phenanthrene-9-carboxamide | 2510-60-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: phenanthrene-9-carboxamide
• 英文别名: Phenanthren-9-carbamid；9-Phenanthrenecarboxamide
• CAS: 2510-60-3
• 化学式: C₁₅H₁₁NO
• 分子量: 221.258
• InChiKey: RKCQJTTZAYJPKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  phenanthrene-9-carboxamide 在 lithium aluminium tetrahydride 、 乙醚 作用下， 生成 1-(9-菲基)甲胺
  参考文献：
  名称：

  DE824491

  摘要：

  公开号：
• 作为产物：
  描述：

  9-腈菲 在 potassium carbonate 作用下， 生成 phenanthrene-9-carboxamide
  参考文献：
  名称：

  Werner; Kunz, Justus Liebigs Annalen der Chemie, 1902, vol. 321, p. 323

  摘要：

  DOI：

文献信息

• Visible Light-Induced Iodine-Catalyzed Transformation of Terminal Alkynes to Primary Amides<i>via</i>CC Bond Cleavage under Aqueous Conditions
  作者：Shashikant U. Dighe、Sanjay Batra

  DOI：10.1002/adsc.201500906

  日期：2016.2.4

  The visible light‐induced iodine‐catalyzed oxidative cleavage of the CC bond for transforming terminal alkynes into primary amides in the presence of ammonia under aqueous conditions is described. This metal‐free protocol which ensued via initial hydroamination of the acetylene bond followed by liberation of diiodomethane (CH2I2) was found to be applicable to aromatic, heteroaromatic and aliphatic

  描述了可见光诱导的碘催化的CC键的氧化裂解，该裂解用于在水性条件下在氨存在下将末端炔烃转化为伯酰胺。通过先乙炔键的加氢胺化反应，然后释放出二碘甲烷（CH 2 I 2）而产生的这种无金属方案适用于芳族，杂芳族和脂族炔烃。
• 1063. Studies in photochemistry. Part I. The stilbenes
  作者：M. V. Sargent、C. J. Timmons

  DOI：10.1039/jr9640005544

  日期：——
• 13. Symmetrical triad prototropic systems. Part IX. The influence of polynuclear aryl groups upon mobility and equilibrium in the αγ-diarylmethyleneazomethine system
  作者：Charles W. Shoppee

  DOI：10.1039/jr9330000037

  日期：——
• A palladium-catalyzed carbonylative route to primary amides
  作者：Enrico Morera、Giorgio Ortar

  DOI：10.1016/s0040-4039(98)00259-7

  日期：1998.4

  The palladium-catalyzed reaction of aryl and vinyl iodides and triflates with carbon monoxide in the presence of hexamethyldisilazane followed by hydrolytic work-up affords aromatic and alpha,beta-unsaturated primary amides in good to high yields under relatively mild conditions. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Semantic aspects of morphological processing: Transparency effects in Serbian
  作者：Laurie Beth Feldman、Dragana Barac-Cikoja、Aleksandar Kostić

  DOI：10.3758/bf03194964

  日期：2002.6

  We examined the contribution of semantics to morphological facilitation in the visual lexical decision task at two stimulus onset asynchronies (SOAs) with Serbian materials. Primes appeared in Roman or Cyrillic characters. Targets always were printed in Roman. When primes were presented at an SOA of 250 msec, decision latencies to verbal targets (e.g., VOLIM) showed greatest facilitation after inflectionally (e.g., VOLE) related primes, significantly less after semantically transparent derived primes (e.g., ZAVOLE), and less again after semantically opaque derived primes (e.g., PREVOLE). Latencies after semantically transparent and opaque derived target words did not differ at an SOA of 48 msec. Both were slower than after inflectionally related primes. Stated generally, effects of semantic transparency among derivationally related verb forms were evident at long SOAs, but not at short ones. Under alphabet-alternating conditions, magnitudes of facilitation were greater overall, but the pattern was similar. The outcome suggests that restricted processing time for the prime limits the contribution of semantics to morphological processing and calls into question accounts that posit a task-invariant semantic criterion for morphological decomposition within the lexicon.