9-[(N-dodecylcarbazole-3-yl)methylene]-2,4,5,7-tetranitrofluorene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-[(N-dodecylcarbazole-3-yl)methylene]-2,4,5,7-tetranitrofluorene
• 英文别名: 9-Dodecyl-3-[(2,4,5,7-tetranitrofluoren-9-ylidene)methyl]carbazole；9-dodecyl-3-[(2,4,5,7-tetranitrofluoren-9-ylidene)methyl]carbazole
• 化学式: C₃₈H₃₇N₅O₈
• 分子量: 691.74
• InChiKey: BSEULITZTSTDSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  51
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  188
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  9-dodecyl-9H-carbazole 在 三氯氧磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.5h， 生成 9-[(N-dodecylcarbazole-3-yl)methylene]-2,4,5,7-tetranitrofluorene
  参考文献：
  名称：

  Bistable molecular orientation of a fluorene derivative with an intramolecular charge transfer in a poly(methyl methacrylate) host

  摘要：

  The orientation of bistable molecules incorporated in a polymer host is addressed and studied by means of all-optical poling. Molecular reorientation between two stable molecular forms is assigned as the origin of the optically induced second-order nonlinear optical susceptibility. We found a new non-photochromic photo-induced reaction scheme by which efficient all-optical poling is achieved. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2006.02.005

文献信息

• Bistable molecular orientation of a fluorene derivative with an intramolecular charge transfer in a poly(methyl methacrylate) host
  作者：Aleksandra Apostoluk、Jean-Michel Nunzi、Igor F. Perepichka

  DOI：10.1016/j.cplett.2006.02.005

  日期：2006.4

  The orientation of bistable molecules incorporated in a polymer host is addressed and studied by means of all-optical poling. Molecular reorientation between two stable molecular forms is assigned as the origin of the optically induced second-order nonlinear optical susceptibility. We found a new non-photochromic photo-induced reaction scheme by which efficient all-optical poling is achieved. (c) 2006 Elsevier B.V. All rights reserved.