3-(1-(2-(2-(2-chloroethoxy)ethoxy)ethyl)-1H-imidazol-3-ium-3-yl)propane-1-sulfonate | 1226896-30-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-(1-(2-(2-(2-chloroethoxy)ethoxy)ethyl)-1H-imidazol-3-ium-3-yl)propane-1-sulfonate
• CAS: 1226896-30-5
• 化学式: C₁₂H₂₁ClN₂O₅S
• 分子量: 340.828
• InChiKey: IFTYKRPDCCZNCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.02
• 重原子数：
  21.0
• 可旋转键数：
  12.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  84.47
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  3-(1-(2-(2-(2-chloroethoxy)ethoxy)ethyl)-1H-imidazol-3-ium-3-yl)propane-1-sulfonate 、 (4-羟基苯基)二苯基膦 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 18.0h， 生成 3-[3-[2-[2-[2-(4-Diphenylphosphanylphenoxy)ethoxy]ethoxy]ethyl]imidazol-1-ium-1-yl]propane-1-sulfonate
  参考文献：
  名称：

  Water-Soluble Palladium and Gold Nanoparticles Functionalized by a New Phosphine with Zwitterionic Liquid Based on Imidazolium Sulfonate Linked Ethylene Glycol Moiety

  摘要：

  A new phosphine with zwitterionic liquid based on imidazolium sulfonate linked ethylene glycol moiety (1) as a protective ligand for metal nanoparticles has been prepared. Its phosphine 1-stabilized palladium and gold nanoparticles (1-Pd and 1-Au) were found to be soluble in water, and remarkably stable in high concentration of aqueous electrolyte and ionic liquid. 1-Pd nanoparticles behave as an efficient catalyst for the Suzuki cross-coupling reaction in an aqueous medium.

  DOI：

  10.3987/com-09-s(s)128
• 作为产物：
  描述：

  1,3-丙烷磺内酯 、 1-(8-chloro-3,6-dioxaoctyl)imidazole 以 丙酮 为溶剂， 反应 120.0h， 生成 3-(1-(2-(2-(2-chloroethoxy)ethoxy)ethyl)-1H-imidazol-3-ium-3-yl)propane-1-sulfonate
  参考文献：
  名称：

  Water-Soluble Palladium and Gold Nanoparticles Functionalized by a New Phosphine with Zwitterionic Liquid Based on Imidazolium Sulfonate Linked Ethylene Glycol Moiety

  摘要：

  A new phosphine with zwitterionic liquid based on imidazolium sulfonate linked ethylene glycol moiety (1) as a protective ligand for metal nanoparticles has been prepared. Its phosphine 1-stabilized palladium and gold nanoparticles (1-Pd and 1-Au) were found to be soluble in water, and remarkably stable in high concentration of aqueous electrolyte and ionic liquid. 1-Pd nanoparticles behave as an efficient catalyst for the Suzuki cross-coupling reaction in an aqueous medium.

  DOI：

  10.3987/com-09-s(s)128