5-(10-butyl-10H-phenothiazin-3-yl)furan-2-carbaldehyde | 1340541-68-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 5-(10-butyl-10H-phenothiazin-3-yl)furan-2-carbaldehyde
• CAS: 1340541-68-5
• 化学式: C₂₁H₁₉NO₂S
• 分子量: 349.453
• InChiKey: ZKHRGBOWVVIFKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.16
• 重原子数：
  25.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  33.45
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  5-(10-butyl-10H-phenothiazin-3-yl)furan-2-carbaldehyde 、 氰乙酸 在 哌啶 作用下， 以 乙腈 为溶剂， 反应 8.0h， 以74%的产率得到(E)-3-(5-(10-butyl-10H-phenothiazin-3-yl)furan-2-yl)-2-cyanoacrylic acid
  参考文献：
  名称：

  Effect of Five-Membered Heteroaromatic Linkers to the Performance of Phenothiazine-Based Dye-Sensitized Solar Cells

  摘要：

  Phenothiazine derivatives with various conjugated linkers (furan, thiophene, and 3,4-ethylenedioxythiophene) were synthesized and used in dye-sensitized solar cells to study the effect of conjugated linkers on device performance. Among them, one with furan as a conjugated linker showed a solar energy-to-electricity conversion efficiency (eta) of 6.58%, an improvement of over 24% compared with the T2-1 reference cells' 5.29% under AM 1.5 G irradiation.

  DOI：

  10.1021/ol2023517
• 作为产物：
  描述：

  N-butylphenothiazine 在 四(三苯基膦)钯 、 溴 、 potassium carbonate 、 溶剂黄146 、 sodium hydroxide 作用下， 以 四氢呋喃 、 氯仿 、 水 为溶剂， 生成 5-(10-butyl-10H-phenothiazin-3-yl)furan-2-carbaldehyde
  参考文献：
  名称：

  Effect of Five-Membered Heteroaromatic Linkers to the Performance of Phenothiazine-Based Dye-Sensitized Solar Cells

  摘要：

  Phenothiazine derivatives with various conjugated linkers (furan, thiophene, and 3,4-ethylenedioxythiophene) were synthesized and used in dye-sensitized solar cells to study the effect of conjugated linkers on device performance. Among them, one with furan as a conjugated linker showed a solar energy-to-electricity conversion efficiency (eta) of 6.58%, an improvement of over 24% compared with the T2-1 reference cells' 5.29% under AM 1.5 G irradiation.

  DOI：

  10.1021/ol2023517