5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol | 36879-93-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol
• CAS: 36879-93-3
• 化学式: C₁₂H₉F₁₇S
• 分子量: 508.242
• InChiKey: FYXGLJLFROBKMJ-UHFFFAOYSA-N

物化性质

• 沸点：
  240.4±40.0 °C(Predicted)
• 密度：
  1.523±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  30
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol 在 sodium hydroxide 作用下， 反应 12.0h， 以96%的产率得到1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-12-(5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluoro-dodecyldisulfanyl)-dodecane
  参考文献：
  名称：

  Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer

  摘要：

  New fluorinated thiols R-F(CH2)(p)SH and disulfides [R-F(CH2)(p)S](2) containing a butylic spacer (p=4) between the perfluorinated part and the thiol (or disulfide) function were easily obtained in good yields with a purity higher than 98%. This allows us to obtain homologues (p>4) for their use as synthetic intermediates or as constituents for molecular organized systems. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00303-8
• 作为产物：
  描述：

  1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷 在 氢氧化钾 、 sodium hydroxide 、 lithium aluminium tetrahydride 、 三溴化磷 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙醚 、 乙醇 为溶剂， 反应 73.0h， 生成 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol
  参考文献：
  名称：

  Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer

  摘要：

  New fluorinated thiols R-F(CH2)(p)SH and disulfides [R-F(CH2)(p)S](2) containing a butylic spacer (p=4) between the perfluorinated part and the thiol (or disulfide) function were easily obtained in good yields with a purity higher than 98%. This allows us to obtain homologues (p>4) for their use as synthetic intermediates or as constituents for molecular organized systems. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00303-8

文献信息

• Semiconductor nanocrystals in fluorous liquids for the construction of light-emitting diodes
  作者：Myeongjin Park、Seok-Heon Jung、Jaehoon Lim、Dae-Young Kim、Hee-Jin Kim、Seungyong Lee、Heeyoung Jung、Seonghoon Lee、Changhee Lee、Jin-Kyun Lee

  DOI：10.1039/c4tc02503b

  日期：——

  This communication reports a materials handling strategy based on fluorous materials chemistry using CdSe/CdS/CdZnS core–shell type semiconductor nanocrystals. When the crystals were treated with the semi-perfluoroalkanethiol ligands in the presence of iPr2EtN, the surface-modified nanocrystals (RF1-NC and RF2-NC) became soluble in the fluorous liquids. Solutions of RF1-NC and RF2-NC in HFE-7500 enabled

  本交流报道了一种基于氟材料化学的材料处理策略，该策略使用CdSe / CdS / CdZnS核-壳型半导体纳米晶体。当在i Pr 2 EtN存在下用半全氟链烷硫醇配体处理晶体时，表面改性的纳米晶体（R F 1-NC和R F 2-NC）可溶于氟液体中。HFE-7500中的R F 1-NC和R F 2-NC解决方案使得能够在小分子空穴传输层之上进行纳米晶体薄膜的溶液浇铸，并提供了适用于发光二极管制造的分层结构。
• Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer
  作者：Natacha Mureau、Frédéric Guittard、Serge Géribaldi

  DOI：10.1016/s0040-4039(00)00303-8

  日期：2000.4

  New fluorinated thiols R-F(CH2)(p)SH and disulfides [R-F(CH2)(p)S](2) containing a butylic spacer (p=4) between the perfluorinated part and the thiol (or disulfide) function were easily obtained in good yields with a purity higher than 98%. This allows us to obtain homologues (p>4) for their use as synthetic intermediates or as constituents for molecular organized systems. (C) 2000 Elsevier Science Ltd. All rights reserved.