 1,1,2,4,4-pentachloro-1,3-butadiene
  参考文献：
  名称：

  Sex and Age Effects on Willingness to Communicate, Anxiety, Perceived Competence, and L2 Motivation Among Junior High School French Immersion Students

  摘要：

  The present study involves a cross–sectional investigation of second–language (L2) communication among students in a junior high French late immersion program. The effects of language, sex, and grade on willingness to communicate (WTC), anxiety, and perceived communication competence, on frequency of communication in French, and on the attitude and motivation variables are examined globally and at each grade level. It was found that students’ L2 WTC, perceived competence, and frequency of communication in French increased from grades 7 to 8 and was maintained between grades 8 and 9, despite a drop in motivation between grades 7 and 8 and a steady level of anxiety across the three grades.

  DOI：

  10.1111/1467-9922.00194
• 作为产物：
  描述：

  1,1,1,3,3,3-Hexachlor-but-2-en 在 五氯化磷 作用下， 反应 50.0h， 生成 1,1,3,4,4,4-Hexachlor-1-buten
  参考文献：
  名称：

  Roedig,A. et al., Chemische Berichte, 1977, vol. 110, p. 1484 - 1491

  摘要：

  DOI：

文献信息

• CHLOROALKENE PRODUCTION METHOD ACCOMPANIED WITH DEHYDROCHLORINATION REACTION
  申请人：Tokuyama Corporation

  公开号：EP3293170A1

  公开（公告）日：2018-03-14

  A chloroalkene production method comprising the steps of: carrying out the dehydrochlorination reaction of a chloroalkane in the presence of a Lewis acid catalyst containing a metal chloride to produce a chloroalkene; removing a metal component derived from the catalyst from the obtained reaction solution; and distilling the reaction solution to obtain the purified chloroalkene.

  一种氯代烃生产方法，包括以下步骤 在含有金属氯化物的路易斯酸催化剂存在下，进行氯代烷烃的脱氢氯化反应，生成氯代烯烃； 从得到的反应溶液中去除催化剂中的金属成分；以及 蒸馏反应溶液，得到纯化的氯代烃。
• Neue Thiosubstituierte Butadien- Und Butenin Verbindungen Aus Hexachlorbutenen Und Thiolen
  作者：Cemil İbiş、Tülay Bal

  DOI：10.1080/10426500307913

  日期：2003.3.1

  2,3-Di-H-butene compound 1 gave compounds 3a-f, 4a, 4e, and 5a-d in the presence of thiols 2a-f and Et3N (or NaOH). Compound 7e was obtained from the reaction of 1,3-Di-H-butene 6 with naphthylthiol in DMF In the presence of NaOH, compound 6 and 2 mmol of thiol 2g in EtOHgave compounds 8, 9, 10, and 11.
• Roedig, Alfred; Ibis, Cemil; Zaby, Gottfried, Chemische Berichte, 1981, vol. 114, # 2, p. 684 - 698
  作者：Roedig, Alfred、Ibis, Cemil、Zaby, Gottfried

  DOI：——

  日期：——
• Mueller; Huether, Chemische Berichte, 1931, vol. 64, p. 598
  作者：Mueller、Huether

  DOI：——

  日期：——
• Ibis, Cemil, Liebigs Annalen der Chemie, 1987, p. 1009 - 1011
  作者：Ibis, Cemil

  DOI：——

  日期：——