9-[4-(carbazol-9-yl)phenyl]-9-(4-iodophenyl)-9H-fluorene | 1226876-07-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-[4-(carbazol-9-yl)phenyl]-9-(4-iodophenyl)-9H-fluorene
• 英文别名: 9-[4-[9-(4-iodophenyl)fluoren-9-yl]phenyl]carbazole
• CAS: 1226876-07-8
• 化学式: C₃₇H₂₄IN
• 分子量: 609.509
• InChiKey: JEDDGPQAJVSRBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  39
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三苯基氯硅烷 、 9-[4-(carbazol-9-yl)phenyl]-9-(4-iodophenyl)-9H-fluorene 在 正丁基锂 作用下， 以 乙基-异丙基醚 、 甲苯 为溶剂， 反应 3.25h， 以21%的产率得到9-[4-(carbazol-9-yl)phenyl]-9-[4-(triphenylsilyl)phenyl]-9 H-fluorene
  参考文献：
  名称：

  EP2351760

  摘要：

  公开号：
• 作为产物：
  描述：

  咔唑 、 9,9-bis(4-iodophenyl)fluorene 在 铜 、 potassium carbonate 、 邻二氯苯 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 以42%的产率得到9-[4-(carbazol-9-yl)phenyl]-9-(4-iodophenyl)-9H-fluorene
  参考文献：
  名称：

  EP2351760

  摘要：

  公开号：

文献信息

• COMPOUND HAVING TRIPHENYLSILYL GROUP AND TRIARYLAMINE STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yokoyama Norimasa

  公开号：US20110220881A1

  公开（公告）日：2011-09-15

  The invention provides a light emitting layer host compound and an electron-blocking compound that have high excited triplet levels, and can completely confine the triplet excitons of phosphorescent material, for use as the material of a high-efficient organic electroluminescent device. The invention also provides a high-efficient, high-luminance organic electroluminescent device with the use of the compounds. The compound of the general formula (1) below has a triphenylsilyl group and a triarylamine structure, and the organic electroluminescent device includes a pair of electrodes and at least one organic layer interposed between the pair of electrodes, wherein the compound of the general formula (1) having a triphenylsilyl group and a triarylamine structure is used as constituent material of the at least one organic layer.

  本发明提供了一种具有高激发三重态能级的发光层主体化合物和电子阻挡化合物，可以完全限制磷光材料的三重激子，用作高效有机电致发光器件的材料。本发明还提供了一种高效、高亮度的有机电致发光器件，使用该化合物。通式(1)化合物具有三苯基硅基团和三芳基胺结构，有机电致发光器件包括一对电极和至少一个夹在电极对之间的有机层，其中使用具有三苯基硅基团和三芳基胺结构的通式(1)化合物作为至少一个有机层的组成材料。
• COMPOUND HAVING TRIPHENYLSILYL GROUP AND TRIARYLAMINE STRUCTURE AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2351760A1

  公开（公告）日：2011-08-03

  The invention provides a light emitting layer host compound and an electron-blocking compound that have high excited triplet levels, and can completely confine the triplet excitons of phosphorescent material, for use as the material of a high-efficient organic electroluminescent device. The invention also provides a high-efficient, high-luminance organic electroluminescent device with the use of the compounds. The compound of the general formula (1) below has a triphenylsilyl group and a triarylamine structure, and the organic electroluminescent device includes a pair of electrodes and at least one organic layer interposed between the pair of electrodes, wherein the compound of the general formula (1) having a triphenylsilyl group and a triarylamine structure is used as constituent material of the at least one organic layer.

  本发明提供了一种发光层主化合物和一种电子阻滞化合物，它们具有较高的激发三重态水平，能够完全限制磷光材料的三重态激子，可用作高效有机电致发光器件的材料。本发明还提供了一种使用上述化合物的高效、高亮度有机电致发光器件。 下面通式（1）的化合物具有三苯基硅基和三芳基胺结构，有机电致发光装置包括一对电极和至少一个夹在这对电极之间的有机层，其中具有三苯基硅基和三芳基胺结构的通式（1）化合物被用作至少一个有机层的组成材料。
• Compound having triphenylsilyl group and triarylamine structure, and organic electroluminescent device
  申请人：Yokoyama Norimasa

  公开号：US10059725B2

  公开（公告）日：2018-08-28

  The invention provides a light emitting layer host compound and an electron-blocking compound that have high excited triplet levels, and can completely confine the triplet excitons of phosphorescent material, for use as the material of a high-efficient organic electroluminescent device. The invention also provides a high-efficient, high-luminance organic electroluminescent device with the use of the compounds. The compound of the general formula (1) below has a triphenylsilyl group and a triarylamine structure, and the organic electroluminescent device includes a pair of electrodes and at least one organic layer interposed between the pair of electrodes, wherein the compound of the general formula (1) having a triphenylsilyl group and a triarylamine structure is used as constituent material of the at least one organic layer.

  本发明提供了一种发光层主化合物和一种电子阻滞化合物，它们具有较高的激发三重态水平，能够完全限制磷光材料的三重态激子，可用作高效有机电致发光器件的材料。本发明还提供了一种使用上述化合物的高效、高亮度有机电致发光器件。 下面通式（1）的化合物具有三苯基硅基和三芳基胺结构，有机电致发光装置包括一对电极和至少一个夹在这对电极之间的有机层，其中具有三苯基硅基和三芳基胺结构的通式（1）化合物被用作至少一个有机层的组成材料。