thiacyclotridecane | 295-05-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: thiacyclotridecane
• CAS: 295-05-6
• 化学式: C₁₂H₂₄S
• 分子量: 200.389
• InChiKey: ROWBXKQQQMGHMH-UHFFFAOYSA-N

物化性质

• 沸点：
  298.14°C (rough estimate)
• 密度：
  0.8969

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  thiacyclotridecane 、 二硫化碳 在 silica modified with dimethylaminopropyl group 作用下， 以 均三甲苯 为溶剂， 反应 24.0h， 以100%的产率得到dodecylene trithiocarbonate
  参考文献：
  名称：

  JP5858212

  摘要：

  公开号：
• 作为产物：
  描述：

  1,12-二溴十二烷 在 sodium sulfide 作用下， 以 乙醇 为溶剂， 反应 12.0h， 以64%的产率得到thiacyclotridecane
  参考文献：
  名称：

  Singh, Alok; Mehrotra, Ashok; Regen, Steven L., Synthetic Communications, 1981, vol. 11, # 5, p. 409 - 412

  摘要：

  DOI：

文献信息

• Functional polymer
  申请人：SUSOS AG

  公开号：US10882931B2

  公开（公告）日：2021-01-05

  A functional polymer including at least two different types of side chains, having the general formula (1), wherein A is an at least monosubstituted alkylene or arylene group; B is an amide, ester or ether group and n is 0 or 1; F is selected from: an ester, secondary amine, amide, ether, thio ether, thio ester, and may be the same or different for the different side chains; D is a side chain intended to reversible bind to a substrate or has a coating function; E is a side chain intended to irreversible bind to a substrate, the side chain E and polymer includes 1 to 10 different side chains D and 1 to 10 different side chains E, but at least one of each, and includes a plurality of each type, whereby the different types of side chains are randomly or regularly distributed in the polymer.

  一种功能聚合物，包括至少两种不同类型的侧链，通式为 (1)、 其中 A 是至少单取代的亚烷基或芳基；B 是酰胺基、酯基或醚基，n 是 0 或 1；F 选自酯、仲胺、酰胺、醚、硫代醚、硫代酯，不同侧链可以相同或不同；D 是旨在与基质可逆结合的侧链，或具有包覆功能；E 是旨在与基质不可逆结合的侧链，侧链 E 和聚合物包括 1 至 10 种不同的侧链 D 和 1 至 10 种不同的侧链 E，但每种侧链至少有一种，且每种侧链包括多种类型，其中不同类型的侧链随机或有规律地分布在聚合物中。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Mueller; Schuetz, Chemische Berichte, 1938, vol. 71, p. 691
  作者：Mueller、Schuetz

  DOI：——

  日期：——
• Singh, Alok; Mehrotra, Ashok; Regen, Steven L., Synthetic Communications, 1981, vol. 11, # 5, p. 409 - 412
  作者：Singh, Alok、Mehrotra, Ashok、Regen, Steven L.

  DOI：——

  日期：——