tetra(4-aminophenyl)porphyrin iron | 71547-22-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetra(4-aminophenyl)porphyrin iron
• 英文别名: iron mesotetrakis(4-aminophenyl)porphyrin；5,10,15,20-tetrakis(4-aminophenyl)porphin iron；iron tetra(o-aminophenyl)porphyrin；poly iron tetra(o-aminophenyl)porphyrin
• CAS: 71547-22-3
• 化学式: C₄₄H₃₂FeN₈
• 分子量: 728.639
• InChiKey: FGJKIZLYKBVWMY-DAJBKUBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis(4-aminophenyl)porphyrin 、 2,5-二羟基-1,4-苯二羧醛 、 tetra(4-aminophenyl)porphyrin iron 在 溶剂黄146 作用下， 以 乙醇 、 邻二氯苯 为溶剂， 生成
  参考文献：
  名称：

  CN116531505

  摘要：

  公开号：
• 作为产物：
  描述：

  5,10,15,20-tetrakis(4-nitrophenyl)-21,22-dihydroporphyrin 在 盐酸 、 tin(II) chloride dihdyrate 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 生成 tetra(4-aminophenyl)porphyrin iron
  参考文献：
  名称：

  Bifunctional porphyrin-based metal–organic polymers for electrochemical water splitting

  摘要：

  电化学水分离技术为以环保方式生产氢气和氧气提供了可能。

  DOI：

  10.1039/d3dt03371f

文献信息

• Systematic Selection of Metalloporphyrin-Based Catalysts for Oxygen Reduction by Modulation of the Donor-Acceptor Intermolecular Hardness
  作者：Justus Masa、Wolfgang Schuhmann

  DOI：10.1002/chem.201203846

  日期：2013.7.15

  Incisive modulation of the intermolecular hardness between metalloporphyrins and O2 can lead to the identification of promising catalysts for oxygen reduction. The dependency of the electrocatalytic reduction of O2 by metalloporphyrins on the nature of the central metal yields a volcano‐type curve, which is rationalized to be in accordance with the Sabatier principle by using an approximation of the

  金属卟啉与O 2之间分子间硬度的精确调节可导致鉴定出有希望的氧还原催化剂。金属卟啉对O 2的电催化还原对中心金属性质的依赖性产生了一条火山型曲线，该曲线通过使用配合物的亲电性近似值而符合Sabatier原理。通过使用电化学和紫外/可见光数据，选择的的影响内消旋上的能量为π→π*激发锰卟啉的变化-取代基被评价允许一个定量的电催化相关的各种配体的影响的O 2减少复合物。鉴定出锰卟啉可在低超电势下催化氧的还原而不会产生过氧化氢。在650°C下热解后，该复合物的活性显着增强。
• Porphyrin‐based NiFe Porous Organic Polymer Catalysts for the Oxygen Evolution Reaction
  作者：Jing Meng、Ze Xu、Hongxi Li、David James Young、Chuanjiang Hu、Yonggang Yang

  DOI：10.1002/cctc.202001876

  日期：2021.3.5

  Porphyrin‐based NiFe porous organic polymers (POPs) have been synthesized with good porosity and large BET surface areas (261 to 313 m2 g−1). These bimetallic POPs exhibit RuO2‐like OER activity, with the reaction for catalyst FeTAPP‐NiTCPP‐POP reaching a current density of 10 mA cm−2 at a low overpotential of 338 mV and with a small Tafel slope of 52 mV dec−1. FeTAPP‐NiTCPP‐POP was stable over a long

  合成了基于卟啉的NiFe多孔有机聚合物（POPs），具有良好的孔隙率和较大的BET表面积（261至313 m 2  g -1）。这些双金属POP表现出类似RuO 2的OER活性，催化剂FeTAPP-NiTCPP-POP的反应在338 mV的低过电势和10 mf的小TAfel斜率下达到10 mA cm -2的电流密度dec -1。FeTAPP-NiTCPP-POP在反应条件下长期稳定。由于铁和镍中心之间的协同相互作用，这些双金属POPs表现出比单金属POPs更好的催化活性，从而促进了电催化过程。
• Amino-metalloporphyrin polymers derived Fe single atom catalysts for highly efficient oxygen reduction reaction
  作者：Qian He、Yuying Meng、Hao Zhang、Ying Zhang、Qingdi Sun、Tao Gan、Huajian Xiao、Xiaohui He、Hongbing Ji

  DOI：10.1007/s11426-019-9703-7

  日期：2020.6

  Recently, nitrogen-doped porous carbon supported single atom catalysts (SACs) have become one of the most promising alternatives to precious metal catalysts in oxygen reduction reaction (ORR) due to their outstanding performance, especially those derived from porphyrin-based materials. However, most of them involve other metal residuals, which would cause the tedious pre- and/or post-treatment, even mislead the mechanistic investigations and active-site identification. Herein, we report a precursor-dilution strategy to synthesize Fe SACs through the Schiff-based reaction via co-polycondensation of amino-metalloporphyrin, followed by pyrolysis at high temperature. Systematic characterization results provide the compelling evidence of the dominant presence of atomically dispersed Fe-Nx species. Our catalyst shows superior ORR performance with positive half-wave potential (E1/2=0.85 V vs. RHE) in alkaline condition and moderate activity (E1/2=0.68 V vs. RHE) under the acidic condition, excellent methanol tolerance and good long-term stability. All the results indicate Fe SACs would be a promising candidate for replacing the precious Pt in metal-air batteries and fuel cells.

  最近，氮掺杂多孔碳支持的单原子催化剂（SACs）已成为氧还原反应（ORR）中最有前途的贵金属催化剂替代品之一，特别是那些来源于卟啉基材料的催化剂，其性能突出。然而，其中大多数涉及其他金属残留物，这会导致繁琐的前处理和/或后处理，甚至干扰机理研究和活性位点的识别。在此，我们报告了一种前驱体稀释策略，通过胺金属卟啉的Schiff反应进行共聚合，合成Fe SACs，随后进行高温热解。系统的表征结果提供了原子分散的Fe-Nx物种主要存在的有力证据。我们的催化剂在碱性条件下显示出优越的ORR性能，正半波电位（E1/2=0.85 V vs. RHE），在酸性条件下则表现出适度的活性（E1/2=0.68 V vs. RHE），并且具有出色的甲醇耐受性和良好的长期稳定性。所有结果表明，Fe SACs将成为替代贵金属铂在金属-空气电池和燃料电池中的有希望的候选材料。
• Heat‐Treated Aerogel as a Catalyst for the Oxygen Reduction Reaction
  作者：Noam Zion、David A. Cullen、Piotr Zelenay、Lior Elbaz

  DOI：10.1002/anie.201913521

  日期：2020.2.3

  Aerogels are fascinating materials that can be used for a wide range of applications, one of which is electrocatalysis of the important oxygen reduction reaction. In their inorganic form, aerogels can have ultrahigh catalytic site density, high surface area, and tunable physical properties and chemical structures-important features in heterogeneous catalysis. Herein, we report on the synthesis and

  气凝胶是令人着迷的材料，可以用于广泛的应用中，其中一种是重要的氧还原反应的电催化。气凝胶以其无机形式可以具有超高的催化位点密度，高的表面积以及可调节的物理特性和化学结构，这是非均相催化中的重要特征。在此，我们报道了铁卟啉气凝胶的合成和电催化性能。5,10,15,20-（四-4-氨基苯基）卟啉（H2 TAPP）和FeII被用作气凝胶的结构单元，随后在600°C下进行热处理以增强电子电导率和催化活性，而保留其宏观结构。所得材料具有很高浓度的原子分散催化位点（9。
• Intrinsic Activity of Metal Centers in Metal–Nitrogen–Carbon Single-Atom Catalysts for Hydrogen Peroxide Synthesis
  作者：Chang Liu、Hao Li、Fei Liu、Junsheng Chen、Zixun Yu、Ziwen Yuan、Chaojun Wang、Huiling Zheng、Graeme Henkelman、Li Wei、Yuan Chen

  DOI：10.1021/jacs.0c10636

  日期：2020.12.30

  Metal-nitrogen-carbon (M-N-C) single-atom catalysts (SACs) show high catalytic activity for many important chemical reactions. However, an understanding of their intrinsic catalytic activity remains ambiguous because of the lack of well-defined atomic structure control in current M-N-C SACs. Here, we use covalent organic framework SACs with an identical metal coordination environment as model catalysts to elucidate the intrinsic catalytic activity of various metal centers in M-N-C SACs. A pH-universal activity trend is discovered among six 3d transition metals for hydrogen peroxide (H2O2) synthesis, with Co having the highest catalytic activity. Using density functional calculations to access a total of 18 metal species, we demonstrate that the difference in the binding energy of O2* and HOOH* intermediates (EO2* - EHOOH*) on single metal centers is a reliable thermodynamic descriptor to predict the catalytic activity of the metal centers. The predicted high activity of Ir centers from the descriptor is further validated experimentally. This work suggests a class of structurally defined model catalysts and clear mechanistic principles for metal centers of M-N-C SACs in H2O2 synthesis, which may be further extendable to other reactions.