7,10-dioxahexadecane | 74231-58-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 7,10-dioxahexadecane
• 英文别名: Glycol-dihexylether；Hexane, 1,1'-[1,2-ethanediylbis(oxy)]bis-；1-(2-hexoxyethoxy)hexane
• CAS: 74231-58-6
• 化学式: C₁₄H₃₀O₂
• mdl: MFCD01535732
• 分子量: 230.391
• InChiKey: ITZAHBOREXAZFQ-UHFFFAOYSA-N

物化性质

• 沸点：
  273.0±8.0 °C(Predicted)
• 密度：
  0.845±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  溴己烷 、 乙二醇 在 sodium hydride 作用下， 生成 7,10-dioxahexadecane
  参考文献：
  名称：

  Klocke, Elisabeth; Matzeit, Agnes; Gockeln, Marianne, Chemische Berichte, 1993, vol. 126, # 7, p. 1623 - 1630

  摘要：

  DOI：

文献信息

• 2,2',6,6' - TETRAOXAZOLINYL BIPHENYL LIGAND AND METHOD FOR PREPARING THE SAME
  申请人：Zhang Wanbin

  公开号：US20090043104A1

  公开（公告）日：2009-02-12

  The present invention relates to a method for preparing 2,2′,6,6′-tetraoxazolinyl biphenyl ligand in chemical industry field. In the present invention, compound (III) is reacted with an activator that can activate the hydroxyl group selected from the group consisting of alkyl halosulfonium compound, aryl halosulfonium compound, phosphoryl chloride, phosphorus pentachloride, thionyl chloride and triphenyl phosphine, in the presence of alkali(s), to give the target product (IV), 2,2′,6,6′-tetraoxazolinyl biphenyl ligand. The ligand of the present invention can be used in various asymmetric reactions catalyzed by metals, with high reactivity and stereoselectivity, and thus represents a good application outlook. The 2,2′,6,6′-tetraoxazolinyl biphenyl ligand has the formula of: wherein, R 1 =hydrogen, alkyl, substituted or unsubstituted aryl, substituted or unsubstituted benzyl; R 2 =hydrogen, alkyl, substituted or unsubstituted aryl, substituted or unsubstituted benzyl; R 3 =hydrogen, alkyl, substituted or unsubstituted aryl, substituted or unsubstituted benzyl; R 4 =hydrogen, alkyl, substituted or unsubstituted aryl, substituted or unsubstituted benzyl.

  本发明涉及一种在化工领域制备2,2′,6,6′-四氧杂环己基联苯配体的方法。在本发明中，化合物（III）与可以激活羟基的活化剂发生反应，所述活化剂选自烷基卤磺酸盐化合物、芳基卤磺酸盐化合物、氯代磷酰氯、五氯化磷、氯化亚硫酰和三苯基膦组成的群体，并在碱的存在下，得到目标产物（IV），即2,2′,6,6′-四氧杂环己基联苯配体。本发明的配体可用于由金属催化的各种不对称反应中，具有高反应性和立体选择性，因此具有良好的应用前景。2,2′,6,6′-四氧杂环己基联苯配体的化学式为：其中，R1=氢、烷基、取代或未取代芳基、取代或未取代苄基；R2=氢、烷基、取代或未取代芳基、取代或未取代苄基；R3=氢、烷基、取代或未取代芳基、取代或未取代苄基；R4=氢、烷基、取代或未取代芳基、取代或未取代苄基。
• POLYMER DISPERSIONS FOR CORROSION CONTROL
  申请人：ELIZALDE Oihana

  公开号：US20110245401A1

  公开（公告）日：2011-10-06

  The present invention relates to coating compositions which comprise dispersions of polymers obtained by a multistage procedure, to processes for preparing them, and to their use in corrosion protection.

  本发明涉及涂料组合物，其包括通过多阶段程序获得的聚合物分散体，涉及其制备过程以及它们在防腐保护中的使用。
• METHOD FOR PURIFYING TETRAKIS(FLUOROARYL) BORATE/MAGNESIUM HALIDE, TETRAKIS(FLUOROARYL) BORATE/ETHER COMPLEX AND PROCESS FOR PREPARING THE SAME, AND PROCESS FOR PREPARING TETRAKIS(FLUOROARYL) BORATE DERIVATIVE
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP0913400A1

  公开（公告）日：1999-05-06

  A method for purifying Ar4 BMgX which comprises treating a tetrakis(fluoroaryl) borate/magnesium halide (Ar4BMgX) with (1) an alkaline (earth) metal salt of carboxylic acid, (2) an acid, (3) an acid and then an alkaline (earth) metal hydroxide, or (4) an acid and then an alkaline (earth) metal salt of carboxylic acid; and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) which comprises reacting the treated Ar4BMgX with a compound capable of generating monovalent cationic species. The above purification method permits separation and removal of impurities contained in Ar4 BMgX in an efficient and simple manner. The invention also provides a tetrakis(fluoroaryl) borate/ether complex, a process for preparing the same, and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) by using the ether complex and the compound capable of generating monovalent cationic species as starting compounds. The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl) borate derivatives.

  一种提纯 Ar4 BMgX 的方法，包括用(1)羧酸的碱(土)金属盐、(2)酸、(3)酸然后碱(土)金属氢氧化物或(4)酸然后羧酸的碱(土)金属盐处理四(氟芳基)硼酸盐/卤化镁(Ar4BMgX)；以及制备四（氟芳基）硼酸酯衍生物（Ar4BZ）的工艺，包括将处理过的 Ar4BMgX 与能够生成一价阳离子物种的化合物反应。上述纯化方法可以高效、简单地分离和去除 Ar4 BMgX 中所含的杂质。本发明还提供了一种四(氟芳基)硼酸酯/醚络合物、制备四(氟芳基)硼酸酯/醚络合物的工艺，以及以醚络合物和能够生成一价阳离子种类的化合物为起始化合物制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺。醚络合物很容易提纯到高纯度，因此适合用作制备各种四（氟芳基）硼酸酯衍生物的中间体。
• A method for continuous production of propylene oxide and other alkene oxides
  申请人：REPSOL QUIMICA S.A.

  公开号：EP1074548A1

  公开（公告）日：2001-02-07

  Alkene oxides are produced in a continuous integrated two-step process performed in liquid phase. Step I comprises the oxidation of a secondary alcohol with molecular oxygen to generate hydrogen peroxide at moderate temperature and pressure. This reaction mixture is introduced directly to an olefmic substrate maintained in organic solvent at elevated pressure. During step II of the procedure the olefins undergo epoxidation by the hydrogen peroxide in the presence of a catalyst of titanium-impregnated, amorphous silica. The integrated process requires no intermediate purification or enrichment step and it is particularly well adapted to the production of propylene oxide.

  烯氧化物是在液相中通过连续集成的两步法生产的。步骤 I 包括在中等温度和压力下用分子氧氧化仲醇，生成过氧化氢。反应混合物被直接导入在高压有机溶剂中的烯烃基质中。在该工艺的第二步中，烯烃在钛浸无定形二氧化硅催化剂的作用下被过氧化氢环氧化。这种综合工艺不需要中间提纯或浓缩步骤，特别适用于环氧丙烷的生产。
• Tetrakis(fluoroaryl) borate/ether complexes and process for preparing the same
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1400524A1

  公开（公告）日：2004-03-24

  The invention provides a tetrakis(fluoroaryl) borate/ether complex, and the process for preparing the same, The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl)borate derivatives.

  本发明提供了一种四(氟芳基)硼酸酯/醚络合物及其制备方法，该醚络合物很容易提纯到高纯度，因此适合作为制备各种四(氟芳基)硼酸酯衍生物的中间体。